삼양트리라이트이온교환수지소개 삼양사이온수지판매팀서울특별시종로구종로 33 길 31 TEL) 02-740-7732 7, FAX) 02-740-7709 http://samyangtrilite.com
1. Samyang Group Overview 2 /49 1924 년설립 / 종업원수 : 3,200 명 / 매출액 : 4.2 조원 (2018)
2. Product Line of Samyang Group 3 /49 ( 사업분야 ) ( 계열사 ) ( 생산제품 ) 삼양사 엔지니어링플라스틱 이온교환수지 (Gaussian) 정보전자소재 삼남석유화학 Terephthalic acid 삼양화성 Poly Carbonate 화학사업 상해 EP 삼양이노켐 엔지니어링플라스틱 Bisphenol-A 헝가리 EP 삼양화인테크놀로지 엔지니어링플라스틱 이온교환수지 ( 균일계 ) Samyang Corporation Samyang Petro-Chemicals Samyang Kasei Samyang Innochem Samyang Fine Technology 삼양패키징 PET Bottle PET Preform Aseptic Bottling 식품사업 삼양사 설탕감미료식용유 Homemade Mix 전분전분당당알콜건강기능식품화장품 삼양 F&B 세븐스프링스외식사업 상쾌환제과재료가공유지 Olive & Grape Seed Oil 진황도전분당 전분당 의약사업삼양바아오팜봉합사항암제패치제 기타 삼양데이타시스템 IT Service
3. Locations ( 본사, 공장, 테크센터 ) 4 /49 3 개분야의전문기술영업인력보유 - 수처리 / 초순수 / 응축수처리 (Condensate polishing)/ 촉매 - 전분당 / 핵산 / 아미노산 / 의약 - 폐수처리 / 킬레이트 / 특수정제 원스톱토탈솔루션제공 - 이온교환수지분석 - 설비진단 - 설계지원 - 기술세미나 - Trouble shooting guide Seoul Headquarter Technical Center Daejeon 이온교환수지분석 이온교환수지생산 Recipe 개선 신제품개발 - 주문품 / 특수품 응용기술개발 - Pilot test - Engineering data gathering - Process proposal UPS Resin Plant Gunsan Ulsan UPW/Tailored/Specialty Resin Plant Since 2016 일본미쓰비시케미칼과의합작법인 Production Capacity : 20,000 kl / 년 ( 양이온 13,000 kl / 년, 음이온 7,000 kl / 년 ) Product line - 균일계이온교환수지 - 초순수수지 (OLED, LCD) - 크로마토그래피수지 Since 1976 일본미쓰비시케미칼기술도입및자체개발 Production Capacity : 7,000 kl / 년 ( 양이온 4,000 kl / 년, 음이온 3,000 kl / 년 ) Product line - 초순수수지 ( 반도체 ) - 주문품수지 ( 전분당, 핵산, 촉매, 의약등 ) - 특수수지 ( 킬레이트, 합성흡착제등 )
4. Overview of Samyang Fine Technology Corp. 5 /49 삼양화인테크놀로지는신뢰의삼양사와기술의미쓰비시케미칼의합작법인으로서, 군산에위치한균일계이온교환수지전용공장입니다. 단일공장으로서아시아최대규모를자랑하고있으며엄격한품질관리및납기준수로고객사로부터호평을받고있습니다. History) 2016.04 준공식및본격출하개시 2015.12 상업운전개시 2014.01 삼양화인테크놀로지설립 2013.07 삼양사, 미쓰비시케미칼합작투자계약
5. Cutting-edge Technology Droplet Generator 6 /49 기존이온교환수지생산방식 균일계이온교환수지생산방식 ( 원부원료조정 ) ( 원부원료조정 ) + + ( 중합 - 교반 ) ( 중합 - 액적발생기 ) ( 후처리 교환기도입 ) ( 후처리 교환기도입 )
운전교환용량 (eq/l-resin) Conductivity ( μs / cm ) 6. Next Generation IER, high performance low cost 7 /49 기존이온교환수지는입자크기가균일하지않아반응이고르지않음 유효수지층을효율적으로사용할수없음 Conventional Resin UPS Resin 균일계수지는입자크기가균일하여않아반응이일정함 유효수지층을효율적사용하는것이가능함 빠른반응속도및차압감소 + 우수한물리화학적특성 운전교환용량이높고빠른처리수질확보로수세수량감소장시간이온교환수지사용이가능 경제적인운전및설비투자절감이가능함 30 1.5 25 1.3 균일계수지 () 20 1.1 0.9 기존이온교환수지 () 0.7 25 50 75 100 125 150 Specific Flow Rate (SV) 15 균일계수지 (Mixed) 10 기존이온교환수지 (Mixed) 5 0 0 10 20 30 40 50 60 70 80 90 100 110 120 Service Volume (Bed Volume)
