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1 바이오소재 Bio Polymer Co., Ltd

2 바이오소재 / 가톨릭대학교 / ( 사 ) 한국바이오소재패키징협회 가톨릭대학교생명공학기술응용 Application product by the Catholic Univ. of Biotechnology 바이오플라스틱 (Bio plastics) 생분해플라스틱 (Biodegradable plastics) 산화생분해플라스틱 (Oxo-biodegradable plastics) 바이오베이스플라스틱 (Bio based plastics) 응용제품 (Application products) 바이오비닐 (Bio Vinyl) 바이오시트 (Bio Sheet) 사출품 (Injection molding) 식품포장 (Food packaging) 기능성제품 (Functional products) 신선도 (Freshness) 항균 (Anti bacterial) 방충 (Anti insect) 멀칭필름 (Mulching film) 산업용품 (Industrial supplies) 에코패키징 (Eco-packaging) 3D 프린팅등 (3D printing etc.) 기타 (etc.) 바이오소재대표인사말 최근환경문제에대한사회적인식이높아지면서기업, 정부, 각가정에서도쓰레기나탄소배출량을줄이려는움직임이어느때보다활발합니다. 하지만아무리폐기물을줄이려해도시장한번보고나면쓰레기가한짐인이유는대부분의패키징 ( 포장재 ) 이나세제, 식품포장재, 화장품용기등이플라스틱, 스티로폼, 비닐로만들어졌기때문입니다. 안쓸수는없고, 하지만쓸때마다찜찜한 플라스틱을환경친화적재료로대체하여자연에서쉽게분해되고, 탄소배출량을최소화하며, 재활용이용이할뿐만아니라인체에무해한바이오소재및바이오플라스틱을적용한친환경제품에관심이집중되고있으며, 정부에서도저탄소녹색성장을국정전략의하나로설정하여바이오플라스틱산업발전을위한기반이마련되어있습니다. 바이오소재는저탄소녹색성장에일조하기위하여바이오플라스틱 ( 생분해, 산화생분해, 바이오베이스플라스틱 ) 제품이외에방충, 항균, 신선도등기능성을추가한제품을출시하였습니다. 국내외인증, 각종정부관련과제, 기술및특허연구개발에매진함으로써친환경글로벌추진에견인차가되도록최선을다하겠습니다. ( 주 ) 바이오소재대표이사, 가톨릭대학교생명공학과교수, ( 사 ) 한국바이오소재패키징협회회장 - 유영선 02

3 Bio Polymer Co., Ltd. / Korea Bio Material Packaging Association / Catholic Univ. of Korea 바이오매스 (Biomass) 란? / What is Biomass? 생명체 (Bio) 와덩어리 (Mass) 를결합시킨용어로 양적생물자원 이라는개념 Biomass is a combination of the words Bio and Mass. 바이오매스 (Biomass) 란생명체 (bio) 와덩어리 (mass) 를결합시킨용어로 양적생물자원 이란개념입니다. 바이오매스는재생가능한유기성자원으로사탕수수, 전분등농산물, 임산물등의셀룰로오스성분이외에클로렐라, 스피루리나등의미생물, 고래기름등도포함합니다. 즉, 모든생물체가바이오매스에속한다고볼수있습니다. 산업바이오 (White Bio) 범주에서는광합성작용의산물인식물체와미생물의대사산물, 해조류를지칭합니다. Biomass is a concept of Quantitative biotic resources. It is also a combination of the words bio and mass. Biomass is renewable biotic organic resource which includes all organisms such as cellulose in sugar canes, agricultural products such as starch and forest products as well as microorganisms such as chlorella, spirulina, animal life forms such as whales. White Bio refers to plant body, which is a product of photosynthesis and metabolite of microorganisms. 바이오플라스틱특성비교 / Compare Features for Each Type of Bioplastics Division 구분 Biomass content 바이오매스함량 Materials 사용원료 Kind of products 종류 Standard 규격기준 Feature 특징 Degradation mechanisms 분해기작 Plastics 플라스틱 Biodegradation period 생분해기간 Recycle 재활용 Product Price 제품가격 Biodegradable plastics 생분해플라스틱 Biomass base 바이오매스유래 More than 50-70% Natural, Microbial PLA, TPS, PHA, AP, CA etc. Petroleum base 석유계유래 Bioplastics / 바이오플라스틱 Oxo-biodegradable plastics 산화생분해플라스틱 Bio based plastics 바이오베이스플라스틱 Combined 결합형 Polymerized 중합형 - - More than 20-25% Petroleum polymerization PBS, PES, PVA, PCL, PBAT etc. ISO 14855, KSM ISO ASTM D 6400 etc. Biodegradability, Expensive, Poor physical properties Microbial degradation Anticle biodegradable oxidation, plants, etc. Oxo Bio-PE, Oxo Bio-PP etc. ASTM D 6954, UAE S 5009 KBMP-OBP-001 etc. Adjustable period of degradation, oxidative degradation Microbial degradation following oxidative degradation Natural-polymer conjugates Natural-monomer polymerization Bio-PE, Bio-PP, Bio-PET, Bio-PA etc. ASTM D 6866 CEN/TR etc. CO₂reduction, physical properties, Water resistance Not use Use Use 6 months 90% or more 6 months 60% or more - Impossible Possible (1-5years in Biodegradation) - Possible 4-5 $/kg $/kg $/kg 바이오플라스틱시장전망 / Market Prospect of Bio Plastics 글로벌바이오플라스틱시장현황및전망 Market trend & prospect of Global Bio Plastics 글로벌바이오플라스틱사업별소비비율 (%) consumption rate of Global Bio Plastics(%) 03

