National October 7, 2015 (Wed) (For Industrial Water & Wastewater Treatment) Chang-Han Yun / Ph.D.
Contents 1. Membrane Market in 1998 2. 산업용폐수에서막분리공정시장분석 Contents Contents 3. 산업용폐수용막종류별시장분석 4. 산업용폐수처리시장에서막분리공정필요사유 5. 국가별막분리공정시장의매력도및진입장벽 2
1. Membrane Market in 1998 세계시장 (1998 년 ) : 4.4 billion USD( 약 5.3 조원 ) 장비및장치포함 : 8.8 billion USD( 약 10.6 조원 ) 1. 지역별시장 USA : 40% EU & Middle East : 29% Other(Asia & South America) : 31% 2. 막종류별시장 Filtration(RO+UF+MF) : 1.8 billion USD( 약 2.2조원 ) RO/NF : 0.4 billion USD( 약 4,800억원 ) UF : 0.5 billion USD( 약 6,000억원 ) MF : 0.9 billion USD( 약 1.1조원 ) Hemodialysis : 2.2 billion USD( 약 2.6조원 ) Gas Separation : 0.23 billion USD( 약 2,760억원 ) ED : 0.18 billion USD( 약 2,160억원 ) Pervaporation : 0.026 billion USD( 약 312억원 ) Non-separating membrane : 2.8 billion USD( 약 3.4조원 ) <Figure 3-6> Membrane and module sale for different process application in 1998 3
2. 산업용폐수에서막분리공정시장분석 1. 산업용폐수처리에서의막분리공정시장 8.2%/yr(2008년이전 ) 13%/yr (2008년이후 ) $2.3 billion in 2008 $5.5 billion in 2015 RO & NF 시장점유율 : 40%(at 2008) MF 증가율 : 15%/yr through 2015 산업폐수처리에 MF 공정을응용 13%/yr 8.2%/yr 4
2. 산업용폐수에서막분리공정시장분석 2. 지역별시장분석 미국시장점유율 : 40% Asia Pacific 에서의급속한시장점유율증가 Asia-Pacific 시장 : 17%/yr 증가예상 점유율 : 22% in 2008 29% in 2015 Others 5% 지역 시장 mi $ 2008 2015( 예상 ) 점유율 (%) mil $ 점유율 (%) USA 937 39.8 1,816 33.0 EU 780 33.1 1,853 33.7 Asia-Pacific 527 22.4 1,608 29.2 Others 109 4.6 223 4.1 Others 4% Asia-Pacific 22% 2008 년 (2.3 bil $) US 40% Asia-Pacific 29% 2015 년 (5.5 bil $) US 33% EU 33% EU 34% <Figure 3-1> Regional market analysis 5
3. 산업용폐수용막종류별시장분석 RO/NF 시장점유율 39%(919 mil $) in 2008 <Figure 3-2> Global MBR market for IW & WW 36%(1,964 mil $) in 2015 MF 시장점유율 37%(861 mil $) in 2008 43%(2,347 mil $) in 2015 MF 증가율 : 15%/yr through 2015 산업폐수처리에 MF 공정을응용 막 USA EU Asia-Pacific Other Area 2008 2015( 예상 ) 2008 2015( 예상 ) 2008 2015( 예상 ) 2008 2015( 예상 ) mil. $ % mil. $ % mil. $ % mil. $ % mil. $ % mil. $ % mil. $ % mil. $ % RO/NF 403 43 696 38 295 38 677 37 179 34 511 32 42 38 80 36 UF 205 22 380 21 208 27 387 21 134 25 375 23 27 25 48 22 MF 329 35 740 41 277 36 789 43 214 41 722 45 41 37 96 43 Total 937 100 1,816 100 780 100 1,853 100 527 100 1,608 100 109 100 223 100 6
3. 산업용폐수용막종류별시장분석 전세계적으로산업폐수방류수에대한규제가크게강화 이에따른산업폐수처리를위한 MBR(Membrane Bio-Reactor) 적용사례가크게증가 <Figure 3-3> 지역별및막종류별시장변화분석 <Figure 3-4> 지역별및막종류별시장증가율변화분석 7
