1 3 (200 12 ) J Koren Soc Occup Environ Hyg 200;1(3):290-300 이익진 안규동 조광성 김남수 이성수 이병국 Ik-Jin Lee Kyu-Dong Ahn Kwng-Sung Cho Nm-Su Kim Sung-Su Lee Byung-Kook Lee Institute of Industril Medicine, Soonchunhyng University Ⅰ 서 200 11 1, 200 12 22 ( 66 Tel 01-530-1761, E-mil kdong@schckr) 론
2 Ⅰ 서 론 (, XRF 1992), 2, (Lithrge; led oxide), (, 1999),, Ⅱ 연구대상및방법, -1 연구대상및 시기 -,, 6,, 1, 5-20 2003 3, 12 75,,,, 6,, 6, ( ( ) ), ( ), 2 (PCB),, 1 2, (, XRF(portle X-ry fluorescence) 2 시료채취및분석방법 2001) (AAS) EPA Method 6200 (Zenz, (ICP) 199) EPA Method 6200 X- XRF,, 10cm,,,, 20 50g 2 150, 60mesh, 1 (Pirkle, (2001) 199), XRF 2 3 2 smple 1960 cup 1/ mil mylr film (, 196) 1972 (, collr) 1/ mil 193 mylr film 196 3
3 ( ) A B C D E F G H 630 110 6 1 360 300 7 720 1975 1995 1977 1997 195 19 1993 1 19 ( ) (ton/ ) 3,250 3,119 500 913 3,760 2,000 50 19,000 ( ) ( ) ( /min) 92,23 33,05 1,559 62,10 51,570 6,35 1,003 6,939 3,36 11,570 13,957 1,512 1,55 2,3 12,72 23,25 20,000 5,1-10,720 26,660 13,60 3,512 9,299,,, Duncn Multiple Com- prison Test (% ( ) recovery rte) Bis I = n 109 Cd 1 2 =i X-ry Fluorescence (XL-309 led nlyser, (NIOSH, 1995; Tylor, 197) = ( - 1) NITON Corp, Bedford, Msschusetts) 분석량회수율 XRF EPA 첨가량 METHOD 6200 ( 1) Ⅲ 연구결과 3 Bis XRF 분석량첨가량 1 휴대용 XRF 의정확도및정밀도 Test Pltform( ) smple 첨가량 cup 3 자료분석 (coefficient of vrition, CV) Bis, (CV %) (overll (CV pooled %) SAS version 0(Stticl CV, CV pooled ) CV 3 { Anlysis System) CV pooled 3 (19mg/kg), (1,1620mg/kg), (NIOSH, 1995; OSHA, 1990) (5,5320mg/kg)}, ANOVA(Anlysis of Vrince) test 1 2 3 5 6 7 9 10 (19mg/kg) 26 290 33 30 10 51 60 6 539 5 (1,1620mg/kg) 1,1000 1,1100 1,1200 1,1300 1,100 1,100 1,110 1,1500 1,1600 1,1700 표준편차평균 ( 2) ( 3) ( : mg/kg) (5,5320mg/kg) 5,5600 5,5600 5,500 5,500 5,6000 5,6200 5,6300 5,600 5,6500 5,6600 XRF X-ry Fluorescence 2 (19mg/kg) 2196%, (1,1620mg/kg) 97%, (5,5320mg/kg) 101%, (CV %) (19mg/kg) 231%, (1,162mg/kg) 191%, (5,5320 mg/kg) 066% XRF ( ) (CV %)
START 1 Follow mnufcturers mnul for opertion of FPXRF instrumenttion in situ intrusive 3 Remove deris from soil surfce nd level surfce if necessry Tp soil to increse density nd compctness 3 Perform nlysis Collect smple from inch squre of soil No Follow preprtion procedure chieve your DQOs yes Thoroughly mix smple in eker or plstic g Monitor homogeniztion with sodium fluorescein dye 5 Dry 20-50 grms of smple for 2- hours t temp no greter thn 150 6 Ground smple until 90% of originl smple psses through 60-mesh sieve 6 Plce smple in polyethylene smple cup nd perform nlysis STOP METHOD 6200 Field portle X-ry Fluorescence spectrometry for the determintion of elementl concentrtions in soil nd sediment