4 Notice of Certification / Application ID: 6244 June 28, 2018 Youngsun You Biopolymer Co., Ltd. #305, Business incubator, The Catholic University of Korea Bucheon-si, Dear Youngsun You, On behalf of the United States Department of Agriculture's (USDA's) BioPreferred program, I am pleased to inform you that your application for use of the USDA Certified Biobased Product Label for Think Green Bio Container has been approved as of March 05, The test result for Think Green Bio Container indicates that its biobased content is 88%. According to your application, you may now use the Label on the product Think Green Bio Container. The Label remains in effect as long as the product or package is manufactured and marketed in accordance with the approved application and requirements in the US Code of Federal Regulations Title Voluntary Labeling Program for Biobased Products unless one of the following conditions occurs: 1. Product or package reformulation: The product or package formulation of the certified product is changed such that the biobased content is reduced to a level below that reported in the approved application. When products have been reformulated, a new application for certification must be submitted in order to resume using the USDA Certified Biobased Product Label; and/or, 2. New minimum biobased content: USDA revises the minimum biobased content required for a product or package to be eligible to display the certification mark and the product or package does not meet the revised minimum. USDA will inform you that your certification is no longer valid. In this case, you must increase the biobased content of your product to be at or above the revised minimum and re-apply for certification within 60 days in order to continue to use the certification mark. Please note that all certifications are subject to USDA's periodic auditing activities. You must read the BioPreferred Brand Guidelines and Graphic Standards document prior to downloading label artwork (eauthentication login is required). This is your official notice of biobased product certification. Please print and save this should you need to provide certification documentation to any entity. The BioPreferred program looks forward to a long and successful partnership with you in the promotion of biobased products. If you have additional questions or would like further information, you may call the BioPreferred Program Information Line at (919) or us at BioPreferred_Support@amecfw.com. Sincerely, Kate Lewis Deputy Manager USDA BioPreferred Program 바이오소재 / 가톨릭대학교 / ( 사 ) 한국바이오소재패키징협회 인증, 시험분석현황 / Certificate, Test Report etc. Venture Certification 벤처인증 R&D Center 기업부설연구소인증 ISO 9001 ISO 농무성 USDA TGR-KBMP-900S Beta 성적서 39% TGR-KBMP-900S 농무성 USDA TGR Bio Wrap Beta 성적서 35% TGR Bio Wrap 농무성 USDA Bio Container Beta 성적서 88% Bio Container 녹색기술제품산업통상자원부 Green Tech Certi(Gov) Biodegradable Tech. 녹색전문기업환경부 Green Product Certi(Gov) Biodegradable product 녹색전문기업환경부 Specialized green company(gov) 녹색기술산업통상자원부 Green Tech Certi(Gov) Oxo-Bio Tech. 녹색기술제품산업통상자원부 Green Product Certi(Gov) Oxo-Bio Product 씽크그린 Think Green 04

5 Bio Polymer Co., Ltd. / Korea Bio Material Packaging Association / Catholic Univ. of Korea 인증, 시험분석현황 / Certificate, Test Report etc. BP 인증 Bio Based Certi EU 식품인증 LFGB(EU) 환경호르몬 Endocrine disrupter 식품포장 Food packaging FDA 다이옥신 Dioxine 전자렌지 Microwave oven 원적외선 Far infrared 내열성고주파적합성 Heat resistant Microwavable 알칼리해리성알칼리분해성 Water dispersibility 투습투기도흐림광택도 Air,Water permeability, Haze 비스페놀 A Bisphenol A 녹색기술농식품부 Green Tech Certi(Gov) Water Soluble Bio TGR Paper 녹색제품농식품부 Green Product Certi(Gov) TGR Paper 환경마크 Eco Lable (Gov) TGR paper 환경마크 Eco Lable (Gov) Food container 05

6 바이오소재 / 가톨릭대학교 / ( 사 ) 한국바이오소재패키징협회 비닐 / Vinyl M 자봉투, 쇼핑백, 링펀치, 롤백, 헤다봉투, 왕겨봉투, 멀칭필름, 담뱃갑등 M bags, Shopping bags, Ring Punch, Roll bags, Header bags, Bags containing rice husks, Mulching films, Cigarette Case etc. 기존난분해비닐제품과유사한물성, 강도, 신율을유지 산소배리어특성, 유연성, 내한성이매우우수 수요자가원하는규격, 종류, 인쇄색도, 강도등맞춤제작가능 생태계독성저감, 석유자원절약효과, 탄소저감효과우수 자연상태에서미생물, 온도, 수분등에의해생분해되어자연계로선순환 다양한제품으로적용가능 녹색인증 ( 정부 ) Green Certi (Gov) 탄소저감인증 Bio Based Certi. 생분해인증 ( 협회 ) KBMP Certi Maintains similar physical property, strength and elongation rate to existing plastic products, which show difficulty in degrading abilities Shows excellent qualities in oxygen barrier characteristics, flexibility and cold resistance Can be custom made to a customer s desire on sizes, types, print color, solidity etc. Excellence in reducing toxicity in the ecosystem, conserving oil resources and reducing Carbon Returns to the nature through microorganisms, temperature, moisture etc. in the natural state Is adaptable to a variety of different products 06