4. 산업용폐수처리시장에서막분리공정필요사유 1. 산업응용분야 Boiler 수처리 냉각수처리 3. 물의경제적가치증가 (Water Supplying) 물수요와공급의불균형 저가의상품인물단가의지속적인상승 물의경제적가치상승 세척 제조 폐수처리 인구의증가 산업화의가속화 자원의과잉개발 전세계적인물위기상황을유도할가능성커짐. 2. 주요응용산업 원유정제 화학및석유화학 반도체 식품 & 음료 의약품 4. 산업용폐수처리시장 (Wastewater Treatment and Discharge) 산업에서의폐수처리후방류는비용발생으로생각 경쟁사와의경쟁도구로서의폐수재이용에대한인식전환 막분리공정에기초한처리시설의성장속도 >> 기존처리방법의성장속도 방류규제의강화 시설의부지 물부족과단가상승 물재이용필요 8
4. 산업용폐수처리시장에서막분리공정필요사유 5. 막분리공정의경쟁력향상 R&D 증가 기술발전 수요의증가 시장의확대 Membrane Module 단가의하락 (2000 년이후로 30~40% 의단가하락 ) 제품의개선 생산성향상과수명의증가 전체적인비용감소 소비자의관심을유도 향후예측수요의지속적증가 생산규모의확대 Membrane Module의단가하락을가속 6. 막분리공정의위험요소 (Membrane Fouling) Membrane Fouling Membrane의처리용량감소 Membrane의가치하락 막분리기술보급의가장큰저해요소 막분리공정에친숙치않은운전및유지관리 인적자원이부족한 S&M 산업으로의낮은보급율 S&M 산업에서의 Customized membrane system 요구 공정가격상승 재정적문제 9
5. 국가별막분리공정시장의매력도및진입장벽 1. 막분리공정의진입장벽 재정적여건 인적자원의확보가능성 기술적자원의확보가능성 기타 Infrastructure 시설의여건 2. 2000년대의주요소비국가 India, Brazil, Poland, Australia 사유 Market 매력도 ( 큰잠재적수요 ) - Project 투자계획에대한발표 경제력의증가및정치적의지 - 물과폐수방류규제천명 낮은시장진입장벽 <Figure 3-5> Market assessment based on market attractiveness and ease of entry 10
Question and Answer Contact Dr. Chang-Han Yun E-mail : changhanyun@hanmail.net Mobile : 010-288-2250 11
National October 7, 2015 (Wed) Chapter 4. Various Particle Filters and Application Chang-Han Yun / Ph.D.
Contents 1. Comparison of Various PF Contents Contents 2. Operation Principle Gravity Type 3. Operation Principle Pressure Type 4. Pore Controllable Fiber (PCF) Filter 13
1. Comparison of Various Particle Filter (PF) Commercial Name Particle Filter Filtering Filtration Media SS Principle Inorganic Polymer Rejection(%) PDF(Poly Disk Filter) : Paper Ind. Surface Filter (Screen Filter) Automatic Self-cleaning Filters (Amiad Co.) MDF(Multi Disk Filter) Thread Filter 30 ~ 60 Algas Filter Depth Filter Slow Sand Filter(SSF) Rapid Sand Filter(RSF) Dual-Media Filter(DMF) Multi-Media Filter(MMF) Fiber Filter - GFF(Gravity Flow Fiber) - PCF(Pore Controllable Fiber) 60 ~ 80 14
1. Comparison of Various Particle Filter (PF) Comparison 구분 직사각판형 (GFF) 원통판형 (MDF) 원통형 ( PCF) 원판형 (RSF) 형상 여과면 면적 40m 2 (100 %) 29.44m 2 (74 %) 12.56m 2 (31 %) 3.14m 2 (8 %) 용도 For low SS rejection and bulk treatment - Tertiary Treatment of STP or WWTP - T-P removal with coagulation For high SS rejection - Tertiary Treatment of STP or WWTP - T-P removal with coagulation - Water Treatment Plant(WTP) 15
2. Operation Principle - Gravity Type GFF 16
2. Operation Principle - Gravity Type MDF 17