5 ( 3) 2 토양중납농도에관한결과 The NITON test Pltform Plcing the NITON on the NITON Test Pltform Firmly ltching the NITON flt ginst the NITON Test Pltform 100mg/kg, 20 A G 21±2316mg/kg 230±3597 mg/kg 100 mg/kg 5 D 12±2512mg/kg, C 72,069±25mg/kg 1 00 mg/kg, 1,000mg/kg 6 100, 101 300 301 3 7 500ton, 501ton 2,000ton, 2,001ton 10,000ton 10,001ton (p<005) 30,000, 30,001 50,000 50,001 3
6 (M) (SD) Bis (%) (Rec %) (CV %) (CVpooled %) 15 1,1361 5,600 95 2173 3706 1197 22 1 2196 97 101 230 191 066 133 ( : mg/kg) ± A B C D E F G 21 ± 2316 3 ± 1073 7 ± 1197 69 ± 1105 77 ± 119 57 ± 1323 230 ± 3597 59 67 9 5 9 3 73 95 119 106 113 11 130 ( : mg/kg) ± A B C D E F G H 20 5 7 11 3,21 ± 269 1,59 ± 1066 72,069 ± 25 12 ± 2512 667 ± 2622 1,932 ± 635 9,793 ± 660 5,65 ± 705 1,00 1,26 23,00 1,267 1221 12515 2,103 1236 3,233 251,333 16,000 157,913 3,296 239,000 665,333 397,000 ( ) ± (mg/kg) 100 101-300 301 21 16 3 3,5 ± 175 5,500 ± 1257 2,39 ± 3 pvlue 0599 (ton/ ) ± (mg/kg) Duncn grouping(r) 500 501-2,000 2,001-10,000 10,001 13 16 35 11 21,102 ± 7 1,5 ± 1767 2,002 ± 65 5,65 ± 7055 Fvlue pvlue 510 0003 (r) 005,
7 ( ) ± (mg/kg) Duncn grouping 30,000 30,001-50,000 50,001 Fvlue pvlue 13 16 6 21,102 ± 7 5,500 ± 1257 1,761 ± 557 53 00005 ( ) ± (mg/kg) 15,000 15,001-50,000 50,000 2 36 11,257 ± 1127 2,521 ± 7676 5,65 ± 77055 pvlue 057 (p<005), 10 30,000 50,001 ( / ) 9 200, 201 300 301 11 3 15,000, 15,001 5,000 /min, 5,001 50,000 50,001 3 /min 10,000 /min, 10,001 (p<005) /min 20,000 /min 20,001 /min / ( ) ± (mg/kg) Duncn grouping 200 201-300 301 Fvlue pvlue 21 39 15 20,2 ± 779 3,273 ± 511 33 ± 30 c 2636 00001 ( /min) ± (mg/kg) Duncn grouping 5,000 5,001-10,000 10,001-20,000 20,001 Fvlue pvlue 13 36 1 21,102 ± 7 1,59 ± 1067 2,521 ± 7676 2,71 ± 69 23 0003
/ ( ) ± (mg/kg) Duncn grouping 030 031-09 050 Fvlue pvlue 13 39 23 21,102 ± 7 5,3 ± 533 576 ± 5933 c 1992 00001 (p<005) 1 13 100 12, 101 300, 301 190, 191 1990 3 ( /, 1991 1995 1996 ) (p<005), 030, 031 09 050 3 (p<005) (p<005) Ⅳ 고찰 1,,,,, ( ) ± (mg/kg) Duncn grouping 190 191 1990 1991 1995 1996 25 26 16 5,992 ± 73,62 ± 50 3,956 ± 10799 12 ± 25192 Fvlue pvlue 695 0000 ( ) ± (mg/kg) Duncn grouping 100 101-300 301 21 27 1,933 ± 105 3,5 ± 635 2,10 ± 3267 Fvlue pvlue 331 003