7 Bio Polymer Co., Ltd. / Korea Bio Material Packaging Association / Catholic Univ. of Korea 필름 / Film 녹색인증 ( 정부 ) Green Certi (Gov) 생분해인증 ( 협회 ) KBMP Certi TGR 바이오롤백 160 매 ( 중 )25cm 35cm TGR Bio Roll Bag 160EA 25cm 35cm 제품코드 /Code : 개 /Box TGR 바이오롤백 120 매 ( 중 )25cm 35cm TGR Bio Roll Bag 120EA 25cm 35cm 제품코드 /Code : 개 /Box TGR 바이오싱싱롤백 100 매 25cm 35cm TGR Bio Roll Bag 100EA 25cm 35cm 제품코드 /Code : TGR 바이오롤백 200 매 25cm 35cm TGR Bio Roll Bag 200EA 25cm 35cm 제품코드 /Code : TGR 바이오위생백 50 매 ( 중 )25cm 35cm TGR Bio Sanitary Bag 50EA 25cm 35cm 제품코드 /Code : 개 /Box TGR 바이오위생백 34 매 ( 소 )17cm 25cm TGR Bio Sanitary Bag 34EA 17cm 25cm 제품코드 /Code : TGR 바이오위생장갑 20 매 24cm 28cm Bio Sanitary grove 20EA 24cm 28cm 제품코드 /Code : 개 /Box TGR 바이오위생장갑 54 매 ( 중 )24cm 28cm Bio Sanitary grove 54EA 24cm 28cm 제품코드 /Code : 개 /Box TGR 바이오위생장갑 200 매 24cm 28cm TGR Sanitary grove 200EA 24cm 28cm 제품코드 /Code : 개 /Box TGR 바이오위생장갑 50 매 24cm 28cm TGR Sanitary grove 50EA 24cm 28cm 제품코드 /Code : 바이오더블지퍼백 20 매 25cm 30cm Bio fresh double zipper Bag 20EA 25cm 30cm 제품코드 /Code : 개 /Box TGR 바이오손잡이롤백 20 매 34cm 42cm Case size 4x9.5x4(H)cm TGR Bio Handle RollBag 제품코드 /Code : 개 /Box 07

8 바이오소재 / 가톨릭대학교 / ( 사 ) 한국바이오소재패키징협회 바이오랩 / Bio Wrap 녹색인증 ( 정부 ) Green Certi (Gov) 탄소저감인증 Bio Based Certi. 생분해인증 ( 협회 ) KBMP Certi 미국농무성인증 USDA Certi. 제품특장점 / Product Features 생태계독성저감, 석유자원절약효과, 이산화탄소저감효과우수 자연상태에서미생물, 온도, 수분등에의해분해되어자연계로선순환 바이오매스, 천연물등인체무해원료사용 인체에무해하여입에넣거나음식물과직접접촉하여도안전 방담기능부여 : 수분에의한김서림방지 Excellent in reducing toxicity in the ecosystem, conserving oil resources and reducing CO2 (35%) Returns to the nature through microorganisms, temp., moisture etc. in the natural state Use harmless materials to human such as biomass, natural substances etc. Harmless to the body and safe to put in the mouth or come in direct contact with food Anti fogging agent : defogging by moisture TGR 바이오랩 / 25cm 50m TGR Bio Wrap 제품코드 /Code : EA/Box TGR 바이오랩 / 30cm 50m TGR Bio Wrap 11.8in X 164ft 제품코드 /Code : EA/Box TGR 바이오랩 / 30cm 100m TGR Bio Wrap 11.8in X 328ft 제품코드 /Code : ea/Box, 45Box/Palette 30EA/Box TGR 바이오랩 / 13.5mic 43cm 1.450m TGR Bio Wrap 13.5mic x 17 X 47757ft 제품코드 /Code : TGR 바이오랩 / 8mic 46cm 457m TGR Bio Wrap 8mic x 18 X 15007ft 제품코드 /Code :

9 Bio Polymer Co., Ltd. / Korea Bio Material Packaging Association / Catholic Univ. of Korea 바이오랩비교표 / Bio Wrap Comparison Table 구분 Division PVC Wrap PE Wrap Bio Wrap 주요원료 Main raw materials 폴리비닐클로라이드, 가소제, 방담제등 Poly vinyl chloride, Plasticizer, Antifog agent etc. 폴리에틸렌, 점착성수지, 방담제등 Polyethylene, Adhesive resin, Antifog agent etc. 식물체성분, 에폭시대두유, 폴리비닐클로라이드, 방담제, 생분해촉매제등 Biomass, Epoxized soybean oil, Poly vinyl chloride, Antifog agent, Biodegradable catalyst etc. 장점 Advantages 전자레인지사용가능 투명 점착성우수 김서림방지효과 Microwavable Transparency Good stickiness Antifog effect 전자레인지사용가능 재활용성 Microwavable Recyclability 전자레인지사용가능 투명 점착성우수 김서림방지효과 투기, 투습성우수 Microwavable Transparency Good stickiness Antifog effect Gas, Moisture permeability 단점 Disadvantages 소각성저하 Bad incineration 신축성저하 점착력부족 Low flexibility Low stickiness 가격경쟁력저하 High price 프탈레이트계가소제사용여부 Use of phthalate plasticizer 분해가능여부 Decomposability 환경부규제여부 Ministry of Environment regulation 이산화탄소저감 Carbon dioxide reduction 모름식물성가소제로대체 - unknown Replace with vegetable plasticizer 300년이상 300년이상 1~2년 ( 조절가능 ) More than 300 years More than 300 years 1~2 years(adjustable) X X O 보유인증 Retention authentication FDA, LFGB FDA, LFGB FDA, LFGB 미국농무성 (USDA) 인증, 녹색인증 ( 산업통상자원부 ) 씽크그린인증 바이오베이스인증 (BP인증) 등 USDA certif. Green certif. Think Green certif. Bio based certif. 탁월한점착력 Good stickiness 전자레인지 OK Microwavable 순식물성첨가 Plant Biomass 신선도유지 Freshness 식품용 Food Grade 09

