11-1480523-001362-01 NIER-SP2012-334
수질유해물질확대지정및기준안설정연구
제1장조사대상물질선정및시료채취지점의선정
수질유해물질확대지정및기준안설정연구 1-1. 1 A 1 + ( ) + ( ) 2A ( B 2B ( B 3A ) ) 3B 1-2. 1 Se (Selenium) 1) EPA IRIS BCF ( ) AIRC Report PBT PBT ( ) ( ) D 3 4.8 - - / / Benzene 1) A 1 5.2** 8.7 38 / / / Carbon Tetrachloride 1) B2 2B 18.75** 30 60 / / / Dichloromethane 1) B2 2B 0.9 1.8 38 / / / 1,1-Dichloroethylene 1) C - 5.6 8.7 38 / / Chloroform 1) B2 2B 3.75* 6.6 38 / / / Ethylbenzene D 2B 37.5** 53 15 Styrene C 2B - 37 15 ( ) 1,1,1-Trichloroethane D 3-16 60 ( )/ Toluene D 3 10.7 25 15 20 Vinyl Chloride A 1 1.17 3.6 15 ( )/ ( )/ ( ) Xylene - 3-50 15 Acrylonitrile B1 2B 30* 3.2 15 ( ) 1,2-Dichloroethane 1) B2 2B - 2.8 38 / / 2,4-Dinitrotoluene B2 3) 2B 3.8 6.7 38 - Nitrobenzene D 2B 2.89 5.3 15 - Antimony - 3 1 - - / ( ) Bromoform B2 3 3.75 14 38 ( ) Bis(2-Ethylhexy)Phthalate B2 3 130 310 15 ( )/ / ( ) 1,4-Dioxane 2) B2 2B - 3.2 15 ( ) ) 1. 2. 3. 2,4-DNT & 2,6-DNT mixture
제1장조사대상물질선정및시료채취지점의선정 1-2. ( ) 2A 2B Asbestos BCF ( ) EPA IRIS AIRC Report PBT PBT ( ) ( ) A 1 - - - Dichlorobromomethane B2 2B 3.75 6.9 38 2,6-Dinitrotoluene B2 2B - 8.3 38 - Hexachloroethane C 2B 86.9 310 180 - Ni (Nickel) (A,B2) 4) (1,2B) 47 - - 1,4-Dichlorobenzene - 2B 55.6 89 38-3,3-Dichlorobenzidine 14 B2 2B 312* 100 60 - Naphthalene C 2B - 69 38 - Acrylamide 2) B2 2A - - - - Epichlorohydrin* 2) B2 2A - 3.2 15 - Formaldehyde 2) B1 1-3.2 15 - Nitrilotriacetic acid (NTA) 2) - 2B - - - - Chlorothalonil 2) - 2B - 45 180 - Dichlorvos 2) B2 2B 0.45 38 - Be (Berylium) B1 1 - - - - 2,3,7,8-TCDD B 1 - - - - Chloroethane (=Ethyl chloride) - 3-2.5 15 ( ) Chlorophenol - - - - - ( ) 2,4-Dichlorophenol - 2B 40.7** 18 38 ( ) 1,2-Dichloropropane - 3 4.1 6.7 38-1,3-Dichloropropylene B2 2B 1.9 6.7 38-2,4,6-Trichlorophenol B2 2B 150 55 60 ( ) pentachlorophenol B2 2B 11 700 180(0~0.013 ***) ( ) Benzo(a)Anthracene B2 2B 30 5400 60 - Benzo(a)Pyrene B2 1-10000 60 ( ) Benzo(b)Fluoranthene 23 B2 2B 30 5600 60 - Benzo(k)Fluoranthene B2 2B 30 10000 60 - Chrysene B2 2B 30 5900 60 - Dibenzo(a,h)Anthracene B2 2A 30 22000 60 - Hexachlorobenzene B2 2B 17.5 5200 180 - Indeno(1,2,3-cd)Pyrene B2 2B 30 29000 60 - Benzidine A 1 87.5* 2.2 38 - Bis(2-Chloroethyl)Ether (=BCEE) B2 3 6.9 2 38-1,2-Diphenylhydrazine B2-24.9 37 15 - N-Nitrosodimethylamine B2 2A 0.026 3.2 38 - N-Nitrosodi-n-Propylamine B2 2B 1.13 2.2 38 - N-Nitrosodiphenylamine B2 3 - - - - ) 1. 2. 3. 2,4-DNT & 2,6-DNT mixture 4. Nickel carbonyl : B2,Nickel refinery dust : A, Nickel subsulfide : A, Nickel(soluble salts) : Information reviewed :, :, ( ):, :, :, ( ): * BCF ** BCF ***
