노동부고시 제 호 상반기

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1 고용노동부공고제 호 산업안전보건법 제 40 조제 3 항및같은법시행규칙제 91 조에따라신규화학물질의명칭, 유해성 위험성, 연간제조 수입량및노동자건강장해예방을위한조치사항을다음과같이공고합니다. 일련번호 : 000, 공표년도 - 접수년도 - 접수번호 2018 년 8 월 27 일고용노동부장관 유해성 위험성 : 사업주가제출한독성자료의범위내에서국내외화학물질정보 DB 등을활용하여 화학물질의 분류 표시및물질안전보건자료에관한기준 ( 고용노동부고시제 호 ) 에따라유해성 위험성을분류 * 독성시험등추가연구를통해새로운유해성 위험성정보가확인될수있음 노동자건강장해예방을위한조치사항 : 유해성 위험성정보란에기재사항이없더라도신규화학물질취급 노동자가화학물질에장 단기노출될경우등을대비하여사업주가취해야하는기본적인조치사항을제시 신규화학물질의명칭, 유해성 위험성, 연간제조 수입량및조치사항 001 Alkyl(C=3~7)alkyl alkenoate(c=2~6) polymer with alkoxy(c=1~5)alkoxy(c=1 ~5)alkoxy(C=1~5)alkyl(C =1~5)alkylalkenoate(C=2 ~6), alkyl(c=1~5)alkyl(c=4~8) alkylalkenoate(c=2~6), alkylalkylalkenoate(c=2~6), carbomonocyclicalkyl alkyl alkeenate(c=2~6) quaternized with benzyl chloride compound with polyphosphoric acids reaction products with hetermonocycleone, glycols, polyethylene, monoethyl ether and hydropyranone 002 Amines, polyalkylene(1-3)poly-, N-[substituted hydroxyalkyl(3-5)] derivs. 1,000 톤미만 003 Tintitaniumtungstenzincoxid e (CASNo ) -1-

2 Carbomonocycle-(alkylsubstituted-9Hcarbopolycycle-yl)- alkanone(c=3~7)-(oacetyloxime) alkyl(C=1~3)-2- adamantyl alkyl(c=1~3)acrylate, 1- alkyl(c=1~3)cycloalkyl(c= 2~6) methacrylate, 3- hydroxy-1-adamantyl alkyl(c=1~3)acrylate, t- alkyl(c=3~5) methacrylate, γ-alkyl(c=3~5)lactone alkyl(c=1~3)acrylate copolymer 4-[4-(1,1- Alkyl(C=1~4)alkyl(C=2~5) carbomonocycle-1,4- heteromonocycle salt with 1-(5,5,6,6- tetrafluorospiro[1,3- hetermonocyclic- 2,2'tricyclo[3,3,1,13,7]deca n-5'-yl]2,2-substitutedsulfoacetate (1:1) Propanol,3-[1,3,3,3- tetramethyl-1- [(trimethylsilyl)oxy]-1- disiloxanyl]- (CASNo ) Benzeneamine,2,2'-[1,2- ethanediylbis(oxy)]bis- (CASNo ) 9-[1,1-Biphenyl]-4-yl- 3-bromo-9H-carbazole (CASNo ) Glycine,N-[5- (acetylamino)-2- methoxy-4-[2-(5-nitro- 2,1-benzisothiazol-3- yl]diazenyl]phenyl]-n-(2- methoxy-2- oxoethyl)-,methylester 피부부식성 / 피부자극성물질구분 2( 피부자극성 ) 심한눈손상성 / 눈자극성구분 2( 눈자극성 ) -2-

3 (CASNo ) H- Benzimidazole,zincsalt (CASNo ) 012 Glycine,N-[5- (acetylamino)-4-[2-(2- bromo-4,6- dinitrophenyl)diazenyl]-2- methoxyphenyl]-n-(2- methoxy-2- oxoethyl)-,methylester (CASNo ) Trialkyl(C=1~5)[(alkyl(C=1 ~5)-oxoalkenyl(C=1~3)oxy]alkane( C=1~4)aminium, halogen(1:1), polymer with alkyl(c=2~4)alkyl(c=1~5) -alkeno(c=1~3)ate, 2- alkyl(c=1~4)alkyl(c=2~7) alkyl(c=1~5)- alkeno(c=1~3)ate and alkyl(c=1~5) alkyl(c=1~5)- alkeno(c=1~3)ate, (diazenediyl) bis[dialkyl(c=1~5)- alkane(c=2~8) substituted]-initiated -3-

4 (Dialkyl(C=1~5)phenyl)ami no][(dialkyl(c=1~5)sulfop henyl)amino]- sulfophenylheteropolycycle, inner salt, metal salt, polymer with substituted bis[dialkyl(c=1~5)alkene( C=2~8)nenitrile]-initiated alkyl(c=1~5) methacrylate, alkyl(c=2~4) methacrylate, alkyl(c=1~4) alkyl(c=2~7) methacrylate, acrylic acid, alkyl(c=1~5), cycloalkyl(c=2~7) ester, isoalkyl(c=2~4) methacrylate, acrylic acid, alkyl(c=1~5), dialkyl(c=1~5) alkyl(c=1~4) ester, hydroxy alkyl(c=1~4) ester, hydroxy alkyl(c=1~4) methacrylate, methacrylic acid and alkene(c=1~4)aminium, trialkyl(c=1~5) - [(alkyl(c=1~5)-oxoalkenyl(c=1~3)oxy], halogenated Silane,ethenyldimethoxymet hyl- (CASNo ) Acryoic acid, alkyl(c=1~5)-, octahydroalkano(c=1~5)-1hindenyl ester, polymer with alkenyl(c=1~6) carbomonocycle and substituted alkyl(c=1~5)- alkyl(c=1~5)acrylate, hydrogen alkane(c=1~4)dioate acrylate 인화성액체구분 2-4-