10 바이오소재 / 가톨릭대학교 / ( 사 ) 한국바이오소재패키징협회 녹색인증 ( 정부 ) Green Certi (Gov) 탄소저감인증 Bio Based Certi. 생분해인증 ( 협회 ) KBMP Certi 미국농무성인증 USDA Certi. 환경마트 ( 정부 ) Eco Label 원료특장점 / Product Features BBP 주의사항 / BBP Precaution ㅇ수분흡수우려가있으므로, 개봉후즉시사용권장ㅇ We recommend you to use it immediately after unsealing it as it could absorb moisture TGR-BBP (Bio Based) TGR-G03 M/B Biodegradable Catalyst KBMP-900S (Bio degradable) (Starch, Bamboo, Mugwort etc.) TGR-001 M/B Biodegradable Catalyst TGR-00A M/B Biodegradable Catalyst TGR-G10 (Vinyl,Sheet etc.) TGR-G10-IM (Injection molding) 원료의종류 / Product Grade 품목명 Product name 특성 Characteristic 종류 Types 판매단위 Sales unit TGR 산화생분해 Oxo-biodegradable TGR-001, TGR-G03, TGR-00A etc. 1, 5, 25kg, 500kg BBP 탄소저감 Carbon reduction 식물체부산물 ( 왕겨, 참숯, 대나무등 ) Plant by-product (Chaff, charcoal, bamboo etc.) 1, 5, 25kg, 500kg KBMP-900S 생분해 Biodegradable 전분, 대나무, 쑥등식물체 Plant biomass (Starch, bamboo, mugwort etc.) 1, 5, 25kg, 500kg EH-X F-lite 신선도유지, 다양한활용성 Freshness prolongation, Various application EH-X, F-lite EH-X plus, EH-X premium 1, 5, 25kg, 500kg 대량구매시별도상담 / Separate counseling when a large purchase 고객센터로문의주시기바랍니다. ( 고객센터 : ) Please contact the Customer Center ( ) 10

11 Bio Polymer Co., Ltd. / Korea Bio Material Packaging Association / Catholic Univ. of Korea 진공성형 / Vacuum Forming 원형접시, 사각트레이, 국밥공기, 전자트레이등 Round Plates, Rectangular Trays, Soup Bowls, Tray for electronics etc. 녹색인증 ( 정부 ) Green Certi (Gov) 탄소저감인증 Bio Based Certi. 생분해인증 ( 협회 ) KBMP Certi 환경마트 ( 정부 ) Eco Label 바이오매스, 식품첨가물등인체에무해원료사용 재활용가능, 사용후폐기시퇴비가되어자연계로선순환되는친환경제품 우수한내수성, 내유성으로사용이편리뛰어난내열성 ( 상온 ~120 ) : 밥, 국물등뜨거운내용물을담아도열변형없음 전자레인지사용가능소각시다이옥신등환경호르몬이발생하지않음 Harmless to the body materials, such as Biomass and food additives are used as raw materials Recyclable. Eco-friendly products, which will return to the natural cycle as fertilizer when discarded aster use Convenient to use due to excellent heat resistance and greaseproof characteristics Excellent heat resistance(room temperature to 120 ) : No heat deflection when used for hot contents such as rice or soup Microwavable Will not produce Endocrine disruptors such as Dioxin when burned 시트 - 백색, 내츄럴 Sheet - white, natural 시트 - 검정색 Sheet - black 투명시트 Transparent sheet 제품주문생산 / Product - order production 씽크그린씰링용기 18c 12 4cm Think Green sealing container cm 제품코드 /Code : 씽크그린 3 구씰링용기 cm Think Green 3 hole sealing container cm 제품코드 /Code : 씽크그린면용기 Ф19 5cm Think Green noodles container Ф19 5cm 제품코드 /Code : 씽크그린 5 구도시락용기 cm Think Green 5hole lunch container cm 제품코드 /Code : 씽크그린 4 각용기 cm Think Green squre container cm 제품코드 /Code : 씽크그린 4 각용기 cm Think Green squre container cm 제품코드 /Code : 씽크그린 4 각용기 cm Think Green squre container cm 제품코드 /Code : 씽크그린 4 각용기 cm Think Green squre container cm 제품코드 /Code : 씽크그린탕용기 Ф cm Think Green circular container Ф cm 제품코드 /Code : 11

12 바이오소재 / 가톨릭대학교 / ( 사 ) 한국바이오소재패키징협회 사출성형 / Injection Molding 녹색인증 ( 정부 ) Green Certi (Gov) 생분해인증 ( 협회 ) KBMP Certi 바이오푸드트레이 3p 세트 / Size 45X28.5X10cm 보관용기대 (6L), 채반 ( 대 ), 뚜껑 ( 대 ) Bio Food Tray 3p Set Container : 6L, Colander, Lid 제품코드 /Code :3p 개 /Box 바이오멀티워싱볼 cm Bio Multi Washing Bowl 제품코드 /Code : 개 /Box 12

13 Bio Polymer Co., Ltd. / Korea Bio Material Packaging Association / Catholic Univ. of Korea 사출성형 / Injection Molding 녹색인증 ( 정부 ) Green Certi (Gov) 생분해인증 ( 협회 ) KBMP Certi 미국농무성인증 USDA Certi. 바이오싱싱락 1 호세트 1.5L, 2.5L Bio Container Set No.1 1.5L, 2.5L 제품코드 /Code : 바이오싱싱락 2 호세트 4.6L, 2.5L Bio Container Set No.2 4.6L, 2.5L 제품코드 /Code : 바이오쿡앤글라스 4 개세트 400ml 4 Bio Cook&Glass 4ea Set 400ml 4 제품코드 /Code : 개 /Box 바이오아크릴쟁반 2 종세트대 / 중 cm Bio Acryl Tray 2EA Set L / M cm 제품코드 /Code : 2p 개 /Box 바이오아크릴쟁반 3 종세트대 / 중 cm / 소 cm Bio Acryl Tray 3EA Set L / M cm / S cm 제품코드 /Code : 3p ea/Box 13

