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List of Figures List of Tables - i -
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List of Figures - iii -
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List of Tables - v -
국문 초록 충남지역 출토 백제시대 유리구슬의 고고화학적 분석 고찰 송 유 나 공주대학교 대학원 문화재보존과학과 문화재보존과학 전공 - vi -
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1) - 1 -
(a) (b) - 2 -
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(강지원;2004) (공주대학교 박물관, 2000년) - 8 -
(공주대학교 박물관, 2000년) (충남역사문화원, 2005) - 9 -
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이차전자 L-α X-ray 입사전자 K-α X-ray 반사전자 입사광 측정신호 분석깊이 감도 분석원소 원리 취득정보 SEM 전자 2차전자, 100A 100ppm B~ X-선 EPMA 전자 X-선 1μm 10ppm B~ 가속전자에 대한 2차전자나 X- 선 특성 X-선에 의한 원소분포 표면형상, 원소조성 원소의 정량 - 19 -
2) 3) - 20 -
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Sample Phase of remains Characteristic Number Site Century Type Closing Color Transparency Surface Bubble Crack Remark ea-1 A RR R X S-W L-S,L-B X ea-2 A RR R X S-W M-S,M-B X A.D. 3C ea-3 토광묘 7호 A RR R X G-D M-S,M-B X 후반 ea-4 A R X G-D L-S X ea-5 A RR R X G-D M-S X ea-6 A EE R X G-D L-S ea-7 A EE R X S-W L-S 표면풍화 ea-8 A RR R X M-W L-S X 풍화층발생 A.D. 3C ea-9 토광묘 8호 A EE R X S-W L-S X 풍화층발생 후반 ea-10 A EE R X G-D ND X ea-11 A EE R X G-D L-S X ea-12 A RR R X G-D L-S X Type:A;Annular Beads Closing:E;Edge,R;Round,-P:Polishied Color : R:Red Transparency: ;Transparent, ;Translucent,X;Opaque ( ):inner of gold foil glass Surface: GD;Good surface, S-W;Small Weathering layer, M-W;Much Weathering Bubble:L-S; Little Seed, M-S;Much Seed, L-B;Little Blister, M-B;Much Blister Crack: ;Serious crack, ;Some crack, X;No crack - 23 -
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Sample site color * Oxide Concentration(%) Number SiO 2 Na 2 O K 2 O CaO Al 2 O 3 MgO SO Cl TiO 2 MnO Fe 2 O 3 CuO Total ea-1 R(Χ) 72.5 15.9 0.78 1.6 3.5 0.47 0.41 0.64 1.4 0.12 1.4 2.6 101.3 0.4 0.5 0.03 0.1 0.1 0.05 0.02 0.01 0.1 0.05 0.1 0.1 1.6 ea-2 R(Χ) 62.9 19.4 1.9 3.0 8.6 0.26 0.45 0.44 1.5 0.11 1.6 1.0 101.1 0.3 0.2 0.1 0.1 0.3 0.08 0.03 0.04 0.1 0.03 0.1 0.1 1.4 ea-3 7호 R(Χ) 73.0 15.7 1.1 1.8 3.0 0.52 0.39 0.55 1.4 0.12 1.4 2.0 100.8 토광묘 0.3 0.1 0.1 0.1 0.1 0.09 0.06 0.02 0.1 0.05 0.1 0.2 1.2 ea-4 R(Χ) 63.1 16.5 2.3 3.8 9.1 0.37 0.30 0.48 2.0 0.08 1.9 1.1 101.0 0.6 0.4 0.1 0.4 0.2 0.24 0.05 0.02 0.1 0.04 0.1 0.2 2.5 ea-5 R(Χ) 63.6 18.9 1.9 2.3 8.3 0.12 0.28 0.36 1.4 0.10 1.5 1.3 99.9 0.5 0.2 0.1 0.1 0.1 0.04 0.02 0.03 0.1 0.05 0.1 0.1 1.3 ea-6 R(Χ) 