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1 EL (Org an ic E L D is play T e chn olog y ),,, T el: , F AX : Em ail : h anji@keti.re.kr, dgm I.. CRT,,,. CRT T F T LCD, PDP, EL. EL 1m s ( ), EL,,,, EL. PDA % 695 EL, Car Navigation Sy st em (CNS ) 30% 4,230 EL EL. II. EL EL ( ), 1963 P ope anthracene,,,

2 , Kodak V an Slyke T ang Alq3 T PD EL, 1990 Cam bridge PPV - (conju gat ed ) EL EL, 1998 Princeton Pt (OEP ) Ir (ppy )3 100% EL. EL 10 R&D, P ioneer EL 1997, , 64 x 256 EL. M otorola EL. Idem it su Kosan , T DK NEC. EL Eastm an Kodak S any o 2, 5.5" QVGA EL EL, CDT (Cam bridg e Display T echnology ) EL S eiko- Epson inkjet print T F T 2.5 EL. 2 T oshiba 2.85" EL, S ony 13 T F T EL. P ioneer EL EL. LG QV GA EL, 8 VGA EL, 2 EL. SDI NE C SNMD (S am sun g NEC M obile Display ) 2" EL. SDI 8 V GA 15 T F T EL. III. EL 1(a ) EL, (an ode) (cath ode). 100 nm.,. (ex cited stat e ; ex cit on ), (groun d stat e).

3 . 1(b ).,. H OM O (Highest Occupied M olecular Orbital), LUM O (Low est Occupied M olecular Orbit al). EL. < 1> EL (a ) (b ). (a ), (b ) EL,. e x t = in t x ou t = r x p x o u t (1) e x t, in t ( ), o u t. ( in t ) ( r ; ) ( p )., PL, (radiativ e decay efficiency ). EL,,. 1 ).. [ 1(b )] nm IT O. IT O ev, LUM O 4.5 ev IT O

4 ,. IT O, IT O IT O LUM O ( ). IT O IT O IT O.,, IT O,. A qu aregia IT O. IT O. IT O ( ). 1-5 nm, PANI PEDOT, MT DAT A CuP c 5.0 ev LUM O. T PD, NPD. 2 PPV EL IT O. B ( 2 A ) 5. < 2> PPV EL IT O Ca, M g, M g :Li, M g :A g. LiF. LiF

5 . 2 ) E L 3., 25% (sin glet ) 75% (triplet ). (ground state),. (decay tim e) (nano),., (m icro) (milli). 100%, 20%. < 3> (1) (2). e x t = r ( s fl q s r + t p h qt r ) o u t (2) s, f l PL, q s r (radiativ e decay efficiency ), t, p h P L, qt r. PL EL. coum arin 6, rubrene, DCJT B, DSA arm in e, Ir (ppy )3, Pt (OEP ). EL. EL 21% ( 100 % ) EL. EL 4 EL P L (ph otolum inescence) H OM O

6 .. < 4> EL. HIL : Hole Injection Lay er, HT L : H ole T ran sportin g Lay er, EML : Em is sion Lay er, HBL : H ole Blocking Lay er, ET L : Electron T ran sporting Lay er, EIL : Electron Injection Lay er EL, - (T riplet - T riplet Annihilation ) ( 5). Pt (OEP ) 100 sec. 1 sec. Ir - com plex, EL EL. EL EL, ( ).

7 < 5> EL. 3 ) EL, EL, [ 6 (a )]. 6 (b ) 50%.. carb on, black carbon,. < 6> EL

8 4 ) E L. EL. - * ( 7). EL F W HM nm, Ir (ppy )3 Pt (OEP ) EL F W HM nm. Eu T b EL F W HM 10 nm,,.. 8. < 7> EL

9 < 8> EL 5 ) E L EL,. 8,..,, (capacitance). PL,,. T ran sient EL. 8 (b ) 1 KHz,.

10 < 9> EL T ran sient EL IV. EL EL. EL 10 EL ( ), (lin e by line scanning ). EL, ( OF F ) OF F. ON. 100, 100. EL. EL. 1, EL 5 QVGA W. EL,,, IC EL. < 10> EL 1. EL EL 11 EL (

11 ) T ran sist or ON/ OF F, EL. EL,. EL T F T, T F T. EL EL LCD. 2. T F T 3 T F T ( 12). 3 T F T T F T.. (T op emission ) ( 14). EL. EL P t, Au.., 10 nm..