3. Operation Principle Pressure Type PCF 여과시작여과종료역세시작 Backwash Water Air 18
4. Pore Controllable Fiber (PCF) Filter Shape Filtration Backwash 19
4. Pore Controllable Fiber (PCF) Filter Size Comparison with Sand Filter <PCF Filter> Items PCF Rapid Sand Filter Filtration Area Side of Cylinder (πdf h) Cross Section (πd 2 /4) Capacity(m 3 /d) 1,200 1,200 <Rapid Sand Filter> Velocity(m/hr) Filtration Area(m 2 ) Size(mm) 11.4 4.4 860Φ 2,250H 12.5 4.0 2,260Φ 3,000H Volume(m 3 ) 1.3 (1.0) 12.0 (9.2) Area need(m 2 ) 0.74 (1.0) 5.1 (6.9) 20
C C 3. Double stage PCF Filter Process - DCoF PFD PAC FI #1 Coagulation C C Tu ST ST Tu In-line Mixer In-line Mixer Backwash Concentrate Out Air C Feed Initial Filtrate Recirculation Tu C C C Blower Filtrate Out Filtrate Tank FI #2 Coagulation Backwash Pump Air 21
3. Double stage PCF Filter Process - DCoF Multi Array Filtration Feed 1.5 bar 2 nd Filtrate 0.3 bar Backwash Feed 1.5 bar (Mobile Type) 2 nd Filtrate 0.3 bar Backwash Feed 1.5 bar (Plant Type) 2 nd Filtrate 0.3 bar Conc. 0.1 bar Conc. 0.1 bar Air Conc. 0.05 bar Air 22
Feed Water Turbidity(NTU) 4. Small Scale DCoF System - Plant Type Feed Water Malaysia(75 m 3 /d) Shah Alam 10,000 8,000 6,000 Samples were analyzed by SL WTP hourly Feed Water Turbidity Average : 323.1 NTU 4,000 2,000 Sungai Langat(SL) WTP 0 3/1 3/11 3/21 3/31 4/10 4/20 4/30 Date(1 March 30 April, 2010) Sungai Langat(SL) WTP Raw Water( Ultra High Turbidity) Average : about 300 NTU Maximum : more than 10,000 NTU Other South East Asia : less than 3,000 NTU Korea : less than 1,000 NTU 23
Filtrtae Turbidity(NTU) 4. Small Scale DCoF System - Plant Type Filtrate Small Scale DCoF-WTP Malaysia(75 m 3 /d) 6 5 DCOF SL WTP SL WTP : 1.00 NTU DCOF Pilot : 0.36 NTU 4 3 2 1 0 3/1 3/11 3/21 3/31 4/10 4/20 4/30 Date(1 March 30 April, 2010) Sungai Langat(SL) WTP Filtrate Turbidity of DCoF : 36 % of SL WTP DCoF-WTP : 0.36 NTU Sungai Langat(SL) WTP : 1.00 NTU 24
8% Alum Dose(ppm) 4. Small Scale DCoF System - Plant Type Malaysia(75 m 3 /d) Coagulant Dose 100 80 DCOF SL WTP SL WTP : 27.75 ppms DCOF Pilot : 16.74 ppms(60% of SL WTP) 60 40 20 0 3/1 3/11 3/21 3/31 4/10 4/20 4/30 Date(1 March 30 April, 2010) Coagulant Dose of DCoF : 60.3% of SL WTP DCoF: 16.74 ppms of 8% Alum Sungai Langat(SL) WTP : 25.75 ppms of 8% Alum 25
Question and Answer Contact Dr. Chang-Han Yun E-mail : changhanyun@hanmail.net Mobile : 010-288-2250 26