70.9 15.8 0.80 1.7 3.4 0.35 0.43 0.64 1.4 0.16 1.4 2.6 99.7 0.2 0.1 0.03 0.0 0.0 0.06 0.04 0.02 0.2 0.04 0.1 0.2 1.0 ea-7 R(Χ) 63.2 18.6 1.1 2.0 6.8 0.65 0.36 0.91 1.9 0.17 2.3 1.0 99.1 0.2 0.2 0.0 0.0 0.1 0.06 0.02 0.03 0.2 0.06 0.1 0.2 1.3 ea-8 R(Χ) 61.9 18.5 1.9 3.0 8.3 0.19 0.45 0.44 1.6 0.17 1.5 0.92 98.6 0.7 0.7 0.1 0.1 0.1 0.06 0.03 0.03 0.2 0.11 0.1 0.1 2.2 ea-9 8호 R(Χ) 71.9 14.8 1.2 1.7 3.3 0.58 0.33 0.51 1.4 0.11 1.5 2.0 99.3 토광묘 0.3 0.3 0.1 0.1 0.3 0.11 0.07 0.07 0.2 0.07 0.1 0.1 2.0 ea-10 R(Χ) 66.9 16.8 1.3 1.9 4.8 0.92 0.39 0.82 1.6 0.14 1.7 1.2 98.5 0.2 0.1 0.0 0.1 0.1 0.07 0.02 0.02 0.1 0.07 0.1 0.1 0.9 ea-11 R(Χ) 67.2 16.5 1.3 2.0 4.8 0.92 0.38 0.80 1.8 0.07 1.7 1.1 98.5 0.2 0.2 0.1 0.2 0.1 0.11 0.05 0.05 0.1 0.04 0.1 0.1 1.5 ea-12 R(Χ) 63.4 17.3 2.9 3.8 6.9 1.2 0.40 0.72 1.5 0.23 1.8 1.2 101.1 0.3 0.3 0.1 0.1 0.1 0.1 0.04 0.02 0.1 0.09 0.1 0.2 1.5 *Color : R;Red, ( X) ;Opaque(Transparen - 26 -
20.0 15.0 7호(5) 8호(7) K2O 10.0 5.0 Soda Group 0.0 0.0 5.0 10.0 15.0 20.0 Na2O 10.0 LCHA 7호(5) 8호(7) Al2O3 5.0 LCA-A 0.0 0.0 5.0 10.0 CaO - 27 -
4.5 LMHK 7호(5) 8호(7) 3.0 K2O 1.5 LMK 0.0 0.0 1.5 3.0 4.5 MgO - 28 -
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20.0 15.0 wt(%) 10.0 5.0 0.0 Na2O K2O MgO CaO Al2O3 C:A ratio ea-1 15.9 0.78 0.47 1.6 3.5 0.47 ea-3 15.7 1.1 0.52 1.8 3.0 0.59 ea-6 15.8 0.80 0.35 1.7 3.4 0.48 ea-9 14.8 1.2 0.58 1.7 3.3 0.50 ea-10 16.8 1.3 0.92 1.9 4.8 0.40 ea-11 16.5 1.3 0.92 2.0 4.8 0.43 ea-2 19.4 1.9 0.26 3.0 8.6 0.35 ea-4 16.5 2.3 0.37 3.8 9.1 0.42 ea-5 18.9 1.9 0.12 2.3 8.3 0.27 ea-7 18.6 1.1 0.65 2.0 6.8 0.29 ea-8 18.5 1.9 0.19 3.0 8.3 0.36 ea-12 17.3 2.9 1.2 3.8 6.9 0.55-30 -
Oxide Concentration(%) Type Color SiO 2 Na 2 O K 2 O CaO Al 2 O 3 MgO SO Cl TiO 2 MnO Fe 2 O 3 CuO Total ea-Ⅰ 70.4 15.9 1.1 1.8 3.8 0.63 0.39 0.66 1.5 0.12 1.5 1.9 99.7 R (6) 2.7 0.7 0.2 0.2 0.8 0.24 0.04 0.13 0.1 0.03 0.1 0.6 5.9 ea-Ⅱ 63.0 18.2 2.0 3.0 8.0 0.46 0.37 0.56 1.6 0.14 1.8 1.1 100.1 R (6) 0.6 1.1 0.6 0.8 0.9 0.39 0.08 0.21 0.3 0.06 0.3 0.1 5.4-31 -
3.0 wt(%) TiO2 MnO Fe2O3 CuO 2.0 1.0 0.0 R(ea-Ⅰ) Color R(ea-Ⅱ). - 32 -
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Table 6. 