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발간등록번호 11-1543000-000377-01 펄스전기장과콜드플라즈마를이용한고품질고춧가루제조기술개발 (Development of the manufacturing technology for high-quality hot red pepper powder using pulsed electric fields and cold plasma) 중앙대학교 농림수산식품부

제출문 농림축산식품부장관귀하 이보고서를 펄스전기장과콜드플라즈마를이용한고품질고춧가루제조기술개발에관 한연구 과제의보고서로제출합니다. 2014 년 01 월 24 주관연구기관명 : 중앙대학교주관연구책임자 : 이동언협동연구기관명 : 서울여자대학교협동연구책임자 : 민세철협동연구기관명 : 괴산고추조합공동사업법인협동연구책임자 : 박영운

요약문 ➀ ➁ ➂ ➃ - 2 -

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μ μ μ - 4 -

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국문초록 Δ - 7 -

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ABSTRACT Δ - 9 -

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CONTENTS I. Introduction of research and development... 13 II. Situation of technical development in domestic and foreign... 16 III. Perform and Result of research and development... 20 A. Accelerated dehydration of red pepper using pulsed electric field treatment... 20 B. Pasteurization of red pepper powder using cold plasma... 69 IV. The attainment of goal and level of contribution of related part... 125 V. Outcome of research and development and plan to application of result... 128 VI. Reference... 130-11 -

목 차 제 1 장연구개발과제개요... 13 제 2 장국내외기술개발현황... 16 제 3 장연구개발수행내용및결과... 20 제 1 절펄스전기장 (PEF) 처리를이용한고추의신속건조기술개발... 20 제 2 절콜드플라즈마를이용한분말식품살균기술... 69 제 4 장목표달성도및관련분야에의기여도... 125 제 5 장연구개발성과및성과활용계획... 128 제 6 장참고문헌... 130-12 -

제 1 장연구개발과제의개요 ➀ ➁ ➂ ➃ - 13 -

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제 2 장 국내외기술개발현황 - 16 -

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대상국가특허 DB 검색기간검색범위 대한민국, 미국 WIPS 특허온라인검색최근 5년간제목및초록 개발기술명 펄스전기장을이용한식품의신속건조기술 콜드플라즈마를이용한분말식품살균기술 Cold plasma, non-thermal Keyword pulsed electric filed, drying plasma, food 검색건수 19 28 유효특허건수 0 5 핵심특허 및 관련성 특허명 - System and method for non-thermal plasma treatment of foodstuffs 보유국 - 미국 등록년도 - 2011 관련성 ( %) - 30 유사점 - Cold plasma pasteurization 차이점 - 처리장치및조건, 그리고대상식품 - 18 -

대상국가논문 DB 검색기간검색범위 미국, 일본, 유럽 Web of Science 최근 10년간제목, 초록및키워드 개발기술명 펄스전기장을이용한콜드플라즈마를이용한식품의신속건조기술분말식품살균기술 Keyword Pulsed electric field, Drying, Cold plasma, non-thermal plasma, Pepper food, treatment 검색건수 79 47 유효논문건수 3 11 논문명 Combined effects of pulsed Effect of atmospheric pressure electric field pre-treatment and plasma on inactivation of pathogens partial osmotic dehydration on air inoculated onto bacon using two drying behaviour of red bell different gas compositions. pepper 학술지명 JOURNAL OF FOOD ENGINEERING Food Microbiology 핵심논문 Kim B, Yun H, Jung S, Jung Y, 및저자 Ade-Omowaye BIO et al Jung H, Choe W, Jo C. 관련성게재년도 2003 2011 관련성 ( %) 60% 50% 유사점 PEF를이용한건조효율상승 식품에서의식중독균저해 차이점 Lab-scale의 Batch방식으로효과확인 식품의종류, 처리조건등 - 19 -

제 3 장 연구개발수행내용및결과 μ - 20 -

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Conductivity (S/m) Pulse frequency Treatment time (Hz) (s) 0.001 0.017 0.020 0.040 25 3 0.060 0.080 0.100 0.001 1 0.001 2 0.001 50 3 0.001 4 0.001 5 % power pulse width 10-80% 10, 20, 30 μs Field strength(kv/cm) Out voltage(%) Pluse width( μs ) Frequency(Hz) Time(second) 1 45 10 25 3 2 55 20 25 3 2.5 55 30 25 3-23 -