14 바이오소재 / 가톨릭대학교 / ( 사 ) 한국바이오소재패키징협회 물에녹는수용성생분해코팅특장점 / Water Soluble Biodegradable coating Features 천연물, 바이오매스, 수용성고분자로코팅하여사용후폐기시자연에서생분해 물에완전히해리되어재활용용이전자레인지사용가능 인체무해, 친환경코팅 : 비닐코팅이아님생산시파지, 스크랩은재활용가능 Biodegrades in nature when disposed due to the use of natural substances, Biomass, and water soluble polymer coating Easy to recycle due to the characteristic to completely dissociate in water Microwavable Harmless to the body, Eco-friendly coating: Not plastic coatings Scrap and scratch papers produced during production can be recycled 구분 Division 특장점 Features 단점 Disadvangages 기존비닐코팅 Existing Vinyl Coating 내수성, 내유성, 열실링성매우우수 접힘부위크랙현상없음 Excellent in Water proof, Oil proof, Heat sealing No Crack phenomenon on folded part 재활용어려움 Difficulty in Recycling 수용성코팅지 Water Soluble Coating Paper 인체무해, 환경유해물질無 재활용용이 Harmless to the body, No environmental harmful substances Easy Recycling 접힘부위크랙현상있을수있음 Possible Crack phenomenon on folded part 생분해기간 Biodegradation Period 베리어성 Barrier 투기도 Gas Permeability 투습도 Water Vaper Permeability - 5 이하 less than 5 30 이하 less than 30 * 내유성, 내수성, 열실링성동등수준 * Same level in Oil proof, Water proof, Heat Sealing 자연분해 ( 생분해성 -6 개월 ) Biodegradation (6 Months) 500 이상 more than 이상 more than 800 응용제품 / Product application 식품포장재 : 햄버거, 도넛, 김밥, 종이컵, 라면컵등 기능성추가 : 방충, 신선도, 항균등 Food packaging : Hamburger, Donut, Gimbap, Paper cup, Ramen cup etc. Additional Functionality : Anti insect, Freshness, Anti bacterial etc. 내유성, 내수성, 산소차단성, 방습, 열접착성, 재활용성, 자연분해성등의기능을선택적으로부여하여각종포장재의대체품으로개발및확장생산가능 Available development & extended production as replacement of various packaging by assigning selectively various function(oil proof, Water proof, Oxygen barrier, Moisture proof, Heat adhesiveness, Recycling, Bio degradation etc.) 14

15 Bio Polymer Co., Ltd. / Korea Bio Material Packaging Association / Catholic Univ. of Korea 수용성코팅 / Water Soluble Coating 녹색인증 ( 정부 ) Green Certi (Gov) 생분해인증 ( 협회 ) KBMP Certi Recycling Paper Eco-friendly packaging 햄버거포장지 Hamburger Wrapping paper 23cm 23cm 제품코드 /Code 친환경종이컵 6.5oz Eco-friendly Paper cup 윗지름 Top diameter 72 아랫지름 Bottom diameter 50 높이 Height 75mm 용량 / 재질 volume / material : 약 195ml 180g 크라프트지 kraft 수량 quantity : 1,000 개 ( 박스 ) 제품코드 /Code 친환경종이컵 6.5oz Eco-friendly Paper cup 윗지름 Top diameter 72 아랫지름 Bottom diameter 50 높이 Height 75mm 용량 / 재질 volume / material : 약 195ml 190g 식품지 food paper 수량 quantity : 1,000EA/Box 제품코드 /Code 친환경종이컵 10oz Eco-friendly Paper cup 윗지름 Top diameter 84 아랫지름 Bottom diameter 62 높이 Height 98mm 용량 / 재질 volume / material : 약 300ml 350g 식품지 food paper 수량 quantity : 1,000EA/Box 제품코드 /Code 친환경종이컵 13oz Eco-friendly Paper cup 윗지름 Top diameter 84 아랫지름 Bottom diameter 62 높이 Height 117mm 용량 / 재질 volume / material : 약 300ml 350g 식품지 food paper 수량 quantity : 1,000EA/Box 제품코드 /Code 친환경종이호일 TGR Paper foil 30cm 20m 씽크그린 Think green 제품코드 /Code 15