천안 두정동 유리의 가시적 특징 Sample Phase of remains Characteristic Number Site Century Type Closing Color Transparency Surface Bubble Crack 충남 천안 두정동 유적 dj-1 A EE-P lt-gb S-W L-S L-B dj-2 A lt-gb S-W M-S,L-B Ⅰ-토광묘 dj-3 4C 초반 A EE-P lt-gb M-S,L-B 5호 dj-4 A EE-P lt-gb S-W L-S dj-5 A lt-gb S-W M-S,L-B dj-6 C cut lt-gb M-W M-S,L-B X dj-7 GF EE-P colorless ( ) S-W(S-W) L-S(ND) ( ) dj-8 GF EE-P colorless ( ) M-W(S-W) L-S(L-S) ( ) dj-9 GF colorless G-D L-B X dj-10 A RR-P lt-gb S-W M-S,L-B dj-11 A lt-gb G-D M-S Ⅱ-토광묘 dj-12 4C 초반 A RR-P lt-pb S-W M-S,L-B 12호 dj-13 A RR-P lt-pb S-W M-S,M-B dj-14 A RR-P lt-pb S-W M-S,M-B dj-15 A RR-P lt-pb M-W M-S,M-B dj-16 A RR-P lt-pb S-W M-S,L-B dj-17 A RR-P lt-pb S-W M-S,M-B dj-18 A RR-P lt-pb M-W M-S,M-B Type:A;Annular Beads, C;Cyliderical Beads, GF:Gold Foil Beads Closing:E;Edge,R;Round,-P:Polishied Color : lt-gb :light greenish Blue, dk-gb:dark greenish Blue, BG:Bluish Green, lt-pb ; light Purplish Blue Transparency: ;Transparent, ;Translucent,X;Opaque ( ):inner of gold foil glass Surface: GD;Good surface, S-W;Small Weathering layer, M-W;Much Weathering Bubble:L-S; Little Seed, M-S;Much Seed, L-B;Little Blister, M-B;Much Blister Crack: ;Serious crack, ;Some crack, X;No crack Remark - 34 -
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Figure 14-2. 천안 두정동 유리의 단면 사진 - 36 -
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Table 7. 천안 두정동 유리의 화학조성 Sample Oxide Concentration(%) site color * Number SiO 2 Na 2 O K 2 O PbO CaO Al 2 O 3 MgO SO Cl TiO 2 MnO Fe 2 O 3 CuO BaO Total dj-1 lt-gb 68.1 16.4 3.3 2.7 4.5 1.1 0.50 0.20 0.75 0.04 1.6 1.36 99.7 0.3 1.8 0.0 0.1 0.2 0.1 0.04 0.03 0.17 0.03 0.1 0.12 2.8 dj-2 lt-gb 67.8 15.4 3.2 2.8 4.5 1.1 0.46 0.20 0.83 0.08 1.4 1.17 99.0 0.3 0.1 0.1 0.1 0.1 0.1 0.02 0.03 0.06 0.04 0.1 0.15 1.0 dj-3 Ⅰ-5호 lt-gb 68.6 16.0 2.9 2.2 4.1 1.2 0.44 0.28 0.81 0.07 1.7 1.13 99.4 토광묘 0.4 0.2 0.1 0.1 0.1 0.1 0.05 0.04 0.13 0.03 0.2 0.16 1.4 dj-4 lt-gb 66.4 16.9 2.3 3.7 4.7 1.3 0.45 0.15 0.89 0.12 1.5 0.94 99.5 0.2 0.2 0.1 0.1 0.1 0.05 0.05 0.03 0.12 0.04 0.1 0.10 1.0 dj-5 lt-gb 70.7 15.3 2.6 2.1 4.9 0.66 0.37 0.16 0.64 0.12 0.94 0.58 99.1 0.2 0.1 0.1 0.1 0.1 0.09 0.04 0.01 0.17 0.05 0.05 0.09 1.0 dj-6 lt-gb 44.3 5.2 31.5 2.5 0.2 1.2 0.82 0.29 0.07 0.11 0.59 12.1 98.9 0.2 0.1 0.3 0.0 0.1 0.1 0.08 0.14 0.06 0.05 0.17 0.3 1.3 dj-7out colorless 68.0 16.7 0.58 8.4 2.5 0.54 0.43 0.92 0.30 0.09 0.81 0.30 99.3 0.3 0.1 0.01 0.1 0.1 0.04 0.05 0.02 0.07 0.07 0.13 0.01 0.9 dj-7in colorless 69.8 15.9 0.74 7.4 2.2 0.40 0.41 0.81 0.23 0.09 0.85 0.08 99.0 0.3 0.2 0.05 0.1 0.0 0.05 0.03 0.03 0.09 0.06 0.10 0.08 1.0 dj-8out colorless 67.8 16.6 0.58 8.5 2.5 0.54 0.41 0.89 0.44 0.07 0.76 0.09 99.1 0.4 0.1 0.03 0.1 0.1 0.06 0.02 0.02 0.17 0.05 0.11 0.05 1.2 dj-8in colorless 69.9 15.9 0.80 7.3 2.2 0.44 0.38 0.85 0.24 0.11 0.84 