수질유해물질확대지정및기준안설정연구 1-2. ( ) 3A 3B Bis(2-Ethylhexy)adipate BCF ( ) EPA IRIS AIRC Report PBT PBT ( ( ) C 3-61 8.7 ( ) Butylbenzyl Phthalate C 3 - - - - Hexachlorocyclopentadiene E - - - - - B (Boron) - - - - - - Acrolein - 3 - - - - Methyl Chloride D 3 - - - - Nonyl Phenols - - - 540 60 - Octyl Phenols - - - 340 15 - Isophorone C - - - - - Carbaryl 2) - - - 13 38 - Carbofuran 2) 21 - - - - - - Diquat 2) - - - - - - Chlorpyrifos 2) - - - 1300 180-2,4-D (=2,4-Dichlorophenoxyacetic acid) 2) - - - 3.2 38 ( ) Diazinon 2) - - - 170 38 ( )/ 2) α-endosulfan 2) β-endosulfan - - - - - - - - - - - - EPN 2) - - - 960 38 - Fenitrothion 2) - - - 71 15 - Iprobenfos 2) - - - 74 38 - Perchlorate 2) - - - - - ( ) Pentachlorobenzene D - 2125 1900 180 - Anthracene D 3 - - - - Di-n-Butyl Phthalate D - 89 580 8.7 - Fluoranthene D 3 1150 1900 60 - Pyrene D 3 - - - - Tl (thallium) D - - - - - Ag (silver) D - - - - - Ti (titanium) - 2B 5) - - - - Mo (Molybdenum) - - - - - - Chlorobenzene D - 10.3 31 15-42 Chlorodibromomethane C 3 3.75 9.2 38-1,1-Dichloroethane C - - 4.8 38 - cis-1,2-dichloroethylene D - - 8.1 38 - Methyl Bromide (=Bromomethane) D 3 3.75 1.6 15-1,1,2,2-Tetrachloroethane C 3 - - - - 1,2-Trans-Dichloroethylene - - 1.58 8.1 38-1,1,2-Trichloroethane C 3 4.5 5.7 38-2,4-Dimethylphenol - - 93.8* 12 15-2-Methyl-4,6-Dinitrophenol - - 5.5 8.6 38-2,4-Dinitrophenol - - 1.5 3.8 38 - ) 2. 5. Titanium dioxide :, :, ( ):, :, :, ( ): * BCF ** BCF ***
제1장조사대상물질선정및시료채취지점의선정 1-2. ( ) 2-Nitrophenol EPA IRIS BCF ( ) AIRC Report PBT PBT ( ) ( ) - - - 4.8 15-4-Nitrophenol - - - 5.9 15-3-Methyl-4-Chlorophenol - - - 49 38 - Acenaphthene - 3 242 210 38 - Acenaphthylene D - - - - - Benzo(g,h,i)Perylene D 3 - - - - Bis(2-Chloroethoxy)Methane D - - 2 38 - Bis(2-Choroisopropyl)Ether D - 2.47 16 38-4-Bromophenyl Phenyl Ether - - - 1300 38-2-Chloronaphthalene - - - - - - 3B 4-Chlorophenyl Phenyl Ether - - - 830 38-42 1,2-Dichlorobenzene D 3 55.6 87 38-1,3-Dichlorobenzene D - 55.6 100 38 - Diethyl Phthalate D - 73 15 15 - Dimethyl Phthalate D - 36 3.4 15 - Di-n-Octyl Phthalate - - - 64 15 - Fluorene D 3 30 330 15 - Hexachlorobutadiene C 3 2.78** 960 180 - Phenanthrene D 3 - - - - 1,2,4-Trichlorobenzene D - 114 250 60 - Tributyltin compounds D 6) - - - - - 2-Chloroethylvinyl Ether - - - 1.6 15 - ) 6. Tributyltin oxide (TBTO) :, :, ( ):, :, :, ( ): * BCF ** BCF ***
수질유해물질확대지정및기준안설정연구