16 바이오소재 / 가톨릭대학교 / ( 사 ) 한국바이오소재패키징협회 기능성제품 / Functional product 싱싱플러스적용보관 Keeping with fresh Plus 일반보관 Keeping without fresh Plus 45 일보관후 After 45 Days 7 일보관후 After 7 Days 45 일보관후 After 45 Days 7 일보관후 After 7 Days 신선도유지효과 1. 야채, 과일의에틸렌가스 ( 노화유발물질 ) 를분해합니다. 2. 천연유래항균물질이부패균의활성화를억제합니다. 3. 원적외선이방출되어곰팡이나박테리아를억제합니다. 4. 미세기공이있어야채, 과일의호흡을도와줍니다. 5. 톨루엔, 자일렌, VOC, 냄새성분등을분해합니다. 제품특징 1. 상온장기보관시에도휘발또는변질되지않음 2. 재사용이가능하며, 최초사용후 6 개월간신선도유지 3. 상온에서원적외선이발출되어신선도를유지방사율약 0.9 (5~20 μm / 37 상온실험 ) 4. 신선도유지성분함유 ( 미네랄, 이온화금속, 항균제, 다공성흡착제, 에틸렌가스분해촉매제, 기능성광물등 ) 신선도유지검증 1. 국가연구과제물농림축산식품부고부가가치식품기술개발사업연구과제친환경유사생체막식품포장기술개발신선농식품의생물학적안전성확보를위한관리시스템과제번호 ( / 가톨릭대유영선교수 ) 2. 한국식품저장유통학회발표물 인증사항 녹색기술인증 ( 환경부 GT ) 녹색전문기업인증 ( 환경부 GE ) FDA ( 미국식품의약국 ) 인증신선도유지물질 LFGB ( 독일식품용품법 ) 인증신선도유지물질씽크그린인증 (TGR-P0002) Freshness maintenance effect 1. Decomposes ethylene gas (aging inducer) of begetables and fruits 2. Naturally derived antimicrobial substances inhibit the activation of decay bacteria 3. Far infrared rays are emitted to suppress mold and bacteria 4. Micro-pores help to breathe vegetable and fruits 5. Disassemble toluene, xylene, VOC, and odor components Product Fratures 1. It does not volatilize of deteriorate even when stored at room temperature 2. It is reusable and keep freshness function for 6 months after first use 3. Far infrared rays are emitted at room temperature to maintain freshness Emissivity of about 0.9 (5~20 μm / 99 room temperature experiment) 4. Contains freshness maintenance ingredients(minerals, Ionized metal, antibacterial agent, porous adsorbent, ethylene gas decomposition catalyst, functional mineral etc.) Freshness maintenance verification 1. National Research Projects The Development of Biological Membrane-like Eco Food Packaging Containers Biological safety management system development for postharvest fresh organic agricultural mineral products 2. J. of food preservation Certification Green Technology Certification (Ministry of Environment GT ) Certified as a green professional enterprise (Ministry of Environment GE ) FDA (US Food and Drug Administration) certified Freshness Retention Substance LFGB (German Food and Drug Act) certified Freshness keeping material Think Green certification (TGR-P0002) 16

17 Bio Polymer Co., Ltd. / Korea Bio Material Packaging Association / Catholic Univ. of Korea 신선도제품 ( 롤백, 위생백등.) / Freshness Product(Roll Bag, Sanitary Bag etc.) 에버후레쉬롤백 200 매 25 cm 35 cm Everfresh Roll Bag 200EA 25 cm 35 cm 싱싱플러스팩 Freshness plus 9~10g/Bag 바이오롤백 200 매 25 cm 35 cm Bio Roll Bag 200EA 25 cm 35 cm 제품개요 / Product Information 신선도연장및악취제거 (Freshness Prolongation and Deodorizer) 에틸렌가스제거 & 숯불효과 (Remove Ethylene Gas & Charcoal Effect ) 생체내물의클러스터를작게하여수화성 (hydration) 이향상되어신선도유지 톨루엔, 자일렌, VOC, 냄새성분등의 C-H 체인절단 Maintains freshness minifying cluster into a living system and increasing hydration by emission radiation. C-H chain abscission of Toluene, Xylene, VOC, odor component, etc. 에틸렌가스를제거하여신선도유지기간연장가능 3 일이상연장 : 추가실험진행 숯불효과 : 숯중의원적외선 이노신산발생 Freshness Prolongation is possible, when removing ethylene gas causing sponge and drip effect in food Extend more than 3 days : extra experiment progression Far-infrared radiation from coal inosinic acid 미생물선택살균, 항균효과 (Alternative microbial sterilization, Antibacterial Effect) 방충효과 (Insect proof Effect) 발효등유익균 : 성장촉진효과 유해미생물, 바이러스 : 진동파가다름, 사멸 Fermentation, - beneficial bacteria : growth promotion effect Harmful microorganism, virus : different oscillating wave, extinction 생약추출물을적용한해충유입방지형방충포장 미세기공구조체및초정밀미세캡슐도입 Insect proof packaging with application of plants and herb medicine extracts. Highly detailed micro capsules introduced 17

18 바이오소재 / 가톨릭대학교 / ( 사 ) 한국바이오소재패키징협회 3D 프린팅, 기타적용제품 / 3D Printing, Product application 천연물, 바이오매스, 산화생분해첨가제, 미네랄등을주원료로하여사용후폐기시자연에서생분해 인체에무해하여입에넣거나음식물과직접접촉하여도안전 뜨거운음식, 끓는물속에서도열변형없음 다이옥신, 중금속등유해물질저감효과탁월 재활용, 재사용이가능 유아용, 성인용, 업소용등제품의종류다양 When discarded, biodegrades in nature due to the main materials : natural substance, biomass, oxo-biodegradable additive, minerals, etc. Is harmless to the body and safe to put in the mouth or come in direct contact with food No heat deflection in boiling water or when in contact with hot food Excellent in reducing harmful to the body materials such as dioxin and heavy materials Recyclable, Reusable Diverse products available : Baby, Adult, Business products 바이오사출품 Bio ijection molding 참숯용기 Charcoal Container 라이스볼 Rice Ball 숮숯칫솔 Charcoal toothbrush 제습용기 Dehumidification Container 3D 프린팅제품 / 3D printing products 화장품용기 Cosmetics Container 바이오렌지볼 Bio microwave range ball 주요적용제품 / Major Products 싱크그린제품 Think green products 바이오비닐, 필름 Bio vinyl, film 일회용품 Disposable products 진공성형 vaccum foaming 두부용기 - 펄프 Tofu container - Pulp 식품용기 Food packaging 사무용품 Office apploances 바이오파우치, 지퍼백등 Bio pouch, Zipper Bag etc. 멀칭필름 Mulching film 새싹키우기 Breed sprout kit 식품포장 Food&functional packaging 18 완충트레이 Buffer tray 뼈조립 - 교구 Bone assemble - Teaching aid 자동차부품 Car door trim 파렛트 Pallette (1100X1100mm)