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exp exp exp exp - 27 -

Model no. Model name Model References 1 Newton exp Mujumdar (1987) 2 Page exp Page (1949) 3 Logarithmic exp Yagcioglu, Degirmencioglu, and Cagatay (1999) 4 Two term exp exp Henderson (1974) 5 Modified Henderson and exp exp exp Pabis Karathanos (1999) - 28 -

- 29 -

용수 Conductivity [S/m] 저수지 ( 경기도안성시고삼저수지 ) 0.014 지하수 1 ( 경기도안성시고삼면 ) 0.023 지하수 2 ( 경기도안성시당왕동 ) 0.017 수돗물 ( 경기도안성시대덕면 ) 0.017 증류수 0.001-30 -

Setting % power pulse width 10% 15% 20% 25% 30% 35% 40% 45% 50% 55% 60% 65% 70% Electric field strength (kv/cm) Peak Voltage (kv) Peak Current 10μs 0.2 1.4 2.1 20μs 0.3 2.6 2.1 30μs 0.4 3.1 2.1 10μs 0.3 2.3 2.1 20μs 0.5 4.1 2.1 30μs 0.6 4.8 2.1 10μs 0.4 3.3 2.1 20μs 0.7 5.6 2.1 30μs 0.8 6.6 2.1 10μs 0.5 4.1 2.1 20μs 0.9 7.1 2.1 30μs 1.0 8.3 2.1 10μs 0.6 5.0 2.2 20μs 1.1 8.7 2.2 30μs 1.3 10.1 2.3 10μs 0.7 5.9 2.5 20μs 1.3 10.2 2.5 30μs 1.5 11.9 2.5 10μs 0.9 6.9 2.9 20μs 1.5 11.8 3.0 30μs 1.7 13.7 2.8 10μs 1.0 7.9 2.2 20μs 1.7 13.3 3.4 30μs 1.9 15.4 3.5 10μs 1.1 8.7 4.1 20μs 1.9 14.8 4.2 30μs 2.2 17.2 4.2 10μs 1.2 9.6 4.9 20μs 2.0 16.3 4.9 30μs 2.4 19.0 5 10μs 1.3 10.6 5.7 20μs 2.2 17.9 5.7 30μs 2.6 20.7 5.9 10μs 1.4 11.4 6.6 20μs 2.4 19.4 6.6 27μs 2.8 22.5 6.8 10μs 1.5 12.3 7.4 20μs 2.6 20.9 7.5 25μs 2.9 23.3 7.5 (A) - 31 -

Setting % power pulse width 10% 15% 20% 25% 30% 35% 40% 45% 50% 55% 60% 65% 70% Electric field strength (kv/cm) Peak Voltage (kv) Peak Current 10μs 0.2 1.3 2.1 20μs 0.3 2.5 2.1 30μs 0.4 3.0 2.1 10μs 0.3 2.1 2.1 20μs 0.5 3.9 2.1 30μs 0.6 4.6 2.2 10μs 0.4 3.0 2.2 20μs 0.7 5.4 2.3 30μs 0.8 6.4 2.4 10μs 0.5 3.8 2.5 20μs 0.9 6.9 2.8 30μs 1.0 8.1 2.9 10μs 0.6 4.7 3.1 20μs 1.0 8.4 3.6 30μs 1.2 9.8 3.8 10μs 0.7 5.6 4.2 20μs 1.2 10.0 4.7 30μs 1.4 11.6 4.9 10μs 0.8 6.4 5.1 20μs 1.4 11.4 5.7 30μs 1.7 13.3 5.9 10μs 0.9 7.2 6.3 20μs 1.6 12.9 6.9 30μs 1.9 15.0 7.1 10μs 1.0 8.1 7.4 20μs 1.8 14.4 8.0 30μs 2.1 16.7 8.2 10μs 1.1 8.9 8.6 20μs 2.0 15.8 9.3 30μs 2.3 18.4 9.5 10μs 1.2 9.8 9.7 20μs 2.2 17.3 10.3 30μs 2.5 20.1 10.6 10μs 1.3 10.6 10.9 20μs 2.3 18.8 11.6 27μs 2.7 21.4 11.8 10μs 1.4 11.4 12.0 20μs 2.5 20.3 12.8 25μs 2.9 22.6 12.9 (A) - 32 -