0.10 99.1 0.2 0.3 0.04 0.1 0.1 0.08 0.03 0.04 0.07 0.03 0.13 0.12 1.2 dj-9out colorless 67.1 16.2 0.58 9.0 2.6 0.59 0.40 0.91 0.37 0.13 0.79 0.20 98.6 0.3 0.2 0.05 0.2 0.0 0.08 0.05 0.02 0.10 0.07 0.08 0.01 1.1 dj-10 lt-gb 71.0 15.6 2.7 2.1 4.8 0.64 0.39 0.15 0.46 0.11 0.99 0.51 99.5 0.3 0.1 0.1 0.1 0.1 0.05 0.04 0.01 0.11 0.07 0.09 0.12 1.2 dj-11 Ⅱ-12호 lt-gb 71.0 15.8 2.6 2.1 5.0 0.66 0.35 0.18 0.58 0.08 1.0 0.42 99.7 토광묘 0.6 0.2 0.0 0.1 0.2 0.07 0.02 0.02 0.16 0.04 0.1 0.23 1.7 dj-12 lt-pb 70.5 15.9 1.0 4.1 2.4 0.18 0.39 0.73 1.6 2.6 1.6 0.06 101.0 0.2 0.1 0.1 0.1 0.2 0.06 0.02 0.05 0.1 0.2 0.1 0.01 1.3 dj-13 lt-pb 70.4 16.0 0.90 4.0 2.3 0.17 0.42 0.77 1.5 2.7 1.5 0.10 100.6 0.3 0.1 0.06 0.1 0.1 0.04 0.04 0.02 0.2 0.1 0.1 0.04 1.1 dj-14 lt-pb 69.6 16.4 0.90 3.9 2.1 0.21 0.40 0.79 1.3 2.6 1.6 0.19 99.9 0.2 0.1 0.03 0.1 0.1 0.04 0.03 0.03 0.1 0.1 0.1 0.09 1.0 dj-15 lt-gb 65.4 16.9 2.2 2.4 7.7 0.74 0.31 0.92 1.4 0.12 1.1 1.13 100.3 1.3 0.8 0.2 0.5 0.9 0.43 0.04 0.02 0.6 0.02 0.2 0.31 5.1 dj-16 lt-pb 73.7 15.7 0.71 4.1 2.3 0.21 0.27 1.0 0.40 1.5 0.9 0.10 100.8 0.4 0.2 0.04 0.1 0.1 0.09 0.04 0.0 0.16 0.1 0.1 0.04 1.3 dj-17 lt-pb 72.0 15.9 0.50 4.3 2.1 0.27 0.21 0.89 0.78 2.0 1.0 0.21 100.2 0.4 0.2 0.03 0.1 0.1 0.07 0.05 0.03 0.09 0.1 0.1 0.04 1.2 dj-18 lt-pb 73.4 1.1 18.4 1.5 1.5 0.38 0.17 0.15 0.52 1.6 1.4 0.09 100.1 0.4 0.1 0.1 0.1 0.1 0.04 0.04 0.01 0.11 0.0 0.1 0.01 1.0 * Color : lt-gb;light greenish Blue, gb;greenish Blue, dk-gb;darkgreenish Blue, PB;Purplish Blue. - 38 -
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20.0 15.0 Potash Group Ⅰ-5호(5) Ⅱ-12호(13) K2O 10.0 5.0 Soda Group Lead-Barium Group 0.0 0.0 5.0 10.0 15.0 20.0 Na 2 O 10.0 HCLA Ⅰ-5호(5) Ⅱ-12호(13) Al2O3(%) 5.0 LCA-A HCLA 0.0 LCA-A 0.0 5.0 10.0 CaO(%) - 40 -
4.5 LMHK Ⅰ-5호(5) Ⅱ-12호(13) 3.0 K2O(%) 1.5 LMK 0.0 0.0 1.5 3.0 4.5 MgO(%) - 41 -
wt(% ) 15.0 10.0 5.0 0.0 Na2O K2O MgO CaO Al2O3 C:A ratio dj-7 16.3 0.66 0.47 7.9 2.4 3.3 dj-8 16.3 0.69 0.49 7.9 2.4 3.3 dj-9 16.2 0.58 0.59 9.0 2.6 3.5 dj-1 16.4 3.3 1.1 2.7 4.5 0.61 dj-2 15.4 3.2 1.1 2.8 4.1 0.67 dj-3 16.0 2.9 1.2 2.3 4.1 0.56 dj-4 16.9 2.3 1.3 3.7 4.7 0.79 dj-5 15.3 2.6 0.66 2.1 4.9 0.42 dj-10 15.6 2.7 0.64 1.7 4.8 0.35 dj-11 15.8 2.6 0.66 2.1 5.0 0.42 dj-15 16.9 2.2 0.74 2.4 7.7 0.31 dj-12 15.9 1.0 0.18 4.1 2.4 1.7 dj-13 16.0 0.90 0.17 4.0 2.3 1.7 dj-14 16.4 0.90 0.21 3.9 2.1 1.9 dj-16 15.7 0.71 0.21 3.5 2.3 1.6 dj-17 15.9 0.50 0.27 4.3 2.1 2.1-42 -