5 Alkyl(C=1~4)alkyl(C=2~8) alken(c=2~5)oate, polymer with alkyl(c=1~4) substituted alkyl(c=1~5) alkyl(c=1~4) alken(c=2~5)oate and alkyl(c=1~4) alkyl(c=1~4) alken(c=2~5)oate, [(1- methoxy-2-methyl-1- propen-1- yl)oxy]trimethylsilaneinitiated, compounds with polyphosphoric acids, reaction products with 2- oxepanone, polyl alkyl(c=1~5)ene glycol alkyl(c=1~4)ether and tetraydro-2h-pyran-2- one Benzene,1-bromo-2,4,5- trifluoro- (CASNo ) 특정표적장기독성 (1 회노출 ) 구분 3( 호흡기계자극 ) 피부부식성 / 피부자극성물질구분 2( 피부자극성 ) 심한눈손상성 / 눈자극성구분 2( 눈자극성 ) 인화성액체구분 Octanone,1-[4- (phenylthio)phenyl]- (CASNo ) 특정표적장기독성 (1 회노출 ) 구분 3( 호흡기계자극 ) 피부과민성구분 1 심한눈손상성 / 눈자극성구분 1( 심한눈손상성 ) Phenol, 2,2'-[6-(4- methoxyphenyl)-1,3,5- triazine-2,4-diyl]bis[5- [(2-ethylhexyl)oxy]-(CAS No ) Cyclohexyl-1Hpyrrole-2,5-dione polymer with alkenyl(c=2~4) carbomonocycle, alkyl(c=1~3)-alkenoic acid, alkyl(c=1~3)- alkenoic acid trialkyl(c=1~3)carbopolycy clic ester and -5-

6 heteromonocyclicalkyl methacrylate 022 [N-Alkyl- cycloalkadiene(c=3~8)- alkan(c=2~7)aminato(2-) ] (Nalkylmethanaminato)metal 급성독성구분 4( 경구 ) 023 Phosphonicacid,P,P'-(1- hydroxyethylidene)bis-,pot assiumsalt(1:3) (CASNo ) 024 2,4-Dichloro-6- [1,1':3',1''-terphenyl]-5'- yl-1,3,5-triazine (CASNo ) [[[8- (Trimethoxysilyl)octyl]oxy]m ethyl]-oixrane (CASNo ) 026 1,4-Piperazinediethanol (CASNo ) Oxacycloalkan(C=5~9)one, polymer with 1,6- diisocyanatohexane and alkyl- (hydroxyalkyl(c=1~5))- alkane(c=2~6)diol, dialkyl alkane(c=2~6)dioateand alkyl acetoacetateblocked, alkyl(c=3~7) esters 100 톤미만 -6-

7 (Difluoromethyl)-N- methoxy-1-methyl-n- [(RS)-1-methyl-2- (2,4,6- trichlorophenyl)ethyl]-1hpyrazole-4-carboxamide Hexane, 1,6- diisocyanato-, homopolymer, dialkyl(c=1~5) alkane(c=2~6)dioateand alkyl(c=1~5) acetoacetate-blocked, iso-alkyl(c=3~7) alkylalkyl((c=3~7) esters Alkenoic(C=1-3) acid, alkyl(c=1-5), polymer with 1H,3H- Carbomonocyclic[1,2- c:4,5-c ]difuran-tetrone, dialkyl(c=1-5)alkyl(c=1-4) alkenoate(c=1-3), alkyl(c=1-4) alkenoate(c=1-3), substituted-alkane(c=1-3)diol and alkyl(c=1-5) dialkyl(c=1-5)- alkenoate(c=1-3) (CASNo ) a-hydro-w-hydroxy- poly[oxy(methyl-1,2- ethanediyl)]etherwith2- ethyl-2-(hydroxymethyl)- 1,3- propanediol(3:1)polymerwit h2,4- diisocyanatotolueneand2- methyl-2- propenoicacid2- hydroxyethylester (CASNo. 부여되지않음 ) Acetoxy-substitutedcarbomonocyclic-phenylheteropolycyclic-octanone 100 톤미만 100 톤미만 -7-

8 Propanaminium,N- (carboxymethyl)-n,n- dimethyl-3-[[(9z)-1- oxo-9- octadecenyl]amino]-,inner salt (CASNo ) MixtureofN-methyl-1,3- cyclopentadiene-1- ethanamine( )andN-methyl-2,4- cyclopentadiene-1- ethanamine( ) (CASNo. 부여되지않음 ) Carbomonocyclic carbopolycycleamine polymer with 1- pyrenecarboxaldehyde and (haloalkyl)substituted carbomonocycle Substitutedpoly(oxyalkanediyl) polymer with 5- isocyanato-1- (isocyanatomethyl)-1,3,3- trimethylcyclohexane and cashew, nutshell liq., ethoxylated Hexaethylene glycol PhenylethynylphthalicAnhyd ride (CASNo ) 2,2-Bis[4-(4- aminophenoxy)phenyl]hexa fluoropropane (CASNo ) 피부부식성 / 피부자극성물질구분 2( 피부자극성 ) 심한눈손상성 / 눈자극성구분 2( 눈자극성 ) 수생환경유해성급성 1 급성독성구분 3( 경구 ) 특정표적장기독성 (1 회노출 ) 구분 1 피부부식성 / 피부자극성구분 1( 피부부식성 ) 심한눈손상성 / 눈자극성구분 1( 심한눈손상성 ) 급성독성구분 3( 경구 ) -8-