Setting % power pulse width 10% 15% 20% 25% 30% 35% 40% 45% 50% 55% 60% 65% 70% Electric field strength (kv/cm) Peak Voltage (kv) Peak Current 10μs 0.2 1.3 2.1 20μs 0.3 2.5 2.1 30μs 0.4 3.0 2.1 10μs 0.3 2.1 2.1 20μs 0.5 4.0 2.2 30μs 0.6 4.6 2.2 10μs 0.4 2.9 2.3 20μs 0.7 5.4 2.4 30μs 0.8 6.3 2.6 10μs 0.5 6.3 2.8 20μs 0.9 6.9 3.2 30μs 1.0 8.0 3.4 10μs 0.6 4.6 3.6 20μs 1.0 8.4 4.2 30μs 1.2 9.8 4.5 10μs 0.7 5.4 5.0 20μs 1.2 9.8 5.5 30μs 1.4 11.5 5.7 10μs 0.8 6.3 6.1 20μs 1.4 11.3 6.8 30μs 1.6 13.2 6.9 10μs 0.9 7.2 7.3 20μs 1.6 12.8 8.0 30μs 1.9 14.9 8.4 10μs 1.0 8.0 8.6 20μs 1.8 14.3 9.2 30μs 2.1 16.6 9.5 10μs 1.1 8.8 9.9 20μs 2.0 15.8 10.6 30μs 2.3 18.3 10.8 10μs 1.2 9.7 11.1 20μs 2.2 17.2 11.9 30μs 2.5 20.0 12.1 10μs 1.3 10.5 12.4 20μs 2.3 18.7 13.2 27μs 2.7 21.3 13.4 10μs 1.4 11.2 13.7 20μs 2.5 20.2 14.7 25μs 2.8 22.5 14.6 (A) - 33 -

Setting % power pulse width Electric field strength (kv/cm) Peak Voltage (kv) Peak Current 10μs 0.1 1.2 2.1 10% 20μs 0.3 2.4 2.2 30μs 0.4 2.8 2.2 10μs 0.2 1.9 2.5 15% 20μs 0.5 3.7 2.8 30μs 0.5 4.4 3.0 10μs 0.3 2.7 3.8 20% 20μs 0.6 5.1 4.4 30μs 0.8 6.0 4.6 10μs 0.4 3.4 5.5 25% 20μs 0.8 6.5 6.2 30μs 1.0 7.6 6.7 10μs 0.5 4.2 7.1 30% 20μs 1.0 7.9 8.0 30μs 1.2 9.3 8.3 10μs 0.6 5.0 9.0 35% 20μs 1.2 9.4 9.8 30μs 1.4 10.9 10.2 10μs 0.7 5.8 10.8 40% 20μs 1.3 10.8 11.8 30μs 1.6 12.6 12.0 10μs 0.8 6.6 12.9 45% 20μs 1.5 12.2 13.8 30μs 1.8 14.2 14.2 10μs 0.9 7.3 14.8 50% 20μs 1.7 13.6 15.7 30μs 2.0 15.9 16.0 10μs 1.0 8.1 16.7 55% 20μs 1.9 15.0 17.7 30μs 2.2 17.6 18.2 10μs 1.1 9.0 18.9 60% 20μs 2.1 16.4 20.2 30μs 2.4 19.2 20.0 10μs 1.2 9.6 20.6 65% 20μs 2.2 17.9 21.9 27μs 2.5 20.4 22.7 10μs 1.3 10.5 22.6 70% 20μs 2.4 19.3 23.8 25μs 2.7 21.5 24.2 80% 22μs 2.9 23.0 26.2 (A) - 34 -