19 Bio Polymer Co., Ltd. / Korea Bio Material Packaging Association / Catholic Univ. of Korea 농림수산, 토목건축 / Agriculture, Forestry and Construction 화분, 화분커버, 육묘포트, 농업용멀칭필름, 조경용품 Pots, Pot Covers, Seedling Pots, Agricultural Mulching Films, Landscaping Products, Etc. 유기물, 함량, 비료량, 일조량, 온도, 수분등에따라분해기간에차이가있음 자연상태에서미생물, 산소, 광등에의해분해되어자연계로선순환됨 자연조건에서 100일전후에분해가시작되어 9~12개월등이내 80% 이상분해 자연에서썩어서식물에영양분공급 분해기간중에분자량감소, 작은파편이되어토양내떼알구조를개선하여통기성, 투수성을개선하여지력을향상시킴 Degrading time differs according to contents of organic matter, fertilizers, sunlight, temperature, moisture etc. Degrades in natural state by microorganisms, oxygen, UV, etc. and returns to the natural cycle In natural state, will start to degrade in approximately 100 days and show 80% and above degradation within 1 year Will degrade in nature and become natural fertilizers During the degradation period, molecular weight will decrease and become small fragments to improve soil structure This will lead to improved soil fertility through improvement in air transmittance and water transmittance 건축자재 Building Materials 지아소리잠바닥재 Zia sorijam Flooring 조경분야 / Landscape 목재유래원료사용저감 벌레, 미생물, 햇빛, 수분등에목재보다강함 사용수명, 연장, 디자인이용이함 Decrease in costs derived from usage of wood Stronger than lumber in insect and microorganism resistance, sunshine, moisture, etc. Increase in usage life and easier to design & mold 화분, 화분커버 Pot, Pot Cover 식물키우기 Growing Plant 화분행거 Pot Hanger 화분행거 3 구 Pot Hanger(3) 친환경전시장 Eco Display 멀칭필름 Mulching Film 바이오매스화분 Biomass Pot 에코테이프화분 Eco Tape 테이프바인더 Tape Binder 바인더끈 Tape Application 19

20 바이오소재 / 가톨릭대학교 / ( 사 ) 한국바이오소재패키징협회 실험결과 / Bio plastics Test Data 열분해및광분해실험 / Pyrolysis & photolysis test Pyrolysis & photolysis - Modified ASTM D , humidity 85%, UV 분자량감소실험 / Molecular weight decrease & Carbonyl group test Hour TGR-001 Other company 300 5,050 Da 42,000 Da 400 3,800 Da 21,000 Da 700 Test end 7,500 Da 900 6,060 Da 1,400 5,010 Da ASTM D 6954 Tier 1 방식, 340nm, 50 ASTM D 6954 Tier nm, 50 OPP 필름, 1% 첨가제사용, GPC220 OPP film, 1% additive, GPC220. TGR 이약 4 배이상빠르게분해 TGR is 4 times faster degradation than the other company 분해전 / Before Degradation 분해후 / After Degradation Molecular weight decrease in 3,800~5,300 after degradation 40 days exposure to UV, the film was found in carbonyl groups 120 days exposure to heat, the film was found in carbonyl groups. 생분해실험 / Biodegradable test Contents Biodegradabilty Period Standard material 77.30% 45days Test substance 55.40% 45days Compared to Reference material Curve of biodegradability calculated by the average carbon dioxide emissions 71.67% 45days * 출처 / Source * 복합분해성식품포장용플라스틱, 산업식품공학-food Engineering Process, 7권 3호, Chung, M.s., Lee, W.H., You, Y.S., Kom, H.Y., Park, K.M., and Lee, S.Y Assessment and Applications of Multi-Degradable polyethylene Films as Packaging Materials. Food Sci. Biotechnol., 15(1) : Scott, G., Ed., 1993, Atmospheric Oxidation and Antioxidants, Elsevier, London 농산부산물인옥피, 대두피, 왕겨, 소맥피를이용한산화생분해바이오플라스틱필름개발 한국청정기술학회 - Clean technology, Vol.20, No.3, september 2014, pp.205~211 농산부산불인옥피, 대두피, 왕겨, 소맥피를이용한산화생분해바이오플라스틱필름개발 Development of Oxo-biodegradable Bio-Plastics Film Using Agriculture By-product such as Corn Husk, Soybean Husk, Rice Husk and Wheat Husk KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY Vol.22, No3 127~134(2016) 생분해촉매제를이용한산화생분해바이오필름개발 Development of Oxo-biodegradable Bio Film by Using Biodegradable Catalyst 20