9 dimethyl-heteropolycycle Heteropolycycle, 7,13- dihydro-7,7-dimethyl- 13-(4-phenylquinazolin- 2-yl)- 1,3,5-Triazine- 2,4,6(1H,3H,5H)- trione,1,3,5-tris(3- mercaptopropyl)- (CASNo ) 1-(2-Bromoethoxy)-2- methoxyethane (CASNo ) 2-[2-(2- chloroethoxy)ethoxy]- ethanol (CASNo ) 2-Hydrazinobenzothiazole (CASNo ) 특정표적장기독성 (1 회노출 ) 구분 3( 호흡기계자극 ) 피부부식성 / 피부자극성물질구분 2( 피부자극성 ) 심한눈손상성 / 눈자극성구분 2( 눈자극성 ) 급성독성구분 4( 경구 ) 급성독성구분 4( 경구 ) 급성독성구분 3( 경구 ) N,N-methanetetraylbis-2- propanamine (CASNo ) 급성독성구분 4( 경구 ) 특정표적장기독성 ( 반복노출 ) 구분 2 피부과민성구분 1 수생환경유해성급성 1 수생환경유해성만성 1 인화성액체구분 3-9-

10 ,1 -[2,2,2-Trifluoro-1- (trifluoromethyl)ethylidene] bis[3,4-dimethylbenzene] (CASNo ) 6-(4- Hydroxyphenoxy)hexyl-2- Propenoate (CASNo ) 1,4- Diazabicyclo[2.2.2]octane- 2-methanol (CASNo ) 1,3-Propanediol,2-ethyl- 2- (hydroxymethyl)-,polymerw ith1,6- diisocyanatohexaneand5- isocyanato-1- (isocyanatomethyl)-1,3,3- trimethylcyclohexane,3,5- dimethyl-1h-pyrazole- and3-hydroxy-2,2- dimethylpropanoicacid- blocked,compds.with2- (dimethylamino)ethanol(ca SNo ) [Alkyl- cycloalkadiene(c=1 6)- alkan(c=2 5)aminato](alky lmethanaminato)-metal Alkyl alkenoic(c=2 8) acid polymer with alkyl(c=1 7) alkenoate(c=2 8) and α- (2-methyl-1-oxo-2- propenyl)-ω-(2- hexyldecyloxy)-poly(oxy- 1,2-ethanediyl),graft 급성독성구분 4( 경구 ) 피부부식성 / 피부자극성구분 1( 피부부식성 ) 심한눈손상성 / 눈자극성구분 1( 심한눈손상성 ) 물반응성물질및혼합물구분 톤미만 100 톤미만 -10-

11 [Heteropolycyclic-oxotrioxadiazaalkenyl(C=10 15)phe nylene]bis(oxyalkylene(c=1 2)]bis[carbomonocyclic carboxylic acid] bis[oxoalkenyl)(c=1 3)oxy alkyl(c=1 6) oxyphenyl] ester [Heteropolycyclic-dioxadiazaalkyl(C=5 10)phenyle ne]bis[carbomonocyclic carboxylic acid] bis[oxoalkenyl(c=1 3)oxya lkyl(c=1 6) oxyphenyl] ester [(formylphenylene)bis(oxyal kylene(c=1 2))]biscarbom onocyclic carboxylic acid 1-Bromo-2- (methylthio)benzene (CASNo ) 3,6 -Dichlorospiro[3H- 2,1-benzoxathiol-3,9 - [9H]xanthene]-1,1- dioxide (CASNo ) Silane,dimethoxymethylpro pyl (CASNo ) Chloroacetaldehydedimethy lacetal(casno ) [(Dialkylsubstituted)alkyl(C =3 5)]-dialkyltrialkoxy(C=1 3)-dioxadisilaoctan-amine 급성독성구분 4( 경구 ) 급성독성구분 4( 경구 ) 급성독성구분 4( 경구 ) 급성독성구분 4( 경구 ) 특정표적장기독성 ( 반복노출 ) 구분 2 인화성액체구분 3 업주는취급근로자가보안경, 보호장갑, 호흡용보호구등적절한 -11-

12 개인보호구를착용하고작업하도록할것 073 Bicyclo[2.2.1]heptane-l- methanesulfonicacid,7,7- dimethyl-2- oxo-,(1r,4s)- (CASNo ) 피부부식성 / 피부자극성구분 1( 피부부식성 ) 심한눈손상성 / 눈자극성구분 1( 심한눈손상성 ) 100 톤미만 074 (pchlorophenyl)metaboricacid (CASNo ) 급성독성구분 4( 경구 ) 075 Substituted-diphenylheteropolycycleamine 076 Metal {[carbomonocyclic phenoxy]-substituted}- heteropolycyclic 078 Alkyl-substitutedheteropolycycle, fluoroalkane(c=1 5)sulfonate 079 Ethanamine,2-bromo-Nmethyl-,hydrobromide (CASNo ) 080 1H-Pyrazole-4,5- dione,1-(2- chlorophenyl)-3- methyl-,4-[2-(4- dodecylphenyl)hydrazone] (CASNo ) 081 Hexane,1,6- diisocyanato-,homopolyme r,3-(trimethoxysily)-n- [3- (trimethoxysilyl)propyl]