12 < 11> EL < 13> EL < 14> EL

13 V.,,,, EL,.,. EL Eastm an Kodak, CDT, UDC. EL. EL EL poly - Si T F T,. EL. EL. 2 EL. 2. EL 1996, EL EL,. SDI NE C SNMD 2001 EL, SDI 15 EL. LG 2001 EL, LG Philip s LCD,,,, S K, CLD, Eliat ech EL. V I. CDT E astm an Kodak Dupont Siem en s 2002 P hilip s 2002 S ony 2002 T oshib a 2003 P ioneer / 1998 / 2003 S any o / 2002 / 2001 SNMD / 2001 LG 2001

14 EL 8, (SRI) EL EL % EL EL EL., 5 EL. EL SRI. 15 SRI EL. EL , % EL %.

15 < 15> EL SRI 1. "SID1997 S em inar Lecture N ote", SID97 (1997) 2. "SID1998 S em inar Lecture N ote", SID98 (1998) 3. C.W. T ang, S.A. Van Slyk e, A ppl. Phy s. Lett. 51, 913 (1987) 4. C.W. T ang, S.A. Van Slyk e and C.H. Ch en, J. Appl. Phy s. 65, 3610 (1989) 5. J. H. Burroughes, et. al, N ature 347, 359 (1990) 6. OLED 2000, St anford Resource, Inc. (2000) 7. M.A. Baldo, et.al, Nature 395, 151 (1998) 8. M.A. Baldo, et.al, Pure Appl. Ch em. 71, 2095 (1999) 9. EL2000 conferen ce n ote, Ham am at su, (2000) 10. SRI 2001 n ote, SRI (2001) 11. OLED 2001, St anford Resource, Inc. (2001) 12. S ony pres s relea se report (2001) 13. T oshiba press release reprt (2001) 14. SID 1999, Digest of T echnical P aper s (1999) 15. SID 2000, Digest of T echnical P aper s (2000) 16. SID 2001, Digest of T echnical P aper s (2001) 17. Philips research report (2000)

16 ( ),, : : : : LG LCD ( LG- Philip s LCD ) : P ost Doc : 2001 : : EL, T F T - LCD

(72) ๋ฐœ๋ช…์ž ๋งˆ ๋นˆ ๋ฏธ๊ตญ 08618 ๋‰ด์ €์ง€์ฃผ ์œ ์ž‰ ํ•„๋ฆฝ์Šค ๋ธ”๋ฐ”๋ฅด 375 ์ฉก ๋ฆฌ์ฐฝ ๋ฏธ๊ตญ 08618 ๋‰ด์ €์ง€์ฃผ ์œ ์ž‰ ํ•„๋ฆฝ์Šค ๋ธ”๋ฐ”๋ฅด 375 ๋ฐ์•ˆ์ ค๋ฆฌ์Šค ์•Œ๋žœ ๋ฏธ๊ตญ 08618 ๋‰ด์ €์ง€์ฃผ ์œ ์ž‰ ํ•„๋ฆฝ์Šค ๋ธ”๋ฐ”๋ฅด 375 ๋ฐ”๋ก  ์—๋“œ์›Œ๋“œ ๋ฏธ๊ตญ 08618 ๋‰ด์ €์ง€์ฃผ ์œ ์ž‰ ํ•„๋ฆฝ์Šค ๋ธ”๋ฐ”๋ฅด 375

