/ KEIT PD / SUMMARY 4 3D First mover 3D 3D ( 13) 3D, 3D 34, 3D, 3D, 3D,,,
KEIT PD Issue Report PD ISSUE REPORT AUGUST 2015 VOL 15-8 1. 3D? (Ceramics),.,, 4 70.,,,,,,,.,.?.. ( ) ( 1)., (), 3.,.,,., ( 80%). 1 3D?, 3 2 3D, (layer-by-layer) 3 3D.?, 3. 30 3D, 3D. 100 한국산업기술평가관리원
ISSUE 6 세라믹 3D 프린팅기술현황과육성전략 1 3D 3D? 3D? 3 3D 3D, 3D 3 3., 3D 3 3D. 3D. 3D. 3D, 3D 3D. 2014 3, 3D, 3D., 2015 MRS Bulletin 3D 3D ( 2). 2-4 Korea Evaluation Institute of Industrial Technology 101
KEIT PD Issue Report PD ISSUE REPORT AUGUST 2015 VOL 15-8 2. 3D ( American Ceramic Society Bulletin (2014.4), Ceramics Japan (2014.10), MRS Bulletin (2015. 2) 3D? 3D. 5-7 3D,., 3D., 3D 3D 3D first mover. 2. 3D 3D! 3D 1990 3D. 3D ASTM F2792-12a ( 3). 102 한국산업기술평가관리원
ISSUE 6 세라믹 3D 프린팅기술현황과육성전략 3D (ASTM) (O) / (X) Binder Jetting (BJ) X () X X ZrO 2, Al 2 O 3, HA, TCP, Bioglass, Ti 3 SiC 2, Si 3 N 4, TiC-TiO 2, SiC, BaTiO 3, PZT,TiO 2, LSMO/YBCO 3DP Material Extrusion (ME) X () X X ZrB 2, Al 2 O 3, Mullite, SiC, ZrO 2, WC-ZrO 2, Zrc, Al 2 0 3 - ZrO 2, HA, TCP, Porcelain, Bioglass, HA-TCP, BaTiO 3, PZT, PMN, LeFePO 4, Li 4 Ti 5 O 12, BaZrO 3, SrTiO 3 FDM, PED, EFF Photo Polymerization (PP), () X X X HA, HA-Al 2 O 3, TCP, SiC, Al 2 O 3, Al 2 O 3 -ZrO 2, Al 2 O 3 -SiO 2, SiO 2, TiO 2, Al 2 O 3 / SiO 2 /Mullite/ZrSiO 4, PZT, Fe 2 O 3 /Fe(C 2 O 4 ), 2H 2 OBi(V X NB 1-X )O 4, SiCN SLA, DLP Powder Bed Fusion (PBF) ( ) X X X HA-Mullite, BCP, ZrO 2, HA-wollastonite, Peek-HA, HA-PA, Al 2 O 3 -SiO 2, TiC-Al 2 O 3, SiC, PZT, BaTiO 3 SLS SLM Sheet Lamination, () X X X HA/TCP, Al 2 O 3, ZrO 2, SiC/C, PE-glassy fiber, Si 3 N 4, SiO 2, TiC/Ni, LZSA-Glass PZT LOM 3 3D (binder jetting, BJ), FDM (fused deposition modeling) PED (paste extruding deposition) (material extrusion, ME), SLA (stereolithography) DLP (disital light processing) (photo polymerization, PP). Korea Evaluation Institute of Industrial Technology 103
KEIT PD Issue Report PD ISSUE REPORT AUGUST 2015 VOL 15-8 3D! 3D 3D 3D., 3D., 3D.,. 3D 3D. 1990 MIT E. Sachs 3 3D. 8,,, 3. (, ) (, ),. 4 3D (1990, MIT). TCP (tri-calcium phosphate) 104 한국산업기술평가관리원
ISSUE 6 세라믹 3D 프린팅기술현황과육성전략, 3 (>1200 C).. TCP., TCP 3 50%. 9 3D. 5 9 (preceramic), 3 PED, extrusion free forming, slurry deposition, dispense plotting, bioplotting, robocasting., 3D. 3D., FDM, 3 3D, 3... 3 Korea Evaluation Institute of Industrial Technology 105
KEIT PD Issue Report PD ISSUE REPORT AUGUST 2015 VOL 15-8... 3.,,,,,,. 6 3D SiC () PZT () 5 ; SLA, DLP 3 1986 Hull. 1996 Griffith,, 3, 3, 1550 C. 10 3D. 3D., Vat, ( 7).,,.,,,. 106 한국산업기술평가관리원
ISSUE 6 세라믹 3D 프린팅기술현황과육성전략 ( 2D ) X 3D 7 3D 6.,, 3. 3D.. 3D,,.. 3D 3D 3D., 3D (template). ( 8 ()) 11 3D (~3, ~1, Prodways ).. 3 3D. 8 () 2, 5, 12. Korea Evaluation Institute of Industrial Technology 107
KEIT PD Issue Report PD ISSUE REPORT AUGUST 2015 VOL 15-8 8 (. ) (. ; turbine engine component, aerospace fuel pump shaft, microwave-guides bone substitute) 9 3D 108 한국산업기술평가관리원
ISSUE 6 세라믹 3D 프린팅기술현황과육성전략 ; SLS, SLM 1986, Texas Deckard IR, 3, 1992 (,, ). 13 3..,.,. 14 9 SLM. 3D 3 ( 10). 10 SLS 3D 5, 16 ( YSZ, alumina, porcelain) Sheet lamination Laminated object manufacturing (LOM), 1986 Helisys Co.. 1994 Griffin pre-ceramic sheet lamination 3. 16 3. 3D,.,,, Korea Evaluation Institute of Industrial Technology 109