Type * Color Oxide Concentration(%) SiO 2 Na 2 OK 2 O CaO Al 2 O 3 MgO SO Cl TiO 2 MnO Fe 2 O 3 CuO Total dj-sⅠ Colorless 68.5 16.3 0.7 8.1 2.4 0.50 0.41 0.88 0.32 0.10 0.81 0.16 99.0 (3) 1.3 0.4 0.1 0.7 0.2 0.08 0.02 0.05 0.09 0.02 0.04 3.0 dj-sⅡ-a lt-gb 67.8 16.2 2.9 2.9 4.3 1.2 0.46 0.21 0.82 0.08 1.6 1.1 99.3 (4) 0.9 0.6 0.5 0.6 0.3 0.1 0.03 0.05 0.06 0.03 0.1 0.2 3.5 dj-sⅡ-b lt-gb 70.9 15.6 2.6 1.9 4.9 0.7 0.37 0.16 0.56 0.10 1.0 0.50 99.4 (3) 0.2 0.2 0.1 0.2 0.1 0.0 0.02 0.01 0.09 0.02 0.1 0.08 1.1 dj-sⅢ lt-pb 71.2 16.0 0.8 4.0 2.2 0.21 0.34 0.83 1.1 2.3 1.3 0.13 100.5 (5) 1.6 0.3 0.2 0.3 0.1 0.04 0.09 0.11 0.5 0.5 0.3 0.06 4.2 * Type : dj-s; 두정동 출토 소다유리 - 43 -
3.0 TiO2 MnO Fe2O3 CuO 2.5 dj-sⅢ 2.0 Potash Group wt(%) 1.5 dj-sⅡ 1.0 0.5 dj-sⅠ Lead-Barium Group 0.0 colorless lt-gb lt-pb lt-pb lt-gb Color - 44 -
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(b) in in (c) out out Sample Color Oxide Concentration (wt. %) Number (Transparence) SiO 2 Na 2 O K 2 O CaO Al 2 O 3 MgO SO 3 Cl TiO 2 MnO Fe 2 O 3 CuO Total GF-out Colorless(O) 67.6 16.5 0.58 8.6 2.5 0.56 0.41 0.91 0.37 0.11 0.78 0.20 99.0 (3) 0.5 0.3 0.01 0.3 0.1 0.02 0.01 0.01 0.07 0.03 0.02 0.10 1.4 GF-in Colorless(O) 69.9 15.9 0.77 7.4 2.2 0.42 0.39 0.83 0.24 0.10 0.85 0.09 99.0 (2) 0.1 0.1 0.04 0.1 0.1 0.03 0.02 0.03 0.01 0.01 0.01 0.01 0.3-46 -
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Sample Phase of remains Characteristic Number Site Century Type Closing Color Transparency Surface Bubble Crack yw-1 A Bk X M-W ND X yw-2 토광묘 37 4C 중반 C Bk X M-W ND X yw-3 Bk X M-W ND X yw-4 A RR lt-pb S-W L-S,L-B yw-5 토광묘 64 4C 중반 A RR lt-pb S-W M-S,L-B yw-6 A RR lt-pb S-W M-S,L-B yw-7 A RR-P lt-pb X S-W M-S X yw-8 토광묘 103 4C 중반 A RR-P lt-pb X M-W M-S,L-B yw-9 A RR-P lt-pb M-W M-S,L-B yw-10 lt-pb X M-W M-S yw-11 유구미상 4C 중반 lt-pb X M-W L-S yw-12 lt-pb X M-W L-S Remark Type:A;Annular Beads, C;Cyliderical Beads Closing:E;Edge,R;Round,-P:Polishied Color : BK;Black,dk-gB;dark greenish Blue, lt-pb;light Purplish Blue Transparency: ;Transparent, ;Translucent,X;Opaque ( ):inner of gold foil glass Surface: GD;Good surface, S-W;Small Weathering layer, M-W;Much Weathering Bubble:L-S; Little Seed, M-S;Much Seed, L-B;Little Blister, M-B;Much Blister Crack: ;Serious crack, ;Some crack, X;No crack - 48 -