9 0-313mg/kg 76mg/kg 11-5mg/kg 26mg/kg (2000), 1997 71mg/kg, 199 906mg/kg 52mg/kg, 716mg/kg, 5177mg/kg, 761mg/kg 57-230mg/kg, 12-72,069mg/kg (1973) 950mg/kg 26 XRF 100mg/kg 9739, (1997) 35km 1132-39mg/kg,, Ⅴ 결 론, 6,, 1, TEL(Tetr-ethyl led),,, X-ry fluorescence(xrf), 17mg/kg(Rose, 1979), 20ppm(, 192) Kloke (1979),,, (thresholds) 100mg/kg,,, 100mg/kg XRF (1996)
10 1 XRF 3 1999; 5(1): 9-65 2002 2002 (19mg/kg) 2196%, (1,1620mg/kg) 97%, REFERENCES 2001 (5,5320mg/kg) 101%,,,,, (CV %), - -, (19mg/kg) 231%, (1,1620 mg/kg) 191%, 1993; 30: Cd, P, Zn (5,5320mg/kg) 066% 22-237 1973; : 71-5 ( ) (CV %), Bernrd BP, Becker CE Environmentl led exposure nd kidney J Clin Tocicol 2000; 6: 9-15 19; 26: 1-3 2,, Clrk S, Menrth W, Chen M, Rod S, D 12± Succop P Use of field portle X-ry 2512mg/kg, C fluorescence nlyzer to determine the 72,069±25mg/kg 1996; 17(2): 192-20 concentrtion of led nd other metls 3,,,,,,, in soil smple Ann Agric Environ Med,, X-ry 1999; 6: 27-32 ( / ), fluorescence high volume ir smpler EPA(Environmentl Protection Agency), Anlyticl methods mnul; Method 200; No 6200, 199 ( (1): 71-76 Mnhn SE Fundmentls of environmentl chemistry Lewis Pulisher, / ),,,,, X-Ry (XRF) 1993, p 756,, MorleyJC,ClrkCS,DeddensJA,Ashely, 2001; 11(3): 235-20 K, Rod S Evlution of portle ( / ),, x-ry fluorescence instrument for the, determintion of led in workplce ir smples Applied Occuptionl nd 199; 1(2): Environmentl Hygiene 1999; 1: ( / ) 0-306-31 NIOSH A NIOSH technicl report; (p<005) Guidelines for ir smpling nd nlyticl method developmentl evlu- tion Cincinnti, OH: DHHS (NIOSH) 1992, p 9-12 Puliction, 1995,, NITON Corportion User's Guide Version 52 [Product Bulletin] NITON 1997; 0(): Corportion, Bedford, MA 199 (p<005) 32-36 OSHA(Occuptionl Sfety nd Helth Administrtion) Anlyticl methods XRF, 2000 mnul Method No 121, 1990,,,,, Pirkle JL, Brody DJ, Gunter Ew, Krmer RA, Pschl DC, Flegl MM, Mtte
11 TD The decline in lood led levels in the United Sttes JAMA 199; 272(): 2-291 Sterling DA, Lewis RD, Luke DA, Shdel BN A portle X-ry fluorescence instrument for nlyzing dust wipe smples for led; Evlution with field smples Environmentl Reserch Section A 2000; 3: 17-179 Tylor JK Qulity ssurnce of chemicl mesurement ed, Chelse MI, Lewis Pulishers Inc, 197 Zenz C Occuptionl medicine Yer Book Medicl Pulishers Inc, Chicgo, 199, pp 506-509