13 propanamine-blocked (CASNo ) B-(2- Hydroxyphenyl)boronicacid (CASNo ) 급성독성구분 4( 경구 ) 특정표적장기독성 (1 회노출 ) 구분 3 피부부식성 / 피부자극성구분 2( 피부자극성 ) 심한눈손상성 / 눈자극성구분 2( 눈자극성 ) 084 (Alkyl(C=1 3)carbomonocy clic)dicarbomonocyclic sulfonium salt with halosulfoalkyl(c=2 4) carbopolycyclic carboxylate 급성독성구분 4( 경구 ) 085 Sulfonium,triphenyl-,saltwit h2-sulfoethyl4,7,7- trimethyl-3-oxo-2- oxabicyclo[2.2.1]heptane- 1-carboxylate(1:1) (CASNo ) 급성독성구분 3( 경구 ) 086 2,2 -Dithiodibenzoicacid (CASNo ) 087 Cobaltate(3-),hexakis(cyan o-kc)-,zinc(2:3),(oc-6-11)- (CASNo ) 088 Disiloxane,1,1,3,3- tetramethyl-1,3-bis[2- (7-oxabicyclo[4.1.0]hept- 3-yl)ethyl]- (CASNo ) 089 Biphenyldimethylcarbopolycyclicdiphenylcarbopolycyclicamine -13-

14 Ferrate(1-),bis[2-[(4- amino-2- hydroxyphenyl)azo]-4- chlorophenolate(2-)]-,(o C-6-22 )-,N,N,N,N - tetrakix[mixed3-butoxy-2- hydroxypropyland2- hydroxy-3- (octyloxy)propyl]derivs.,hyd rogen,compds.withnbutyl-1-butanamine(1:1) Phenylcarbopolycyclic heteropolycycle (CASNo ) Benzenemethanol,4- (dimethylamino)-a,a- bis[4- (dimethylamino)phenyl]- (CASNo ) Amines,C12-14-tert- alkyl,bis[2-[2-[2- (hydroxy- ko)phenyl]diazenyl-kn1]- 3-(oxo-kO)-Nphenylbutanamidato(2-)]c obaltate(1-)(1:1) (CASNo ) 2-([1,1 -biphenyl]3-yl)- 4-chloro-6-phenyl- 1,3,5-triazine (CASNo ) 2-Bromotriphenylene (CASNo ) Oxirane, [(C10-16-alkylsubstituted)alkyl] derivs., reaction products with polyalkyl(c=1 5)ene glycolether with [(9z)- octadecenylimino]bis[alkan(c=1 5)ol (2:1), benzoates(salts) 급성독성구분 3( 경구 ) 급성독성구분 4( 경구 ) 피부부식성 / 피부자극성물질구분 2( 피부자극성 ) 심한눈손상성 / 눈자극성구분 2( 눈자극성 ) -14-

15 급성독성구분 4( 경구 ) 099 Carbonimidodithioicacid,cy ano-,chloromethylhexylest er (CASNo ) 급성독성구분 2( 흡입 ) 피부부식성 / 피부자극성구분 1( 피부부식성 ) 심한눈손상성 / 눈자극성구분 1( 심한눈손상성 ) 피부과민성구분 Graphene (CASNo ) 급성독성구분 3( 경구 ) 특정표적장기독성 (1 회노출 ) 구분 Tetrafluorogermane-72Ge (CASNo ) 특정표적장기독성 ( 반복노출 ) 구분 1 생식독성 - 수유독성 피부부식성 / 피부자극성구분 1( 피부부식성 ) 업주는가스, 증기등이발생하는장소에국소배기장치등적절한환기시설을설치할것 심한눈손상성 / 눈자극성구분 1( 심한눈손상성 ) 급성독성구분 3( 경구 ) 102 2,3-Dibromopropanoicacid (CASNo ) 특정표적장기독성 (1 회노출 ) 구분 1 피부부식성 / 피부자극성구분 1( 피부부식성 ) 심한눈손상성 / 눈자극성구분 1( 심한눈손상성 ) 수생환경유해성급성 1 수생환경유해성만성 Phosphorodifluoridousacid, ethyleneester (CASNo ) 급성독성구분 3( 경구 ) 피부부식성 / 피부자극성구분 1( 피부부식성 ) 심한눈손상성 / 눈자극성구분 1( 심한눈손상성 ) -15-

16 104 1,1,1,5,5,5- hexafluoropentane-2,4- dion (CASNo ) 급성독성구분 4( 경구 ) 급성독성구분 4( 경피 ) 급성독성구분 4( 흡입 ) 피부부식성 / 피부자극성구분 1( 피부부식성 ) 심한눈손상성 / 눈자극성구분 1( 심한눈손상성 ) 인화성액체구분 [(4-amino-3- methoxyphenyl)sulphonyl]et hylhydrogensulphate (CASNo ) 피부부식성 / 피부자극성구분 1( 피부부식성 ) 심한눈손상성 / 눈자극성구분 1( 심한눈손상성 ) 100 톤미만 106 Boron,(benzenemethanami ne)trifluoro-,(t-4)- (CASNo ) 급성독성구분 4( 경구 ) Hexanedioicacidpolymerwit h1,6-hexanedioland2- methylenebutanedioicaciddi -2- propenoate,reactionproduct swith6hdibenz[c,e][1,2]oxaphosph orin6-oxide (CASNo ) 108 Bromosubsititutedheteropol ycycle Propynylmethanesulfonate (CASNo ) 급성독성구분 3( 경구 ) 피부부식성 / 피부자극성물질구분 2( 피부자극성 ) 심한눈손상성 / 눈자극성구분 2( 눈자극성 ) 피부과민성구분 1-16-