제1장조사대상물질선정및시료채취지점의선정
수질유해물질확대지정및기준안설정연구
제1장조사대상물질선정및시료채취지점의선정 EPA 1) IARC 2) / ( ) 3) ( ) 3 (Zinc) D -, 1
수질유해물질확대지정및기준안설정연구 / EPA 1) IARC 2) ( ) 3) ( ) (Styrene) - 2B 1 1,2- (1,2-Dichloropropane) B2 3,, DEHA Bis(2-ethylhexyl)adipate B2 3 Perchlorate - - ) 1) USEPA. IRIS(Integrated Risk Inform ation System ) web-site; USEPA 2010d. Available from http:/ /cfpub.epa.gov/ ncea/ iris/ index.cfm 2). (2006), ; 2008. 3) USEPA. TRI explorer (Release : Chem ical report); USEPA, 2010d. Available from http:/ /w ww.epa.gov/ triexplorer
제1장조사대상물질선정및시료채취지점의선정
수질유해물질확대지정및기준안설정연구 2010 / (, 2012) 4 1
2010 / (, 2012) 제1장조사대상물질선정및시료채취지점의선정
수질유해물질확대지정및기준안설정연구 2010 (, 2012)
2010 (, 2012) 제1장조사대상물질선정및시료채취지점의선정
수질유해물질확대지정및기준안설정연구
제1장조사대상물질선정및시료채취지점의선정
수질유해물질확대지정및기준안설정연구 2010 (, 2012)
제1장조사대상물질선정및시료채취지점의선정
수질유해물질확대지정및기준안설정연구
제1장조사대상물질선정및시료채취지점의선정 3 1 ( )
수질유해물질확대지정및기준안설정연구
제1장조사대상물질선정및시료채취지점의선정
수질유해물질확대지정및기준안설정연구
제1장조사대상물질선정및시료채취지점의선정
수질유해물질확대지정및기준안설정연구
제2장특정수질유해물질지정체계및배출허용기준설정체계
수질유해물질확대지정및기준안설정연구
제2장특정수질유해물질지정체계및배출허용기준설정체계
수질유해물질확대지정및기준안설정연구
제2장특정수질유해물질지정체계및배출허용기준설정체계
수질유해물질확대지정및기준안설정연구
제2장특정수질유해물질지정체계및배출허용기준설정체계 : (N on linear L ow -D ose E xtrapolation ) : (Lin ear Low -D ose E xtrapolation) 위해도 or or
수질유해물질확대지정및기준안설정연구
제2장특정수질유해물질지정체계및배출허용기준설정체계
수질유해물질확대지정및기준안설정연구
제2장특정수질유해물질지정체계및배출허용기준설정체계 Cancer risk 10-4 Threatened Water Environment 10-5 Risk reduction 10-6 Sound & Sustainable Water Environment Recommended value Required value Maximum value Cancer risk 2-3.
수질유해물질확대지정및기준안설정연구 Austrailian and New Zealand Guidelines for Fresh and M arine W ater Quality(ANZECC & ARM CANZ, 2000)
제2장특정수질유해물질지정체계및배출허용기준설정체계 (AF) 1000 LC 50 OECD 100 LC 50 (,, 3 ) 100 1 NOEC(,, 1 ) 50 2 NOEC(,, 2 ) 10 3 NOEC(,, 3 ) EC Guidance D ocum ent for Aquatic Effects Assessm ent(o ECD, 1995) Technical Guidance D ocum ent on Risk Assessm ent(ec, 2003)
수질유해물질확대지정및기준안설정연구
2-5. 제2장특정수질유해물질지정체계및배출허용기준설정체계
수질유해물질확대지정및기준안설정연구
제3장물질별분석방법및분석결과
수질유해물질확대지정및기준안설정연구
제3장물질별분석방법및분석결과 Ω
수질유해물질확대지정및기준안설정연구 Ω
제3장물질별분석방법및분석결과
수질유해물질확대지정및기준안설정연구
제3장물질별분석방법및분석결과
수질유해물질확대지정및기준안설정연구
제3장물질별분석방법및분석결과
수질유해물질확대지정및기준안설정연구
제3장물질별분석방법및분석결과
수질유해물질확대지정및기준안설정연구
제3장물질별분석방법및분석결과
수질유해물질확대지정및기준안설정연구
제3장물질별분석방법및분석결과
수질유해물질확대지정및기준안설정연구
제3장물질별분석방법및분석결과
수질유해물질확대지정및기준안설정연구
제3장물질별분석방법및분석결과
수질유해물질확대지정및기준안설정연구
제3장물질별분석방법및분석결과
수질유해물질확대지정및기준안설정연구
제4 장조사대상물질별특정수질유해물질지정( 안) 및배출허용기준( 안)
수질유해물질확대지정및기준안설정연구
제4 장조사대상물질별특정수질유해물질지정( 안) 및배출허용기준( 안)
수질유해물질확대지정및기준안설정연구
제4 장조사대상물질별특정수질유해물질지정( 안) 및배출허용기준( 안) v v v v v v v v v v v ) 1. 10.