Setting % power pulse width 10% 15% 20% 25% 30% 35% 40% 45% 50% 55% 60% 65% 70% Electric field strength (kv/cm) Peak Voltage (kv) Peak Current 10μs 0.1 1.1 2.2 20μs 0.3 2.3 2.4 30μs 0.3 2.7 2.5 10μs 0.2 1.8 3.3 20μs 0.5 3.6 4.0 30μs 0.5 4.3 4.3 10μs 0.3 2.5 5.6 20μs 0.6 5.0 6.3 30μs 0.7 5.8 6.5 10μs 0.4 3.3 7.7 20μs 0.8 6.4 8.7 30μs 0.9 7.4 9.0 10μs 0.5 4.0 10.6 20μs 1.0 7.7 11.1 30μs 1.1 9.0 11.1 10μs 0.6 4.8 11.8 20μs 1.1 9.1 13.7 30μs 1.3 10.6 13.8 10μs 0.7 5.5 14.8 20μs 1.3 10.4 16.0 30μs 1.5 12.2 16.7 10μs 0.8 6.3 17.3 20μs 1.5 11.8 18.6 30μs 1.7 13.8 18.8 10μs 0.9 7.0 19.9 20μs 1.7 13.2 21.2 30μs 1.9 15.4 21.4 10μs 1.0 7.7 22.3 20μs 1.8 14.6 23.9 30μs 2.1 17.0 24.3 10μs 1.1 8.5 24.7 20μs 2.0 15.9 26.1 30μs 2.3 18.6 26.6 10μs 1.1 9.1 27.3 20μs 2.2 17.3 29.3 27μs 2.5 19.8 29.2 10 μs 1.2 9.9 29.4 20 μs 2.3 18.7 31.3 25 μs 2.6 20.9 32.1 80% 22 μs 2.8 22.4 37.0 (A) - 35 -

Setting % power pulse width 10% 15% 20% 25% 30% 35% 40% 45% 50% 55% 60% 65% 70% Electric field strength (kv/cm) Peak Voltage (kv) Peak Current 10μs 0.1 1.0 2.4 20μs 0.3 2.2 2.9 30μs 0.3 2.6 3.1 10μs 0.2 1.7 4.6 20μs 0.4 3.5 5.6 30μs 0.5 4.1 5.8 10μs 0.3 2.3 7.3 20μs 0.6 4.8 8.3 30μs 0.7 5.6 8.6 10μs 0.4 3.1 10.1 20μs 0.8 6.1 11.4 30μs 0.9 7.2 11.7 10μs 0.5 3.7 13.1 20μs 0.9 7.4 14.5 30μs 1.1 8.7 14.7 10μs 0.6 4.4 16.0 20μs 1.1 8.7 17.4 30μs 1.3 10.2 17.9 10μs 0.6 5.1 19.1 20μs 1.3 10.0 20.7 30μs 1.5 11.8 20.9 10μs 0.7 5.8 22.2 20μs 1.4 11.4 23.9 30μs 1.7 13.3 24.0 10μs 0.8 6.5 25.2 20μs 1.6 12.6 27.4 30μs 1.9 14.9 28.1 10μs 0.9 7.2 29.0 20μs 1.7 13.9 31.1 30μs 2.0 16.3 31.4 10μs 1.0 7.9 31.6 20μs 1.9 15.3 34.2 30μs 2.2 17.8 34.5 10μs 1.1 8.4 34.9 20μs 2.2 16.5 37.4 27μs 2.4 18.9 38.0 10 μs 1.2 9.2 37.4 20 μs 2.2 17.8 41.0 25 μs 2.5 20.0 41.0 80% 22 μs 2.7 21.4 47.0 (A) - 36 -

Setting % power pulse width 10% 15% 20% 25% 30% 35% 40% 45% 50% 55% 60% 65% 70% Electric field strength (kv/cm) Peak Voltage (kv) Peak Current 10μs 0.1 0.9 2.9 20μs 0.3 2.1 3.9 30μs 0.3 2.5 4.1 10μs 0.2 1.5 5.9 20μs 0.4 3.3 7.2 30μs 0.5 3.9 7.4 10μs 0.3 2.2 9.3 20μs 0.6 4.5 10.9 30μs 0.7 5.4 11.2 10μs 0.4 2.8 12.7 20μs 0.7 5.8 14.5 30μs 0.9 6.8 14.6 10μs 0.4 3.4 16.3 20μs 0.9 7.1 17.7 30μs 1.0 8.3 18.3 10μs 0.5 4.1 20.0 20μs 1.0 8.3 21.4 30μs 1.2 9.8 21.8 10μs 0.6 4.7 23.2 20μs 1.2 9.6 25.7 30μs 1.4 11.2 25.6 10μs 0.7 5.4 26.7 20μs 1.4 10.9 29.2 30μs 1.6 12.7 29.4 10μs 0.8 6.1 30.0 20μs 1.5 12.1 32.9 30μs 1.8 14.3 33.1 10μs 0.9 6.8 33.8 20μs 1.7 13.4 36.6 30μs 2.0 15.7 37.2 10μs 0.9 7.4 36.9 20μs 1.8 14.7 40.1 30μs 2.1 17.2 41.2 10μs 1.0 7.9 40.5 20μs 2.0 15.9 44.4 27μs 2.3 18.2 45.6 10 μs 1.1 8.6 44.2 20 μs 2.1 17.1 48.7 25 μs 2.4 19.2 49.0 80% 22 μs 2.6 20.4 59.1 (A) - 37 -