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Sample Oxide Concentration(%) site color Number SiO 2 Na 2 O K 2 O CaO Al 2 O 3 MgO SO Cl TiO 2 MnO Fe 2 O 3 CuO Total yw-4 lt--pb 66.2 16.8 3.4 6.1 2.2 2.3 0.47 0.56 0.25 0.12 1.4 0.19 99.9 0.3 0.2 0.2 0.2 0.0 0.5 0.05 0.01 0.09 0.05 0.2 0.13 2.0 yw-5 64호 lt-pb 66.3 16.7 3.3 6.2 2.2 2.3 0.44 0.56 0.26 0.08 1.5 0.20 100.0 토광묘 0.4 0.5 0.3 0.2 0.2 0.6 0.02 0.03 0.12 0.06 0.3 0.08 2.8 yw-6 lt-pb 66.2 16.1 3.7 6.0 2.3 2.8 0.42 0.56 0.28 0.06 1.2 0.17 99.7 0.2 0.3 0.1 0.2 0.2 0.5 0.03 0.04 0.16 0.06 0.1 0.12 2.1 yw-7 PB 72.7 0.54 19.1 1.6 1.3 0.29 0.11 0.21 0.51 2.0 1.9 0.23 100.4 0.5 0.06 0.1 0.1 0.0 0.03 0.03 0.03 0.18 0.1 0.1 0.12 1.3 yw-8 103호 PB 73.4 0.47 18.8 1.6 1.2 0.25 0.12 0.17 0.50 1.7 1.7 0.06 99.9 토광묘 0.8 0.09 0.5 0.2 0.1 0.06 0.05 0.02 0.18 0.2 0.3 0.04 2.5 yw-9 PB 72.8 0.43 19.1 1.7 1.3 0.30 0.11 0.19 0.59 1.9 1.9 0.13 100.3 0.4 0.03 0.2 0.2 0.2 0.05 0.05 0.01 0.08 0.2 0.1 0.06 1.6 yw-10 lt-pb 65.8 15.9 2.8 7.5 2.6 2.8 0.35 0.66 0.37 0.12 1.7 0.17 100.7 0.5 0.1 0.1 0.1 0.1 0.1 0.02 0.03 0.22 0.06 0.1 0.15 1.6 yw-11 유구 lt-pb 66.2 15.8 2.7 7.5 2.6 2.6 0.37 0.67 0.49 0.12 1.6 0.26 100.8 미상 0.8 0.2 0.1 0.1 0.1 0.2 0.02 0.03 0.23 0.09 0.1 0.12 2.0 yw-12 lt-pb 65.7 15.8 2.6 7.6 2.6 2.7 0.34 0.64 0.40 0.11 1.6 0.21 100.3 0.3 0.2 0.1 0.2 0.1 0.1 0.05 0.02 0.20 0.05 0.1 0.13 1.4-51 -
20.0 15.0 Potash Group 64호(3) 103호(3) 유구미상(3) K2O(%) 10.0 5.0 Soda Group 0.0 0.0 5.0 10.0 15.0 20.0 Na 2 O(%) 3.0 2.5 103호(3) 2.0 Al2O3(%) 1.5 1.0 0.5 0.0 0.0 0.5 1.0 1.5 2.0 2.5 3.0 CaO(%) - 52 -
10.0 64호(3) 유구미상(3) Al2O3(%) 5.0 HCLA 0.0 0.0 5.0 10.0 CaO(%). 4.5 HMK 3.0 K2O 1.5 64호(3) 유구미상(3) 0.0 0.0 1.5 3.0 4.5 MgO. - 53 -
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20.0 wt(%) 15.0 10.0 5.0 0.0 Na2O K2O MgO CaO Al2O3 C:A ratio yw-7 0.54 19.1 0.29 1.6 1.3 1.3 yw-8 0.47 18.8 0.25 1.6 1.2 1.4 yw-9 0.43 19.1 0.30 1.7 1.3 1.3 yw-4 16.8 3.4 2.3 6.1 2.2 2.8 yw-5 16.7 3.3 2.3 6.2 2.2 2.8 yw-6 16.1 3.7 2.8 6.0 2.3 2.5 yw-10 15.9 2.8 2.8 7.5 2.6 2.9 yw-11 15.8 2.7 2.6 7.5 2.6 2.9 yw-12 15.8 2.6 2.7 7.6 2.6 2.9-55 -
Oxide Concentration(%) Type Color SiO 2 Na 2 O K 2 O CaO Al 2 O 3 MgO SO Cl TiO 2 MnO Fe 2 O 3 CuO Total yw-Ⅰ 72.9 0.48 19.0 1.6 1.2 0.28 0.11 0.19 0.53 1.9 1.8 0.14 100.2 lt-pb (3) 0.4 0.06 0.2 0.1 0.1 0.03 0.01 0.02 0.05 0.14 0.15 0.09 1.2 yw-Ⅱ 66.1 16.2 3.1 6.8 2.4 2.6 0.40 0.61 0.34 0.10 1.5 0.20 100.2 lt-pb (6) 0.2 0.4 0.4 0.8 0.2 0.2 0.05 0.05 0.09 0.03 0.19 0.03 2.8 3.0 TiO2 MnO Fe2O3 CuO 2.0 Potash Group wt(%) Soda Group 1.0 0.0 lt-pb Color lt-pb - 56 -