17 Silicagel reaction products with aluminoxane, alkyl(c=1 4), alkyl(c=1 4) group-terminated [bis(2- methyl-4-(4-tert- butylphenyl)- carbopolycyclic)- alkylsilanediyl] zirconium disubstituted Silicagel reaction products with aluminoxane, alkyl(c=1 4), alkyl(c=1 4) group-terminated [(2- methyl-4-(4-tert- butylphenyl)- indenyl)(alkyl(c=2 5)- (alkyl(c=3 6)carbomonocy clic)-carbopolycyclic)- alkylsilanediyl] zirconium disubstituted Furandione, polymer with ethenylcarbomonocycle, (alkylalkylene(c=1 4)- alkan(c=2 5)diyl)carbomo nocycle, oxirane, alkyl, polymer with oxirane, substituted alkyl(c=2 5) alkyl ether, alkylalkane(c=2 5)diamine, polyphosphoric acids, oxepanone, polyalkylene(c=1 5) glycol mono-methyl ether, tetrahydro-2h-pyran-2- one and azobis(alkylbutyronitorile)- initiated Dodecanamide,N-(2- hydroxyethyl)- (CASNo ) Carbomonocyclic dicarboxylic acid [phenylene bis[ethynediyl phenylene ethynediyl[alkyl[bicarbomon ocyclic]ylidene]oxycarbonyl phenylene]]bis[[(oxoprope nyl)oxy]butyl] ester 심한눈손상성 / 눈자극성구분 1( 눈손상성 ) -17-

18 p-menthane-3,8-diol (CASNo ) Cyclohexane,(ethyldimetho xysilyl)- (CASNo ) 급성독성구분 3( 흡입 ) 119 Benzene,(1,1- dimethylethyl)- (CASNo ) 특정표적장기독성 (1 회노출 ) 구분 2 피부부식성 / 피부자극성물질구분 2( 피부자극성 ) 심한눈손상성 / 눈자극성구분 2( 눈자극성 ) 인화성액체구분 Hexanoicacid,2-bromo- (CASNo ) 급성독성구분 4( 경구 ) 피부부식성 / 피부자극성구분 1( 피부부식성 ) 심한눈손상성 / 눈자극성구분 1( 심한눈손상성 ) Benzeneaceticacid,α,αdichloro-,ethylester (CASNo ) 피부과민성구분 1 수생환경유해성급성 Hexamethylenediisocyanate oligomersreactionproducts with3-methoxypropylamine (CASNo ) 123 Substituted alkyl(c=1 10) thiosulfate 124 Sulfonium,triphenyl-,2- hydroxybenzoate(1:1) (CASNo ) 급성독성구분 3 ( 경구 ) 업주는취급근로자가보안경, 보호장갑, 호흡용보호구등적절한 -18-

19 개인보호구를착용하고작업하도록할것 125 Sulfonium,triphenyl-,saltwit h4,4,5,5,6,6- hexafluorodihydro-4h- 1,3,2-dithiazine1,1,3,3- tetraoxide(1:1) (CASNo ) 급성독성구분 4 ( 경구 ) 126 Morpholinium,4-(4,6- dimethoxy-1,3,5-triazin- 2-yl)-4- methyl-,chloride(1:1) (CASNo ) 급성독성구분 4 ( 경구 ) 127 Spiro[12H- benzo[a]xanthene- 12,1 (3 H)- isobenxofuran]-3 -one,9- [ethyl(3- methylbutyl)amino]- (CASNo ) Bromoaniline (CASNo ) 급성독성구분 4 ( 경구 ) chloro-4- phenylquinazoline (CASNo ) 132 Alkyl-alkenoic(C=2 6) acid polymer with 4-(1- Methylethenyl)phenol, alkyl-alkenoic(c=2 6) acid alkyl ester, heteropolycycle alkyl ester alkyl alkenoic(c=2 6) acid, 1-cyclohexyl-1H-pyrrole- 2,5-dione and carbomobocycleheteromonocyclesubstituted, azobis[dialkyl alkane(c=3 7)nitrile]- initiated -19-

20 Tetraethenylsilane (CASNo ) 특정표적장기독성 (1 회노출 ) 구분 3( 호흡기계자극 ) 피부부식성 / 피부자극성물질구분 2( 피부자극성 ) 심한눈손상성 / 눈자극성구분 2( 눈자극성 ) 인화성액체구분 H-1-Benzopyran-2- one, 7-methoxy-3- [(1E)-2,2,2-trifluoro- [[[(trifluoromethyl)sulfonyl] oxy]imino]ethyl]-(cas No ) 135 [Carbopolycyclic- (tetraalkylheteromonocyclic)carbomo nocyclic]- dicarbomonocyclic-triazine 136 [Substituted- (carbopolycyclic)carbomon ocyclic]- dicarbomonocyclicheteromonocycle 137 Dialkyl-carbopolycyclicheteromonocycle 급성독성구분 4 ( 경구 ) 141 9,9 -bis([1,1 -biphenyl]- 4-yl)-heteropolycycle 142 Triphenylsulfoniumsaltwith1 -[(3- hydroxytricyclo[ ,7]d ec-1-yl)methyl]2,2- difluoro-2- sulfoacetate(1:1) (CASNo ) 급성독성구분 3 ( 경구 ) 143 Bis(heteropolycycle phenyl)- dicarbomonocycletercarbomonocyclediamine -20-

21 Poly(oxy-1,2-ethanediyl), α-hydro-ω-hydroxypolymer with 1,1 - methylenebis[4- isocyanatocyclohexane], substituted carbomonocycle and alkyl(c=2~5)-alkanolblocked 145 Aluminium,3-hydroxy-4- [(4-sulfo-1- naphthalenyl)azo]-2,7- naphthalenedisulfonicacidc omplex (CASNo ) 147 1,2- Cyclohexanedicarboxylicaci d,1-butyl2- (phenylmethyl)ester (CASNo ) 100 톤미만 148 Bis(hydroxyalkyl(C=1 7)- alkanediol substitutedalkylethers 149 Tetrahydro-1,3,4,6- tetrakis(2- mercaptoethyl)imidazo[4,5 -d]imidazole2,5(1h,3h)- dione (CASNo ) 급성독성구분 3 ( 경구 ) 150 Tetrakis(substitutedalkyl)-dioxoheteropolycycle 급성독성구분 4 ( 경구 ) (N,N- Diethylaminopropyl)triethox ysilane (CASNo ) 급성독성구분 4 ( 경구 ) -21-