Setting % power pulse width 10% 15% 20% 25% 30% 35% 40% 45% 50% 55% 60% 65% 70% Electric field strength (kv/cm) Peak Voltage (kv) Peak Current 10μs 0.2 1.6 2.1 20μs 0.4 2.8 2.1 30μs 0.4 3.3 2.1 10μs 0.3 2.6 2.1 20μs 0.5 4.4 2.1 30μs 0.6 5.1 2.1 10μs 0.4 3.5 2.1 20μs 0.7 6.0 2.1 30μs 0.9 7.0 2.1 10μs 0.6 4.5 2.1 20μs 0.9 7.6 2.1 30μs 1.1 8.8 2.2 10μs 0.7 5.4 2.2 20μs 1.2 9.2 2.3 30μs 1.3 10.7 2.3 10μs 0.8 6.4 2.5 20μs 1.3 10.8 2.5 30μs 1.6 12.5 2.6 10μs 0.9 7.4 3.0 20μs 1.6 12.4 3.0 30μs 1.8 14.4 3.0 10μs 1.0 8.4 3.6 20μs 1.8 14.0 3.6 30μs 2.0 16.3 3.6 10μs 1.2 9.3 4.2 20μs 2.0 15.6 4.2 30μs 2.3 18.1 4.3 10μs 1.3 10.3 4.9 20μs 2.2 17.2 4.9 30μs 2.5 19.9 5.0 10μs 1.4 11.3 6.0 20μs 2.3 18.8 6.0 30μs 2.7 21.8 6.0 10μs 1.5 12.2 6.6 20μs 2.6 20.4 6.7 27μs 2.9 23.2 6.8 10 μs 1.6 13.2 7.4 20 μs 2.7 22.0 7.4 25 μs 3.0 24.3 7.4 80% 22 μs 3.3 26.2 9.3 (A) - 38 -

Setting % power pulse width 10% 15% 20% 25% 30% 35% 40% 45% 50% 55% 60% 65% 70% Electric field strength (kv/cm) Peak Voltage (kv) Peak Current 10μs 0.2 1.5 2.1 20μs 0.3 2.8 2.1 30μs 0.4 3.3 2.1 10μs 0.3 2.5 2.1 20μs 0.5 4.3 2.1 30μs 0.6 5.1 2.1 10μs 0.4 3.5 2.1 20μs 0.7 5.9 2.1 30μs 0.9 6.9 2.1 10μs 0.6 4.4 2.1 20μs 0.9 7.5 2.2 30μs 1.1 8.7 2.2 10μs 0.7 5.4 2.3 20μs 1.1 9.1 2.3 30μs 1.3 10.6 2.3 10μs 0.8 6.3 2.6 20μs 1.3 10.7 2.6 30μs 1.6 12.4 2.6 10μs 0.9 7.3 3.1 20μs 1.6 12.3 3.1 30μs 1.8 14.3 3.2 10μs 1.0 8.3 3.7 20μs 1.7 13.9 3.8 30μs 2.0 16.1 3.8 10μs 1.2 9.2 4.5 20μs 1.9 15.5 4.5 30μs 2.2 17.9 4.5 10μs 1.3 10.2 5.2 20μs 2.1 17.0 5.2 30μs 2.5 19.8 5.3 10μs 1.4 11.1 6.1 20μs 2.3 18.6 6.1 30μs 2.7 21.6 6.2 10μs 1.5 12.1 6.9 20μs 2.5 20.2 6.9 27μs 2.9 23.0 6.9 10 μs 1.6 13.0 7.0 20 μs 2.7 21.7 7.7 25 μs 3.0 24.2 7.7 80% 22 μs 3.2 26.0 9.4 (A) - 39 -