수질유해물질확대지정및기준안설정연구
제4 장조사대상물질별특정수질유해물질지정( 안) 및배출허용기준( 안)
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수질유해물질확대지정및기준안설정연구
제4 장조사대상물질별특정수질유해물질지정( 안) 및배출허용기준( 안)
수질유해물질확대지정및기준안설정연구
제4 장조사대상물질별특정수질유해물질지정( 안) 및배출허용기준( 안) v v v v v v v ) 1. 10.
수질유해물질확대지정및기준안설정연구
제4 장조사대상물질별특정수질유해물질지정( 안) 및배출허용기준( 안)
수질유해물질확대지정및기준안설정연구
제4 장조사대상물질별특정수질유해물질지정( 안) 및배출허용기준( 안) v v v v ) 1. 10.
수질유해물질확대지정및기준안설정연구 수질준거치 RfD : RSC : BW : DI : FI : BAF : (mg/kg/day) (kg) (L/day) (kg/day) (L/kg)
제4 장조사대상물질별특정수질유해물질지정( 안) 및배출허용기준( 안) - N O E C = 0.06 /L - 1 ( 1 ) =
수질유해물질확대지정및기준안설정연구
제4 장조사대상물질별특정수질유해물질지정( 안) 및배출허용기준( 안)
수질유해물질확대지정및기준안설정연구 v v v v v ) 1. 10
제4 장조사대상물질별특정수질유해물질지정( 안) 및배출허용기준( 안) 수질준거치 RSD : BW : DI : FI : BAF : (mg/kg/day) = (10-5 )/ (q1) (kg) (L/day) (kg/day) (L/kg)
수질유해물질확대지정및기준안설정연구 - N O E C = 32,621 / L - 1 ( 1 ) =
제4 장조사대상물질별특정수질유해물질지정( 안) 및배출허용기준( 안)
수질유해물질확대지정및기준안설정연구
제4 장조사대상물질별특정수질유해물질지정( 안) 및배출허용기준( 안) v v v ) 1. 10
수질유해물질확대지정및기준안설정연구 수질준거치 RSD : BW : DI : FI : BAF : (mg/kg/day) = (10-5 )/ (q1) (kg) (L/day) (kg/day) (L/kg)
제4 장조사대상물질별특정수질유해물질지정( 안) 및배출허용기준( 안) - L C 50 = 780 /L - 1 ( 1 ) =
수질유해물질확대지정및기준안설정연구 DEHA(Bis(2-ethylhexyl)adipate)
제4 장조사대상물질별특정수질유해물질지정( 안) 및배출허용기준( 안) DEHA(Bis(2-ethylhexyl)adipate) 5 2 >.