(72) ๋ฐœ๋ช…์ž ๋งˆ ๋นˆ ๋ฏธ๊ตญ 08618 ๋‰ด์ €์ง€์ฃผ ์œ ์ž‰ ํ•„๋ฆฝ์Šค ๋ธ”๋ฐ”๋ฅด 375 ์ฉก ๋ฆฌ์ฐฝ ๋ฏธ๊ตญ 08618 ๋‰ด์ €์ง€์ฃผ ์œ ์ž‰ ํ•„๋ฆฝ์Šค ๋ธ”๋ฐ”๋ฅด 375 ๋ฐ์•ˆ์ ค๋ฆฌ์Šค ์•Œ๋žœ ๋ฏธ๊ตญ 08618 ๋‰ด์ €์ง€์ฃผ ์œ ์ž‰ ํ•„๋ฆฝ์Šค ๋ธ”๋ฐ”๋ฅด 375 ๋ฐ”๋ก  ์—๋“œ์›Œ๋“œ ๋ฏธ๊ตญ 08618 ๋‰ด์ €์ง€์ฃผ ์œ ์ž‰ ํ•„๋ฆฝ์Šค ๋ธ”๋ฐ”๋ฅด 375 (19) ๋Œ€ํ•œ๋ฏผ๊ตญํŠนํ—ˆ์ฒญ(KR) (12) ๊ณต๊ฐœํŠนํ—ˆ๊ณต๋ณด(A) (51) ๊ตญ์ œํŠนํ—ˆ๋ถ„๋ฅ˜(Int. Cl.) C07F 15/00 (2006.01) H01L 51/50 (2006.01) (21) ์ถœ์›๋ฒˆํ˜ธ 10-2013-7033218 (22) ์ถœ์›์ผ์ž(๊ตญ์ œ) 2012๋…„06์›”06์ผ ์‹ฌ์‚ฌ์ฒญ๊ตฌ์ผ์ž ์—†์Œ (85) ๋ฒˆ์—ญ๋ฌธ์ œ์ถœ์ผ์ž 2013๋…„12์›”13์ผ (86) ๊ตญ์ œ์ถœ์›๋ฒˆํ˜ธ PCT/US2012/041149

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334 ้€€ ๆบช ๅญธ ๊ณผ ๅ„’ ๆ•Ž ๆ–‡ ๅŒ– ็ฌฌ 55 ่™Ÿ ่ง’ ่ชช ์—์„œ๋Š” ๋ฟ”์ด ๋‚œ ๋ง๊ณผ ๊ณ ์–‘์ด๋ผ๋Š” ๊ธฐํ˜•์˜ ๋™๋ฌผ์„ ์†Œ์žฌ๋กœ ํ•˜์—ฌ ๋‹น๋Œ€ ์ •์น˜ ์ƒ ํ™ฉ์„ ๋น„ํŒํ•˜์˜€๊ณ , ็™ฝ ้ป‘ ้›ฃ ์—์„œ๋Š” ์„ ๊ณผ ์•…์„ ์ƒ์ง•ํ•˜๋Š” ์ƒ‰๊น”์ธ ็™ฝ ๊ณผ ้ป‘ ์ด ์„œ๋กœ ๋ฒŒ์ด ๋Š” ๋ฌธ๋‹ต์„ ํ†ตํ•˜์—ฌ ์˜ณ๊ณ  ๊ทธ๋ฆ„์˜ ๊ฐ€์น˜๊ด€์ด ์ „๋„๋œ ํ˜„์‹ค์„ธ ๅ— ๅก ๆดช ๅฎ‡ ้  ์˜ ๋…ผ์„ค๋ฅ˜ ์‚ฐ๋ฌธ ์—ฐ๊ตฌ ็ฆน ่Š ่‹ฑ *1) ์ฐจ ๋ก€. ์„œ๋ก . ์นœ๊ทผํ•œ ์†Œ์žฌ๋ฅผ ํ†ตํ•œ ๊ณต๊ฐ์˜ ํ™•๋Œ€. ๋ฌธ๋‹ต์˜ ์„œ์ˆ ๋ฐฉ์‹์„ ํ†ตํ•œ ๋…ผ๋ฆฌ์„ฑ์˜ ๊ฐ•ํ™”. ์šฐ์–ธ์˜ ์„œ์ˆ ๋ฐฉ์‹์„ ํ†ตํ•œ ํ˜„์‹ค ๋น„ํŒ. ๊ฒฐ๋ก  ๊ตญ๋ฌธ์ดˆ๋ก ๅ— ๅก ๆดช ๅฎ‡ ้  ์€ ไป ็ฅ– ์—์„œ ่‚… ๅฎ— ์—ฐ๊ฐ„์— ํ™œ๋™ํ•œ ๋ฌธ์ธ ๊ด€๋ฃŒ์ด๋‹ค. ํ™์šฐ์›์˜ ๋ฌธ์ง‘์ธ ๅ— ๅก ้›† ์€ ์‹œ์™€ ์ƒ์†Œ๋ฌธ์ด ๋Œ€๋ถ€๋ถ„์˜ ๋น„์ค‘์„ ์ฐจ์ง€ํ•˜๊ณ , ่จ˜ ่ชช ๅบ ๋“ฑ์˜ ์‚ฐ๋ฌธ

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