KEIT PD Issue Report PD ISSUE REPORT AUGUST 2015 VOL 15-8,. SiC, SiC-fiber-SiC, Al, Si 3 N 4, HA TiC/Ni ( 11). 11 Sheet lamination Si-SiC gear wheel 17 3. 3D, Frost & Sullivan 2014 3D,.,,. 3D. 3D DIY (do-it-yourself) high-end. 3D. 3D 3D. 3D, 3. 110 한국산업기술평가관리원
ISSUE 6 세라믹 3D 프린팅기술현황과육성전략.,,,. 3D. Argillasys 3D printed ceramics 3D, 3D systems 3D. Unfold (http://unfold.be) 3D, 3D. 12 3D 3D high-end. 3D,. Frost & Sullivan, 3D 16% 2020 3D 25%. 12, 2020 Top3 3D, 10 2 8 3,. 18 ( ) 3D 4, 19-21., 3D., 3D Korea Evaluation Institute of Industrial Technology 111
KEIT PD Issue Report PD ISSUE REPORT AUGUST 2015 VOL 15-8 3D.,,. 3D Lithoz Prodways. 22, Prodways 3D 3D Ceram, FCP ( 13) 23. NEXT21 3D,, CT-Bone' Xilloc. 24 (KIMS) 2006 3D,,,,. 13 3D (FCP: France, CaP, Zirconia, Alumina; NEXT21: Japan, CaP; KIMS: Korea, CaP, Zirconia, Alumina) 12, 22 112 한국산업기술평가관리원
ISSUE 6 세라믹 3D 프린팅기술현황과육성전략 Sand casting mold & core, 3D,. Stratasys, CNC 60% 37~62%. ExOne (1,800 1,000 700mm) patternless sand casting & core S-Max ( 14),. 25,.. 14 3D (ExOne) 23 2014 WINSUN 3D, 6 5. 26 3D, 60%, 70%, 80%. WINSUN Korea Evaluation Institute of Industrial Technology 113
KEIT PD Issue Report PD ISSUE REPORT AUGUST 2015 VOL 15-8 3D, 3D, 2.. 3D. 15 3D () (),,,, 3D.,.. 3D. 3D,. 28,. 29 114 한국산업기술평가관리원
ISSUE 6 세라믹 3D 프린팅기술현황과육성전략 Print 16 3D (:, :,.,.,. aerospatiale and aeronautic core 4. 3D 1990 rapid prototyping (RP). prototyping additive manufacturing (AM) 2014., 30 3D 3D. 3D ( 17). 3D. 3D 3D.,,. 3D, full-set. 3D (Alumina: 190/ kg (Lithoz), 93/kg (Prodways)). Korea Evaluation Institute of Industrial Technology 115
KEIT PD Issue Report PD ISSUE REPORT AUGUST 2015 VOL 15-8 17 3D (, 2014) 30 3D DIY high-end,. Lithoz (CeraFab 7500), Prodways (ProMaker V4000), Formatec (ADMATEC 80)., Lithoz Formatec 3D. Prodways 3D Ceram,, FCP. Lithoz Prodways. 4. NEXT21 3D, 3D. NEDO,,. SLS Phenix systems. TNO NASA Aeronautics research institute preceramic 116 한국산업기술평가관리원
ISSUE 6 세라믹 3D 프린팅기술현황과육성전략 SiSiC. PZT. 3D. 3D. 3D. 3D,. 3D, 2006 3D,,. 3D 3D 3D., 3D. 5. 3D First mover!. first mover., first mover. 3D. 3D.,. 3D.. follower first mover. 3D first mover 3D... Korea Evaluation Institute of Industrial Technology 117
KEIT PD Issue Report PD ISSUE REPORT AUGUST 2015 VOL 15-8!. 3D. 3D (30µm 3D,, 2014-2021) - ( 3D,, 2015-2017). 2014 12 3D 3D (1). 2017, 2020 2024,. 3D. 3D first mover. 1 3D 2015 2016 2017 2018 2019 2020 2021 2022 2023 2024 / 3D () Anchor, Catch-up Niche, Leading-up Hybrid(Smart), Quantum Jump DB ( ) / /Sillicate/ / // Sillicate / /,,,, (ZrO 2, Al 2 0 3, SiO 2 ),,,,, (TiO 2, SnO 2, SiO 2 (Glass) ) 3D,,, (, ),,,,, ( ), (ZrO 2, Al 2 0 3 ),, (calcium phosphates, bioglasses, porcelain, ZrO 2, Al 2 0 3 ) (calcium phosphates, bioglasses, porcelain, ZrO 2, Al 2 0 3 ) 118 한국산업기술평가관리원