Setting % power pulse width 10% 15% 20% 25% 30% 35% 40% 45% 50% 55% 60% 65% 70% Electric field strength (kv/cm) Peak Voltage (kv) Peak Current 10μs 0.2 1.6 2.1 20μs 0.4 2.8 2.1 30μs 0.4 3.3 2.1 10μs 0.3 2.6 2.1 20μs 0.5 4.4 2.1 30μs 0.6 5.1 2.1 10μs 0.4 3.5 2.1 20μs 0.7 6.0 2.1 30μs 0.9 6.9 2.1 10μs 0.6 4.4 2.1 20μs 0.9 7.5 2.2 30μs 1.1 8.8 2.2 10μs 0.7 5.4 2.3 20μs 1.1 9.1 2.4 30μs 1.3 10.6 2.4 10μs 0.8 6.4 2.7 20μs 1.3 10.7 2.7 30μs 1.5 12.4 2.7 10μs 0.9 7.3 3.3 20μs 1.5 12.3 3.3 30μs 1.8 14.2 3.3 10μs 1.0 8.3 3.9 20μs 1.7 13.9 4.0 30μs 2.0 16.0 4.0 10μs 1.2 9.2 4.7 20μs 1.9 15.4 4.7 30μs 2.2 17.9 4.8 10μs 1.3 10.2 5.5 20μs 2.1 17.0 5.5 30μs 2.5 19.7 5.6 10μs 1.4 11.1 6.3 20μs 2.3 18.6 6.4 30μs 2.7 21.5 6.4 10μs 1.5 12.1 7.1 20μs 2.5 20.2 7.2 27μs 2.9 22.9 7.2 10 μs 1.6 13.0 8.0 20 μs 2.7 21.7 8.0 25 μs 3.0 24.1 8.0 80% 22 μs 3.2 25.9 9.7 (A) - 40 -

Setting % power pulse width 10% 15% 20% 25% 30% 35% 40% 45% 50% 55% 60% 65% 70% Electric field strength (kv/cm) Peak Voltage (kv) Peak Current 10μs 0.2 1.6 2.1 20μs 0.4 2.8 2.1 30μs 0.4 3.3 2.1 10μs 0.3 2.6 2.1 20μs 0.5 4.4 2.1 30μs 0.6 5.1 2.1 10μs 0.4 3.5 2.1 20μs 0.7 6.0 2.1 30μs 0.9 6.9 2.1 10μs 0.6 4.5 2.2 20μs 0.9 7.5 2.2 30μs 1.1 8.7 2.2 10μs 0.7 5.4 2.3 20μs 1.1 9.1 2.4 30μs 1.3 10.6 2.4 10μs 0.8 6.4 2.7 20μs 1.3 10.7 2.7 30μs 1.5 12.4 2.7 10μs 0.9 7.3 3.3 20μs 1.5 12.3 3.3 30μs 1.8 14.2 3.3 10μs 1.0 8.3 4.0 20μs 1.7 13.9 4.0 30μs 2.0 16.0 4.0 10μs 1.1 9.2 4.7 20μs 1.9 15.4 4.8 30μs 2.2 17.9 4.8 10μs 1.3 10.2 5.5 20μs 2.1 17.0 5.6 30μs 2.5 19.7 5.6 10μs 1.4 11.1 6.3 20μs 2.3 18.6 6.4 30μs 2.7 21.5 6.4 10μs 1.5 12.1 7.1 20μs 2.5 20.2 7.2 27μs 2.9 22.9 7.2 10 μs 1.6 13.0 8.0 20 μs 2.7 21.7 8.0 25 μs 3.0 24.1 8.0 80% 22 μs 3.2 25.8 9.7 (A) - 41 -