22 (Substituted-dioxodihydrocarbopolycyclic)heteropolyc yclic naphthalenesulfonate ,6-Bis[(2,6- dimethylphenyl)amino]-9- (2- sulfophenyl)xanthylium,inne rsalt (CASNo ) Isoalkanol,reactionproducts withbis(aminoalkyl(c=1 6)) carbomonocyclealkoxy(c= 3 8)alkanol(C=2 7)and2,4,-TDI Reactionproductsof2- (chloromethyl)oxiraneanddi substituteddicarbomonocyclicalkane,hydrogenated 피부부식성 / 피부자극성물질구분 2( 피부자극성 ) 심한눈손상성 / 눈자극성구분 2( 눈자극성 ) 피부과민성구분 Alkanaminium, hydroxyalkyl(c=2 5)- dialkyl(c=1 4), salts with succinic acid polyisoalkylene(c=1 5) derivs 159 Tri(hydroxyalkyl(C=1 5))iso cyanurate polymer with 1,3(2H,4H)-Primidine diacetic acid, 5-nitro-2, 4-dioxo-, 1,3-bis(1,1- dimethylethyl) ester, Substituteddialkanolic(C=1 5) acid and Alkanediol 160 Poly(oxy-1,2- ethanediyl),a-hydro-w- hydroxy-,polymerwith5- isocyanato-1- (isocyanatomethyl)-1,3,3- trimethylcyclohexane,c13- richc11-14-isoalcsblocked (CASNo ) -22-

23 Phosphonium,tetraphenyl-, saltwith2,3- naphthalenediol,compd.wit h2,3-naphthalenediol (CASNo ) Tetracarbomonocyclicphos phonium,bis[carbopolycycl ediolato(2-)-κo2,κo3] carbomonocyclicsilicate(1- ) Hydroxy-(hydroxyalkyl)- alkyl alkanoic(c=2 8) acid polymer with di(substitutedalkyl)carbomonocycle, alkyl(c=1 7)- (hydroxyalkyl)- alkanediol(c=2 8), dioxoheteromonocycle, hydrohydroxypoly(oxyalkanediyl( C=1 7) and [(alkylalkylidene(c=1 7))di carbomonocyclic]bis[hydro xypoly(oxyalkanediyl(c=1 7))], compd.with ammonia Amines, polyalkylene(1-3)poly-, N-[substituted hydroxyalkyl(3-5)] derivs 1,1 :3,1 -Terphenyl,5 - bromo- (CASNo ) bromobenzene-d5 (CASNo ) 피부부식성 / 피부자극성물질구분 2( 피부자극성 ) 심한눈손상성 / 눈자극성구분 2( 눈자극성 ) 인화성액체구분 3 1,000 톤미만 1,000 톤미만 -23-

24 hydroxydibenzofuran (CASNo ) Benzenemethanaminium,N, N-dimethyl-N-[2-[(2- methyl-1-oxo-2- propen-1- yl)oxy]ethyl]-,chloride(1:1),polymerwithbuthyl2- methyl-2-propenoate,2- (dimethylamino)ethyl2- methyl-2-propenoate,2- ethylhexyl2-methyl-2- propenoate,methyl2- methyl-2-propenoate,α- (2-methyl-1-oxo-2- propen-1-yl)-ω- methoxypoly(oxy-1,2- ethanediyl) (CASNo ) 9,9-Dimethyl-4,5- bis(diphenylphosphino)xant hene (CASNo ) 4-dibenzofuranboronicacid (CASNo ) Benzenemethanaminium,N, N-dimethyl-N-[2-[(2- methyl-1-oxo-2- propen-1- yl)oxy]ethyl]-,chloride(1:1),polymerwithbuthyl2- methyl-2-propenoate,2- (dimethylamino)ethyl2- methyl-2-propenoate,2- ethylhexyl2-methyl-2- propenoate,methyl2- methyl-2-propenoate,α- (2-methyl-1-oxo-2- 특정표적장기독성 (1 회노출 ) 구분 3( 호흡기계자극 ) 피부부식성 / 피부자극성물질구분 2( 피부자극성 ) 심한눈손상성 / 눈자극성구분 2( 눈자극성 ) 급성독성구분 3( 경구 ) 피부부식성 / 피부자극성물질구분 2( 피부자극성 ) 심한눈손상성 / 눈자극성구분 2( 눈자극성 ) -24-

25 propen-1-yl)-ω- methoxypoly(oxy-1,2- ethanediyl)and2-methyl- 2-propenoicacid (CASNo ) 173 Benzenemethanaminium,N, N-dimethyl-N-[2-[(2- methyl-1-oxo-2- propen-1- yl)oxy]ethyl]-,chloride(1:1),polymerwithbutyl2- methyl-2-propenoate,2- (dimethylamino)ethyl2- methyl-2-propenoate,2- ethylhexyl2-methyl-2- propenoate,methyl2- methyl-2-propenoate,α- (2-methyl-1-oxo-2- propen-1-yl)-ω- methoxypoly(oxy-1,2- ethanediyl)andphenylmethyl 2-methyl-2-propenoate (CASNo ) 174 Alkyl alkenoic(c=3 8) acid alkyl ester polymer with alkenyl(c=1 6)carbomono cycle, alkyl(c=1 6) alkenoate(c=3 8), substitutedalkyl(c=1 6) alkenoate(c=3 8), heteromonocyclic-alkyl alkyl-alkenoate(c=3 8) and alkanediol(c=3 8) mono(alkylalkenoate(c=3 8)), reaction products with dialkanol(c=1 6)amine, alkanoates (salts) -25-