Sample Phase of remains Characteristic Number Site Century Type Closing Color Transparency Surface Bubble Crack 충남 공주 수촌리 유적 sch-1 A RR R X S-W L-B X sch-2 A RR R X S-W L-B X sch-3 A RR BG M-W M-S,M-B sch-4 A RR BG M-W M-B sch-5 A RR BG M-W M-B sch-6 A RR dk-gb M-W M-B Ⅱ-2호 sch-7 A RR dk-gb M-W M-S,M-B X 토광목곽묘 4C 후 sch-8 A RR dk-gb M-W M-S,L-B X sch-9 A RR dk-gb M-W L-S,L-B X sch-10 A RR dk-gb M-W M-S,M-B X sch-11 A RR dk-gb M-W M-S,M-B X sch-12 A RR dk-gb M-W M-S,L-B X sch-13 A RR dk-gb L-S,L-B X Type:A;Annular Beads Closing:E;Edge,R;Round,-P:Polishied Color :R:Red, BG:Bluish Green, dk-gb:dark greenish Blue Transparency: ;Transparent, ;Translucent,X;Opaque ( ):inner of gold foil glass Surface: GD;Good surface, S-W;Small Weathering layer, M-W;Much Weathering Bubble:L-S; Little Seed, M-S;Much Seed, L-B;Little Blister, M-B;Much Blister Crack: ;Serious crack, ;Some crack, X;No crack Remark - 57 -
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Sample site color * Oxide concentration (wt%) Number SiO 2 Na 2 O K 2 O CaO Al 2 O 3 MgO SO Cl TiO 2 MnO Fe 2 O 3 CuO Total sch-1 R 70.1 12.1 1.7 2.5 7.4 0.32 0.84 1.2 0.09 2.2 2.1 100.5 0.3 0.2 0.2 0.2 0.1 0.07 0.03 0.1 0.09 0.2 0.3 1.8 sch-2 R 69.1 12.7 1.7 2.5 7.2 0.38 0.75 1.1 0.04 2.3 2.5 100.2 0.6 0.3 0.1 0.1 0.1 0.10 0.04 0.1 0.14 0.1 0.3 1.9 sch-3 BG 71.1 13.3 1.6 2.2 7.0 0.30 0.62 0.59 0.10 1.8 1.5 100.1 0.5 0.2 0.0 0.2 0.1 0.11 0.04 0.13 0.10 0.1 0.1 1.6 sch-4 BG 69.5 14.0 1.7 2.1 6.9 0.35 0.59 0.64 0.20 1.7 1.3 99.0 0.6 0.1 0.0 0.1 0.1 0.04 0.07 0.07 0.05 0.1 0.1 1.4 sch-5 BG 69.1 15.6 1.7 2.1 7.0 0.26 0.61 0.60 0.09 1.6 1.3 100.0 0.8 0.2 0.0 0.1 0.1 0.11 0.05 0.07 0.11 0.2 0.2 2.0 sch-6 lt-pb 69.2 16.9 2.7 6.1 1.8 1.5 1.1 0.10 0.11 1.4 0.14 101.1 0.6 0.4 0.0 0.0 0.3 0.8 0.1 0.10 0.05 0.1 0.11 2.7 Ⅰ-2호 sch-7 lt-pb 68.9 16.2 2.2 6.2 1.9 2.0 0.74 0.11 0.09 1.4 0.19 99.9 목곽 1.0 0.3 0.2 0.5 0.3 1.3 0.23 0.09 0.09 0.4 0.16 4.5 토광묘 sch-8 lt-pb 69.8 16.0 2.0 6.4 1.9 2.2 0.80 0.11 0.00 1.4 0.27 100.8 1.28 0.22 0.11 0.7 0.46 1.76 0.22 0.08 0.00 0.5 0.10 5.4 sch-9 lt-pb 70.2 15.6 0.78 6.8 2.1 1.1 0.96 0.29 0.31 2.2 0.44 100.7 1.0 0.2 0.07 0.2 0.2 0.1 0.02 0.12 0.12 0.2 0.16 2.3 sch-10 lt-pb 68.4 17.4 2.1 6.3 1.2 3.0 0.93 0.09 0.00 1.3 0.28 100.8 1.0 0.2 0.1 0.1 0.1 0.4 0.10 0.09 0.00 0.2 0.20 2.6 ach-11 lt-pb 69.4 15.6 2.1 6.4 1.2 3.1 0.98 0.03 0.00 1.2 0.27 100.2 1.1 0.3 0.1 0.2 0.1 0.3 0.09 0.08 0.05 0.2 0.07 2.6 sch-12 lt-pb 71.4 15.4 0.68 6.3 1.7 0.44 0.91 0.15 0.16 1.9 0.56 99.5 0.5 0.5 0.12 0.2 0.1 0.07 0.06 0.09 0.06 0.0 0.12 1.9 sch-13 lt-pb 73.2 14.3 0.42 6.6 1.7 0.49 1.1 0.13 0.03 1.4 0.37 99.8 0.4 0.2 0.04 0.1 0.1 0.07 0.1 0.09 0.00 0.2 0.10 1.4 color : R; Red, BG;Bluih Green, lt-gb;light greenish Blue - 61 -