Setting % power pulse width 10% 15% 20% 25% 30% 35% 40% 45% 50% 55% 60% 65% 70% Electric field strength (kv/cm) Peak Voltage (kv) Peak Current 10μs 0.2 1.6 2.1 20μs 0.4 2.8 2.1 30μs 0.4 3.3 2.1 10μs 0.3 2.5 2.1 20μs 0.5 4.4 2.1 30μs 0.6 5.1 2.1 10μs 0.4 3.5 2.1 20μs 0.7 5.9 2.1 30μs 0.9 6.9 2.1 10μs 0.6 4.4 2.2 20μs 0.9 7.5 2.2 30μs 1.1 8.7 2.2 10μs 0.7 5.4 2.3 20μs 1.1 9.1 2.3 30μs 1.3 10.5 2.4 10μs 0.8 6.3 2.7 20μs 1.3 10.7 2.7 30μs 1.5 12.3 2.7 10μs 0.9 7.3 3.2 20μs 1.5 12.2 3.3 30μs 1.8 14.2 3.3 10μs 1.0 8.2 3.9 20μs 1.7 13.8 4.0 30μs 2.0 16.0 4.0 10μs 1.1 9.2 4.7 20μs 1.9 15.4 4.7 30μs 2.2 17.8 4.8 10μs 1.3 10.1 5.5 20μs 2.1 16.9 5.5 30μs 2.5 19.6 5.5 10μs 1.4 11.1 6.3 20μs 2.3 18.5 6.3 30μs 2.7 21.4 6.4 10μs 1.5 12.0 7.1 20μs 2.5 20.0 7.1 27μs 2.8 22.8 7.2 10 μs 1.6 12.9 7.9 20 μs 2.7 21.6 7.9 25 μs 3.0 23.9 8.0 80% 22 μs 3.2 25.8 9.6 (A) - 42 -

Control 1kv/cm 2kv/cm 2.5kv/cm 4 3 2 1 0 0 2 4 6 8 Time(h) - 43 -

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Control 1KV/cm 1.5KV/cm 2KV/cm 80 2.5KV/cm 60 40 20 0 0 5 10 15 20 25 30 Time(hour) Field strength(kv/cm) Out voltage(%) Pulse width(µs) Frequency(Hz) Time(second) 1 25 30 25 3 1.5 35 30 25 3 2 55 20 25 3 2.5 65 20 25 3-48 -

control 80 1.5KV/cm 2.5KV/cm 60 40 20 0 0 5 10 15 20 25 30 Time(hour) Field strength(kv/cm) Out voltage(%) Pulse width(µs) Frequency(Hz) Time(second) 1 25 30 25 3 1.5 35 30 25 3 2.5 65 20 25 3-49 -

control 80 second 1 second 3 second 5 60 40 20 0 0 5 10 15 20 25 30 Time(hour) Field strength(kv/cm) Out voltage(%) Pulse width(µs) Frequency(Hz) Time(second) 2.5 55 30 50 1 2.5 55 30 50 3 2.5 55 30 50 5-50 -

control second 1 second 3 second 5 80 60 40 20 0 0 5 10 15 20 25 Time(hour) Field strength(kv/cm) Out voltage(%) Pulse width(µs) Frequency(Hz) Time(second) 2.5 55 30 50 1 2.5 55 30 50 3 2.5 55 30 50 5-51 -

control second 1 second 3 second 5 80 60 40 20 0 0 5 10 15 20 25 30 Time(hour) Field strength(kv/cm) Out voltage(%) Pulse width(µs) Frequency(Hz) Time(second) 2.5 55 30 50 1 2.5 55 30 50 3 2.5 55 30 50 5-52 -

control second 1 second 3 second 5 80 60 40 20 0 0 5 10 15 20 25 30 Time(hour) Field strength(kv/cm) Out voltage(%) Pulse width(µs) Frequency(Hz) Time(second) 2.5 55 30 50 1 2.5 55 30 50 3 2.5 55 30 50 5-53 -

Field strength(kv/cm) Out voltage(%) Pluse width( μs ) Frequency(Hz) Time(second) 1 25 30 25 3 1.5 35 30 25 3 2 55 20 25 3 2.5 65 20 25 3-54 -

Drying rate (kg water/kg dry solid.hour) control kv/cm 1 kv/cm 1.5 kv/cm 2 control kv/cm 1 kv/cm 1.5 kv/cm 2 1.0 2.5 kv/cm 0.8 0.6 0.4 0.2 0.0 0 2 4 6 8 Time(h) 1.0 0.8 0.6 0.4 0.2 2.5 kv/cm 0.0 0 1 2 3 4 5 6 7 content (kg water/kg dry solid) Moisture - 55 -