26 175 Alkyl alkenoic(c=3 8) acid alkyl ester polymer with alkenyl(c=1 6)carbomono cycle, alkyl(c=1 6) alkenoate(c=3 8), heteromonocyclic-alkyl alkyl-alkenoate(c=3 8) and alkanediol(c=3 8) mono(alkylalkenoate(c=3 8)), reaction products with substituteddialkanol(c=1 6), alkanoates (salts) 176 phenyl-substitutedcarbopolycycle 급성독성구분 4( 경구 ) 피부부식성 / 피부자극성물질구분 2( 피부자극성 ) 심한눈손상성 / 눈자극성구분 2( 눈자극성 ) 177 N9,N10-di-2- naphthalenyl-n9,n10- diphenyl-9,10- Anthracenediamine (CASNo ) 179 Bis(phenylheteropolycyclic)carbopolyc ycle 특정표적장기독성 (1 회노출 ) 구분 3( 호흡기계자극 ) 피부부식성 / 피부자극성물질구분 2( 피부자극성 ) 심한눈손상성 / 눈자극성구분 2( 눈자극성 ) 180 Alkane(C=5 9)dione, [[[(acetylsubstituted)imino] -carbomonocycle- oxoalkyl]-alkyl(c=1 5)- heteropolycycle]-, acetyloxime Fattyacids,C18-36,esterswithethyleneglycol (CASNo ) -26-

27 [carbomonocyclic]-yl- (alkyl-carbopolycycle-yl)- carbomonocyclicbenzo[b]fluoren-amine 188 Furandione, telomer with alkyl(c=1 4)- alkyl(c=1 4)enealkan(C=2 6)diyl)[carbom onocycle] and ethenylbenzene, oxycarbomonocyclealkyl(c =1 5)ester, esters with alkyl(c=1 5)ene glycol- (C=13 15) alkyl ethers, ammonium salts,- azenediyl[alkyl(c=1 4)alka n(c=2 6)substituted]- initiated 4-Hydroxybenzophenone (CASNo ) [(Alkoxy(C=2 5)alkyl(C=4 7)alkylsilanediyl)- bis(alkyl(alkyl(c=2 5)carbo monocyclic)- carbopolycyclic)] zirconium disubstituted Formaldehyde,polymerswith epichlorohydrin,phenolandr educed1,1 - [methylenebis(oxy)]bis[2- chloroethane]- sodiumsulfide(na2(sx))- 1,2,3- trichloropropanepolymer (CASNo ) N-[Bicarbomonocycle]- yl-n-[[(heteropolycycle)- carbopolycycle- yl]carbomonocycle]- dialkyl-carbopolycyclic- 특정표적장기독성 (1 회노출 ) 구분 3( 호흡기계자극 ) 피부부식성 / 피부자극성물질구분 2( 피부자극성 ) 심한눈손상성 / 눈자극성구분 2( 눈자극성 ) 특정표적장기독성 (1 회노출 ) 구분 3( 호흡기계자극 ) 피부부식성 / 피부자극성물질구분 2( 피부자극성 ) 심한눈손상성 / 눈자극성구분 2( 눈자극성 ) 100 톤미만 업주는취급근로자가보안경, 보호장갑, 호흡용보호구등적절한 -27-

28 amine 개인보호구를착용하고작업하도록할것 189 Phenyl heteropolycyclic naphthyl heteromonocyclic di-phenyl 190 Alkyl-alkenoic(C=2 6) acid polymer with 4-(1- methylethenyl)phenol, alkyl-alkenoic(c=2 6) acid alkyl ester, alkylalkenoic(c=2 6) acid heteropolycycle alkyl ester, 1-cyclohexyl-1H-pyrrole- 2,5-dione and carbomobocycleheteromonocyclesubstituted, azobis[dialkyl alkane(c=3 7)nitrile]- initiated 100 톤미만 [[[[Substituted [[hydroxysulfo-[[[[(sulfoxxy)alkyl] sulfonyl]carbomonocyclic]a zenyl]carbopolycyclic]amin o- heteromonocyclic]amino]hy droxysulfocarbopolycyclic]azenyl]carb opolycyclic]sulfonic acid 193 Alkane(C=3 7)dioic acid, polymer with dialkyl(c=1 4)alkane(C=2 5)diol, alkyl(c=1 5)(hydroxyalkyl( C=1 4) alkane(c=2 5)diol, heteropolycyclicdione and 2,2,4,4-tetramethyl-1,3- cyclobutanediol 194 Alkenoic acid, alkyl(c=1 4), alkyl (C=12 15) ester polymer with N, N -Diethyl-N,N - bis-[6-(ethyl-{2-[2-(2- methyl-acryloyloxy)- ethylcarbamoyloxy]- ethyl}-azaniumylidene)- 9-o-benzenesulfonate- 9H-xanthen-3-yl]- hexane-1,6-diamine, -28-