ISSUE 6 세라믹 3D 프린팅기술현황과육성전략, /,,,,,,,,,, (ZrO 2, CeO 2 ) / 3D,,,, (MnOx, CoOx, ZnO, Chalcogenide ),,,,, ( ),, (perovskite, fluorite, rocksalt, spinel ) 3D,,, 3 (Al 2 O 3, CeO 2, SiO 2 ),,,,, (Al 2 O 3, Sillicate ),,,,,, (SiO 2, Si 3 N 4, SiC ),,,,, (ZrO 2, Al 2 O 3, SiO 2,,,,,, (Fe 2 O 3, MnOx, SnO 2, ZnO ) / 3D,,, (CeO 2, TiO 2, CaO, Sillicate(mullite, cordierite, zeolite ),,,,, ( ) (PZT, BST, BTO, STO, ITO ),,,,, ( ),, (perovskite, fluorite, rocksalt, spinel ) 3D,,,,, (TiO 2, SnO 2, TiC, AlN /) 3D,,, (CeO 2, TiO 2, CaO, Sillicate(mullite, cordierite, zeolite )) 3D,,,,,,,, ( ) (TiO 2, SnO 2, WC, BC, BN /),,,,, ( ) (/, / ),,,,, ( ) * : 3D, 2014 Korea Evaluation Institute of Industrial Technology 119
KEIT PD Issue Report PD ISSUE REPORT AUGUST 2015 VOL 15-8 6. 3D.,. 3D. 3D.. 3D 3.,,.,,,,,,,.,,, 3D. 3D, R&D.,,. 3D.. 3D. () 1. Modern approaches for the production of ceramic components, F. Klocke, 1997, Journal of European Ceramic Society, 17, 457 2. American Ceramic Society Bulletin, April 2014, 93 3. Ceramics Japan, October 2014, 49 4. MRS Bulletin, February 2015, 40 5. Additive manufacturing of ceramic-based materials, N. Travitzky et. al. 2014, Advanced Engineering Materials, 16, 729 6. Additive manufacturing to produce complex 3D ceramic parts, T. Chartier, 2015, Journal of Ceramic Science and Technology, 06, 95 7. Additive manufacturing of ceramics: issue, potentialities, and oppertunities, A. Zocca et. al. 2015, Journal of American Ceramic Society, 98, 1983 120 한국산업기술평가관리원
ISSUE 6 세라믹 3D 프린팅기술현황과육성전략 8. Three dimensional printing: rapid tooling and prototypes directly from CAD representation, E. Sachs et. al. 1990, CIRP Annals-Manufacturing Technology, 39, 201 9. Resorbable dicalcium phosphate bone substitutes prepared by 3D powder printing, U. Gbureck et. al. 2007, Advanced Functional Materials, 17, 3940 10. Freeform fabricattion of ceramics via stereolithography, M. L. Griffith et al, 1996, Journal of American Ceramic Society, 79, 2601 11. Fabrication of ceramic microstructures by wet powder processing using templates made by stereolithography, J. Tatami et. al. 2014, Ceramics Japans, 49, 875 12. www.prodways.com, 13. Selective laser sintering of metals and ceramics, D. L. Bourrel et al, 1992, International Journal of Powder Metallurgy, 28, 369 14. Additive manufacturing of high performance oxide ceramics via selective laser melting, Y. Hagedorn, 2013 (www.apprimus-verlag.de) 15. Slurry-based additive manufacturing of ceramics, T. Mühler et. al. 2015, International Journal of Applied Ceramic Tehcnology, 12, 18 16. Desktop manufacturing. LOM vs pressing, C. Griffin et. al. 1994, American Ceramic Society Bulletin, 73, 80 17. Laminated object manufacturing of preceramic-paper-derived Si-SiC composites, H. Windsheimer, 2007, Advanced Materials, 19, 4515 18. 3D, 2014 19. 3D printing of ceramic biomaterials, http://www.i-net.ch/wp-content/ uploads/2014/04/fhnwhls-chavanne-biokeramik-20140404-i-net-event.pdf 20. 3D,, 2014, 21. 3D,, 2014, Koita TIP 22. www.lithoz.com, 23. www.cerampilot.com, FCP 24. www.next21.info, 21 25. www.exone.com, ExOne 26. www.yhbm.com, WinSun 27. Wohlers Associates, 2014 28. 3D printing of interdigitated Li-ion microbattery architectures, K. Sun et. al. 2013, Advanced Materials, 25, 4539 29. Printing functional materials, J. A. Lewis, 2012, http://colloids.matse. illinois.edu 30. 㑹 3D 価 2 2014 Korea Evaluation Institute of Industrial Technology 121