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Field strength(kv/cm) Out voltage(%) Pluse width( μs ) Frequency(Hz) Time(second) 2.5 55 30 100 1 2.5 55 30 100 2 2.5 55 30 100 4 2.5 55 30 200 1 2.5 55 30 200 2 2.5 55 30 200 4-58 -

Drying rate (kg water/kg dry solid.hour) Control 1 Second 100Hz 2 Second 100Hz 4 Second 100Hz Control 1 Second 100Hz 2 Second 100Hz 4 Second 100Hz 1.0 0.8 0.6 0.4 0.2 0.0 0 2 4 6 8 10 Time(h) 2.5 2.0 1.5 1.0 0.5 0.0 0 1 2 3 4 5 content (kg water/kg dry solid) Moisture - 59 -

Drying rate (kg water/kg dry solid.hour) Control 1 Second 200Hz 2 Second 200Hz 3 Second 200Hz Control 1 Second 200Hz 2 Second 200Hz 4 Second 200Hz 1.0 0.8 0.6 0.4 0.2 0.0 0 2 4 6 8 10 Time(h) 3.0 2.5 2.0 1.5 1.0 0.5 0.0 0 1 2 3 4 content (kg water/kg dry solid) Moisture - 60 -

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Field strength(kv/cm) Out voltage(%) Pluse width( μs ) Frequency(Hz) Time(second) 2.5 55 30 100 2 2.5 55 30 200 2-62 -

Drying rate (kg water/kg dry solid.hour) Control 2 Second 100Hz Control 2 Second 100Hz 1.0 200Hz 2 Second 0.8 0.6 0.4 0.2 0.0 0 1 2 3 4 5 6 7 Time(h) 3.5 3.0 2.5 2.0 1.5 1.0 0.5 0.0 200Hz 2 Second 0 1 2 3 4 content (kg water/kg dry solid) Moisture - 63 -

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Model Newton Page Logarithmic Two term Frequency Treatment Model constants R 2 MBE RMSE EMD (Hz) time (s) 100 = 0.5178 0.9986 0.04065 0.046341 66.47540 2 200 = 0.6704 0.9953-0.03735 0.061917 28.32854 100 = 0.6008, = 1.1506 0.9999-0.02813 0.035760 14.67760 2 200 = 0.8564, = 1.2100 0.9998-0.03890 0.048941 18.44536 100 = 0.6196, = 1.0346, = -0.0283 0.9989-0.02861 0.036564 10.92562 2 200 = 0.6188, = 1.0436, = -0.0342 0.9976-0.03912 0.053419 13.52020 100 = 0.6696, = 0.5057, = 0.5057 0.9976-0.02694 0.04194 19.70268 2 200 = 0.6787, = 0.5076, = 0.5076 0.9956-0.03685 0.060179 27.05147 Modified Henderson and Pabis 100 200 2 = 0.5146, = 0.8711, = 0.8711, = -0.7372, = 0.5136, = 0.3699 = 0.6777, = 0.2554, = 0.2554, = 0.5044, = 0.6777, = 0.6796 0.9993-0.02921 0.035775 13.19808 0.9956-0.03683 0.060161 27.06114-66 -

μ - 67 -

Treatment time (s) L*-value a*-value b*-value E ASTA Control 49.91±0.40 1)a2) 30.79±0.32 a 22.85±0.47 a 0 136.94±0.32 a 100 Hz 2 50.72±0.14 b 29.67±0.14 b 25.98±0.49 c 3.42 151.12±0.72 b 200 Hz 2 50.76±0.43 b 29.36±0.37 b 24.45±0.63 b 2.30 152.52±0.40 c - 68 -

제 2 절 콜드플라즈마를이용한분말식품살균기술 Ÿ Ÿ Ÿ Ÿ Ÿ Ÿ Ÿ Ÿ Ÿ Ÿ Ÿ Ÿ - 69 -

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제 4 장목표달성도및관련분야의기여도 - 125 -

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제 5 장연구개발성과및성과활용계획 - 128 -

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제 6 장참고문헌 - 130 -

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주 의 이보고서는농림축산식품부에서시행한고부가가치식품기술개발사업연구 보고서입니다 이보고서내용을발표할때에는반드시농림축산식품부에서시행한고부 가가치식품기술개발사업의연구결과임을밝혀야합니다 국가과학기술기밀유지에필요한내용은대외적으로발표또는공개하여서는 아니됩니다