29 alkenoic acid, and heteromonocycle-one, carbomonocycle- 195 Alkenoic acid polymer with alkenoic acid, alkyl(c=1 4) ester, alkenoic acid, alkyl(c=1 4)-, hydroalkanoinden(c=1 4)-yl ester, and benzoic acid, 4-[2-[5-cyano-1-(2- ethylhexyl)-1,6-dihydro- 2-hydroxy-4-methyl-6- oxo-3- pyridinyl]diazenyl]-, 2- hydroxy-3-[(2-methyl-1- oxo-2-propen-1- yl)oxy]propyl ester 197 Bis(pinacolato)diboron (CASNo ) Butyl-2-pyrrolidinone (CASNo ) 급성독성구분 4( 경구 ) 피부부식성 / 피부자극성구분 1( 피부부식성 ) 심한눈손상성 / 눈자극성구분 1( 심한눈손상성 ) 100 톤미만 199 Dialkyl(C=1 5)olalkanoic acid polymer with ethoxylated trialkyl(c=1 5)olalkane and alkenoic acid 200 Dialkyl(C=1 5) phosphonate polymer with alkyl(c=3 7)- alkyl(c=2 6)-alkanediol and alkane(c=4 8)diol 피부부식성 / 피부자극성물질구분 2( 피부자극성 ) 심한눈손상성 / 눈자극성구분 1( 심한눈손상성 ) -29-

30 Benzenemethanaminium,N, N-dimethyl-N-[2-[(2- methyl-1-oxo-2- propen-1- yl)oxy]ethyl]-,chloride(1:1),polymerwithbuthyl2- methyl-2-propenoate,2- (dimethylamino)ethyl2- methyl-2- propenoateandα-[2-(2- methyl-1-oxo-2- propen-1-yl)oxy]ethyl]- ω-hydroxypoly[oxy(1- oxo-1,6-hexanediyl)] (CASNo ) 1-(triphenylen-2- yl)naphthalen-2-yl 1,1,2,2,3,3,4,4,4- nonafluorobutane-1- sulfonate 6 -(Diethylamino)-1,3 - dimethylfluoran (CASNo ) 2-propenoicacid,2- chloro-,3,3,4,4,5,5,6,6,7,7,8,8,8- tridecafluorooctylester (CASNo ) Silanetriol, [(substituted alkoxy)alkyl]- (Substituted-dibenzothiophenyl)carbomonocycle -heteropolycycle 2,4-dichloro- benzo[4,5]thieno[3,2- d]pyrimidine (CASNo ) 급성독성구분 4( 경구 ) 특정표적장기독성 ( 반복노출 ) 구분 2 수생환경유해성만성 2 1,000 톤미만 -30-

31 Tricarbomonocyclicheteropolycyclediamine Alkyl(C=12 16)2-methyl- 2- propenoatepolymerswithpol yethylenepolypropyleneglycolmonoet herwithpropyleneglycolmon omethacrylateandstyrene (CASNo ) 2-Bromo-1-chloro-3- fluorobenzene (CASNo ) N,N-Dimethyl-N-[3- (trihydroxysilyl)propyl]-1- octadecanaminium,chloride (1:1) (CASNo ) Aluminum cerium metal oxide 수생환경유해성급성 1 수생환경유해성만성 1-31-

32 Reaction mixture of hexanedioic acid, polymer with 1,3- diisocyanatomethylbenzene, 2,2-dimethyl-1,3- propanediol, 2-ethyl-2- (hydroxymethyl)-1,3- propanediol and 1,6- hexanediol, toluene diisocyanate, bis(4- isocyanatophenyl)methane, carbomonocycle, alkylene(c=1 3) [isocyanate-, homopolymer, carbomonocyclesulfonyl isocyanate, alkyl(c=1 3)-, alkane(c=1 3), alkoxy(c=1 3)-, oxybis(alkyl(c=1 3)alkylen e(c=2 4)) tetraoxycarbomonocyclic diphosphate, trioxycarbomonocyclic phosphite, siloxanes and Silicones, alkyl(c=1 3), reaction products with silica, alkyl(c=1 3)alkyl(C=3 5) acetate and ethyl methyl ketone Tris[7- substitutedcarbomonocycli c-6-fluoro-1,4-dihydro- 4-(oxo-KO)- heteropolycycle-3- carboxylato-ko3] europium Substituted hydroxy sulfo sulfooxy alkyl sulfonyl carbomonocyclic azenyl carbopolycyclic amino heteromonocyclic amino hydroxyl sulfonapthalenyl azenyl naphthalene sulfonic acid 2-Propenoicacid,2- methyl-,butylester,polymer withbutyl2- propenoate,ethenylbenzene,2-hydroxyethyl2-metyl- 2-propenoate,methyl2- methyl-2- propenoateand2- propenoicacid,tert-bu

33 ethylhexaneperoxoateinitiated (CASNo ) 218 1,3,2,-Dioxathiane,2,2- dioxide (CASNo ) 급성독성구분 3( 경구 ) 219 Carbomonocyclic- bis(heteropolycyclic)- triazine (4,4,5,5-Tetramethyl- 1,3-2-dioxaborolan-2- yl)-dibenzofuran (CASNo ) 222 Alkylsiloxanepolyol tetrakis(substituted) Chloro-2-(4- Fluorophenylamino)-5,6- dimethyl-pyrimidine (CASNo ) 224 (Bicarbomonocyclic-yl)- substituted carbomonocyclic heteromonocycle 225 Bicarbomonocyclic- carbomonocyclic- (carbopolycycle- heteropolycyclic)- heteromonocycle -33-

34 226 (Carbomonocyclic- ((carbopolycyclic)naphthale nyl)-heteromonocyclic)- bicarbomonocycliccarbonitrile (Bicarbomonocycle)-yl- (tricarbomonocyclic dibenzofuran)-ylcarbomonocyclicheteromonocycle (Substitutedcarbomonocyclic)benzocarbopolycyclicheteromonocycle 233 Di(bicarbomonocyclic)- biheteropolycycle 2- Propenoicacid,polymerwith( chloromethyl)oxirane,formal dehydeand2-methylphenol (CASNo ) Phosphonicacid,P- (hydroxymethyl)-,diethylest er (CASNo ) 3- Methacrylamidophenylboro nicacid (CASNo ) Bromo-substituteddicarbomonocyclicheterom onocycle -34-