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20 Ⅰ-2호(13) 15 K2O(%) 10 5 Soda Group 0 0 5 10 15 20 Na 2 O(%) 10.0 LCHA Ⅰ-2호(13) Al2O3(%) 5.0 HCLA 0.0 0.0 5.0 10.0 CaO(%) - 63 -
4.5 LMHK HM K Ⅰ-2호(13) 3.0 K2O(%) 1.5 LMK 0.0 0.0 1.5 3.0 4.5 MgO(%) - 64 -
20.0 15.0 wt(%) 10.0 5.0 0.0 Na2O K2O MgO CaO Al2O3 C:A ratio sch-1 12.1 1.7 0.32 2.5 7.4 0.34 sch-2 12.7 1.7 0.38 2.5 7.2 0.34 sch-3 13.3 1.6 0.30 2.2 7.0 0.31 sch-4 14.0 1.7 0.35 2.1 6.9 0.31 sch-5 15.6 1.7 0.26 2.1 7.0 0.30 sch-6 16.9 2.7 1.5 6.1 1.8 3.3 sch-7 16.2 2.2 2.0 6.2 1.9 3.2 sch-8 16.0 2.0 2.2 6.9 1.9 3.5 sch-10 17.4 2.1 3.0 6.3 1.2 5.4 ach-11 15.6 2.1 3.1 6.4 1.2 5.5 sch-9 15.6 0.8 1.1 6.8 2.1 3.2 sch-12 15.4 0.68 0.44 6.3 1.7 3.8 sch-13 14.3 0.42 0.49 6.6 1.7 3.9-65 -
Oxide Concentration(%) Type color SiO 2 Na 2 O K 2 O CaO Al 2 O 3 MgO SO Cl TiO 2 MnO Fe 2 O 3 CuO Total sch-Ⅰ-a 69.6 12.4 1.7 2.5 7.3 0.35 0.79 1.2 0.06 2.2 2.3 100.4 R (2) 0.7 0.4 0.1 0.1 0.1 0.04 0.06 0.1 0.03 0.1 0.2 1.7 sch-Ⅰ-b 69.9 14.3 1.7 2.1 7.0 0.30 0.61 0.61 0.13 1.7 1.4 99.7 BG (3) 1.1 1.2 0.1 0.1 0.1 0.05 0.01 0.03 0.06 0.1 0.1 2.8 sch-Ⅱ-a 69.1 16.4 2.2 6.4 1.6 2.3 0.92 0.09 0.04 1.3 0.23 100.6 dk-gb (5) 0.2 0.1 0.1 2.8 0.1 0.6 0.1 0.01 0.03 0.1 0.1 4.2 sch-Ⅱ-b 71.6 15.1 0.63 6.5 1.8 0.67 1.0 0.19 0.17 1.8 0.46 100.0 dk-gb (3) 1.5 0.7 0.19 0.2 0.2 0.36 0.1 0.09 0.14 0.4 0.10 4.1 3.0 2.5 sch-Ⅰ-a TiO2 MnO Fe2O3 CuO wt(%) 2.0 1.5 1.0 sch-Ⅰ-b sch-Ⅱ-a sch-Ⅱ-b 0.5 0.0 R gb dk-gb dk-gb Color - 66 -
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Table 16. 충청남도 지역 고대유리의 색상과 주성분의 상관관계 LCA-A LMK, LMHK LCHA LMHK LCA-A LMHK LCHA LMHK CaO Al 2 O 3, MgO 1.5% (Low) HCLA LMK CaO Al 2 O 3, LCA-B,HCLA LMK, HMK MgO 1.5% Or HCLA LMK, HMK MgO 1.5% - 72 -
Glass Color * Group (Transparency) TiO 2 (%) MnO(%) Fe 2 O 3 (%) CuO(%) SUM (%) R(Χ) 1.5 0.12 1.7 1.6 5.0 0.2 0.05 0.3 0.6 1.2 soda glass potash glass Oxide Concentration(wt%) Colorless( ) 0.32 0.10 0.81 0.16 1.4 0.09 0.02 0.04 0.09 0.2 lt-gb( ) 0.71 0.09 1.3 0.87 3.0 0.15 0.03 0.3 0.37 0.9 BG( ) 0.61 0.13 1.7 1.4 3.8 0.03 0.06 0.1 0.1 0.3 dk-gb( ) 0.13 0.09 1.5 0.31 2.0 0.08 0.11 0.3 0.14 0.7 lt-pb-a(( ) 0.34 0.1 1.5 0.20 2.1 0.09 0.0 0.2 0.03 0.3 lt-pb-b( ) 1.1 2.3 1.3 0.13 4.9 0.51 0.5 0.3 0.06 1.5 lt-pb( ) 0.53 1.8 1.7 0.13 4.2 0.04 0.2 0.3 0.08 0.5 * Transparency : ;Transparent, ;Translucent, Χ;Opaque - 73 -
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