21 Bio Polymer Co., Ltd. / Korea Bio Material Packaging Association / Catholic Univ. of Korea 실험결과 / Bio plastics Test Data 미생물배양실험 / Microorganism cultivation test - ASTM G22 : 37, relative humidity 85%, 60days - SEM : X 1,000 PE film Oxo-biodegradation Biodegradation 멀칭실험 / Mulching test Target crop : Chili(Red pepper) Test period : 05.4~ 05.11(7months) Joint research of Rural Development Administration PE film Oxo-biodegradation Biodegradation Initial installation 7 months later 인체무해성실험 / Toxicological test FDA, USDA, KFDA certification 1) FDA 3) KFDA Biodegradable pellet KBMP-900S Test report Materials test Test item Pb Cd Hg Cr6+ Unit Mg/kg Standards & Specifications Below 100 (In total) Test result Non detection (Detection limit 1) Non detection (Detection limit 1) Non detection (Detection limit 0.1) Non detection (Detection limit 1) Heavy metal by Pb Below 1.0 Below 1.0 2) USDA Biobased pellet, packaging ASTM D 6866 test report Radio carbon(c14) % Pellet(M/B) : 39% Product : 35%, 88% Migration test Potassium permanganate consumption Residues evaporated Below 10 1 By 4% acetic acid Below 30 5 Mg/L By H 2O Below 30 4 By n-heptane Below By 20% ethanol Below 30 3 Test method Korean Food Standards Codex 6, Standards and specifications : packaging of appliance and containers Eco-friendly packaging(product) test report 21

22 바이오소재 / 가톨릭대학교 / ( 사 ) 한국바이오소재패키징협회 고분자분해메커니즘 / Polymer degradable mechanism 1 단계 : 생분해성분의미생물분해및산화분해 제품에포함된생분해성분이분해되면서폴리머의물리적붕괴가일어남. ( 표면적증가 ) 물성강도및신장율이저하되고다공성상태의폴리머로진행됨. : 구조의약화 고분자의표면적증가에따른분해작용가속화진행 Degradation of biodegradable materials (Disintegration) Physical disintegration of polymer by biodegradation in the product Down the Strength & extension rate down, disintegrated to the porous polymer 2 단계 : 화학분해 ( 분자량감소 ) => 생분해로의전이 생분해로인해생성된카르복시산, 케톤류, 알데히드류등에의해자동산화진행 : 표면이점차친수성이되어 3 단계메커니즘진행 첨가된생분해촉매제의작용에의해열적 화학적분해가촉진됨. 폴리머의분자량이감소 : 무게의감소 Chemical degradation (molecular weight reduction) Auto-oxidation progress with carboxylic acid, ketones, aldehydes Chemical degradation accelerated with biodegradable catalyst M/B Molecular weight reduction (over 400,000 less than 10,000) 3 단계 : 미생물분해 ( 최종생분해 ) 분자량 : 40만 4만이하 : 폴리올레핀이저분자화되어알코올, 알데히드, 지방산등으로변화된후, 점차더욱분해되어물, 이산화탄소및바이오매스로변화됨 토양에존재하는각종박테리아, 세균, 효소등이저분자화한폴리머에작용하여완전히생분해됨. [1] 실제자연환경에서는 3가지분해가상호동시및상호보완적으로진행됨. Degradation with microbes (Biodegradation) Biodegradation to CO2, water by the action of bacteria, microorganisms and enzyme to the low molecular weight polymers. 3 kinds of degradation process are complementary and simultaneously go on in nature. [1] 분자량이 4 만이하로떨어지면, 첨가제등의작용이없어도미생물에의한분해가활발히진행됨. Microbiological degradation proceed actively without additives when molecular weight of polymer reduced under 40, G. Scott etc., Polymer Degradation and Stability Vol. 46, p.211~224(1994) 분자량감소실험 / Test of decrease MW 수십만의고분자량의폴리머는분해후의경우분자량이 5,000Da 정도로감소하였으며, 열에의한분해의경우에는분자량이 7,800 ~ 8,000 으로감소되었다. 저분자화된필름은미생물에의하여분해될수있으며, 이는바이오제품의생분해특성을확인시켜주는실험결과임. In cases of hundreds of thousands high MW polymer, after degradation, it decreased up to 10,000 ~ 20,000 and in cases of degradation by heat, MW was decreased to 7,800 ~ 8,000. Low MW films can be degraded by microorganisms. These test results show the biodegradable feature of bio product. See Prof. Albertsson,Royal Institute of Technology Stockholm and Prof. Guillet, The University of Toronto 적외선분광실험 / Test results of FT-IR 자외선, 열등의외부자극에노출시킨바이오제품에서는 1710 ~ 1750cm -1 의카르보닐 (carbonyl) 기가생성됨을확인하였다. 분해후바이오제품의중량평균분자량분포가확연하게낮은위치에있는것을확인하였으며, 장쇄고분자는저분자화흡수대를관찰할수없는반면, 40 일간광노출후의제품과 120 일간열노출된제품에서카르보닐흡수대를관찰할수있었다. 카르보닐기는플라스틱이분해되는과정에서생성되는물질이다. In bio product which have not been exposed to external stimulation such as UV or heat, we confirmed that 1710 ~ 1750cm -1 carbonyl was created. After degradation, bio products average MW distribution was considerably lowered and long chain polymer could not observe carbonyl absorption band. On the other hand, in the bio product which have been exposed to light for 40 days and the product which have been exposed to heat for 120days, carbonyl absorption band could be observed. Carbonyl group is a product by the degradation process of plastics. See e.g Scott, G., Ed., 1993, Atmospheric Oxidation and Antioxidants, Elsevier, London. 22

23 Bio Polymer Co., Ltd. / Korea Bio Material Packaging Association / Catholic Univ. of Korea 주요고객사, 현재및이전 / Major Client, current & past 코맥스 23

24 경기도부천시원미구지봉로 43 가톨릭대학교창업보육센터 305~306 호 #305~6 BI Center, The Catholic Univ., Wonmi Gu, Bucheon City, Gyeonggi Do, Korea T ~5 / F , tawake@naver.com 안산사무소 / 경기도안산시단원구광덕 4 로 144, A 동 504 호 ( 고잔동, 트윈타운 ) T / F 중국사무소 ( 난징 ) / China office(nanjing) Mr.chenhong@163.com,