수질유해물질확대지정및기준안설정연구 v v v v v ) 1. 10
제4 장조사대상물질별특정수질유해물질지정( 안) 및배출허용기준( 안) 수질준거치 RfD : RSC : BW : DI : FI : BAF : (mg/kg/day) (kg) (L/day) (kg/day) (L/kg)
수질유해물질확대지정및기준안설정연구 - N O E C = 21.7 /L - 1 ( 1 ) =
제4 장조사대상물질별특정수질유해물질지정( 안) 및배출허용기준( 안) 4-6. (Perchlorate)
수질유해물질확대지정및기준안설정연구 4-19.,
제4 장조사대상물질별특정수질유해물질지정( 안) 및배출허용기준( 안)
수질유해물질확대지정및기준안설정연구 v v v v ) 1. 10 v v v v 수질준거치 RfD : RSC : BW : (kg) (mg/kg/day)
제4 장조사대상물질별특정수질유해물질지정( 안) 및배출허용기준( 안) DI : FI : BAF : (L/day) (kg/day) (L/kg) - N O E C = 0.75 /L - 3 ( 1, 1, 1 )
수질유해물질확대지정및기준안설정연구 = 0.12 mg/ L
제4 장조사대상물질별특정수질유해물질지정( 안) 및배출허용기준( 안)
수질유해물질확대지정및기준안설정연구 1),
제5장연구결과종합
수질유해물질확대지정및기준안설정연구
제5장연구결과종합
수질유해물질확대지정및기준안설정연구 ) 1. 10. 2..
제5장연구결과종합 ) 1.
수질유해물질확대지정및기준안설정연구 ) 1. (, T B EL ) 2., ( 3, : 0.8 m g/l, : 8 m g/l )
제5장연구결과종합
수질유해물질확대지정및기준안설정연구
제5장연구결과종합
수질유해물질확대지정및기준안설정연구
제5장연구결과종합 μ μ μ
수질유해물질확대지정및기준안설정연구 ( μg/l) (%) ( 75~125%) (%) (±25% ) A B C Formaldehyde 10 70.1 96.7 112.6 93.13 23.1 Naphthalene (Headspace) Naphthalene (P&T) 10 71.3 98.3 112.6 94.07 22.3 5 92.2 131.1 97.2 106.8 19.8 Epichlorohydrin 5 102.2 109.0 105.6 105.6 3.2 A B D RSD(%) ( μg/l) A B C A B C 23.8 20.9 24.3 8.0 5.3 6.1 5.8 7.1 61.1 76.9 55.5 17.2 35.7 31.3 32.8 6.8 111.3 106.4 140.1 15.3 74.5 62.1 94.2 21.1 6.3 4.7 7.7 24.5 5.2 4.6 5.7 11.5 33.4 28.5 25.1 14.6 10.7 10.0 12.8 13.2 16.5 18.6 14.9 11.1 9.1 7.0 13.9 35.3
제5장연구결과종합 A B C RSD(%) 77.0 73.6 71.4 3.8 A 72.8 77.0 83.0 6.6 66.6 69.8 72.0 3.9 MS B C 64.6 64.4 71.8 6.3 68.2 62.6 68.8 5.1 77.4 74.4 67.4 7.0 (%) A B C 59.0 64.8 73.8 11.3 66.8 57.2 64.4 8.0 92.2 97.8 113.0 10.7 67.0 74.0 58.0 12.1 61.2 71.0 51.0 16.4 64.6 69.4 67.0 3.6 A B D RSD(%) 54.8 65.3 54.3 10.7 A 59.2 55.0 54.3 4.7 50.3 63.7 61.0 12.2 HS MS (%) B C A B C 62.5 75.9 47.7 22.8 50.3 82.3 49.3 30.9 53.0 80.0 53.7 24.7 58.5 93.1 50.3 33.8 52.7 64.6 68.7 13.4 57.0 64.0 49.7 12.6 50.7 67.2 58.7 14.1 65.7 106.5 59.3 33.1 55.7 93.2 57.0 31.0
수질유해물질확대지정및기준안설정연구 A B C RSD(%) 62.7 58.3 57.2 4.9 A 60.2 59.9 60.0 0.2 69.0 58.3 70.0 9.8 P&T MS (%) B C A B C 81.8 60.1 68.3 15.7 83.2 70.9 69.8 9.9 52.2 69.5 52.7 17.0 61.7 58.3 65.0 5.4 70.0 61.9 58.3 9.4 71.8 95.2 70.0 17.8 58.3 76.5 56.7 17.2 95.8 84.9 94.5 6.5 71.7 52.4 63.3 15.5
제5장연구결과종합 5-1. ( ) 5-13.
수질유해물질확대지정및기준안설정연구 5-14. ( ) 2015 1 (2016) 2 (2017) 3 (2018) 4 (2019) 5 (2020) 6 ( ) 7 8 9 10