8 /49 ( 입자크기, 입도분포, 균일계수 ) Gaussian (0.3 ~ 1.2mm) Gaussian(L) (0.425 ~ 1.2mm) 균일계 (0.5 ~ 0.6mm) 크로마토그래피 (0.2 ~ 0.3mm) ( 가교도, Crosslinkage) ( 세공성, Porosity) Low Crosslinkage High Crosslinkage Gel Type (Micropore) Micropore <100A Porous Type (Macropore) Macropore 10A <, <1000A ( 교환기, Functional Group) 양이온, Cation 음이온, Anion 특수품, Specialty 불활성, Inert 강산성 Strongly acidic () 약산성 Weakly acidic (WAC) 강염기성 Strongly Basic () 약염기성 Weakly Basic (WBA) 킬레이트 Chelate 합성흡착제 Synthetic Adsorbent For packed bed system For mixed bed polisher ( 추가후처리 / 주문품 ) 초순수 혼합, 건조 촉매 핵산, 라이신, 전분당등
9 /49 수처리 (Water treatment) 경수연화 (Softening) 순수 (Demineralization) 응축수처리 (Condensate polishing) 원자력발전수처리 (Nuclear power) 촉매 (Catalyst) 초순수 (Ultrapure water) 크로마토그래피 (Chromatography) F/G 분리 (Fructose/glucose separation) 아미노산정제 (Amino acid separation) 산회수 (Acid purification) 식품 (Food) 전분당정제 (Starch sugar refining) 설탕정제 (Sugar refining) 핵산, 라이신정제 (Nucleic acid, lysine separation) 킬레이트 (Chelating resins) 염수 2 차정제 ((Secondary brine purification) 폐수처리 (Wastewater treatment) 합성흡착제 (Synthetic adsorbents) 혼합수지 (Ready to use mixed resins) 복층상식 (Layered bed anion resins) 불활성수지 (Inert resins) EO/EG cycle water treatment
10 /49 ( 입자크기, 입도분포, 균일계수 ) Gaussian( 일반수지 ) Particle Size : 0.3 ~ 1.2mm 균일계수 : 1.6 Gaussian L-type Particle Size : 0.425 ~ 1.2mm 균일계수 : 1.4 균일계수지 Particle Size : 0.5 ~ 0.7mm 균일계수 : 1.1 ( 이온교환수지층에따른분류 ) ( 재생방식에따른분류 ) 단상탑 Single Bed WAC WBA 병류재생 Co-current Regeneration System 향류재생, Counter-current Regeneration System Water Blocking System Upflow System Packed Bed Downflow System Service Regeneration 복층상탑 Layered Bed WAC WBA Freeboard IER Middle Distributor Freeboard IER IER Freeboard IER Freeboard 혼상탑 Mixed Bed Gaussian Gaussian or L-type 균일계수지
11 /49 균일계수 (U.C) 강산성양이온교환수지 () 제품명 TEC (eq/l) 강염기성음이온교환수지 () Type TEC: Total Exchange Capacity 제품명 TEC (eq/l) Performance Product Line 균일계수지 ( 삼양화인테크놀로지 ) 1.1 MC-08 2.0 MA-12 1.3 MC-10 2.2 Type1 MA-10 1.35 MC-14 2.5 MA-15 1.4 Type2 MA-20 1.3 Basic Product Line Gaussian ( 삼양사울산공장 ) 1.4~ 1.6 SCR-B 2.0 SAR10 1.3 Type1 SAR12 1.3 Type2 SAR20 1.3 Economy Product Line 균일계수지 (OEM) Gaussian (OEM) 1.1~ 1.2 1.4~ 1.6 UKC-08 2.0 Type1 UKA-12 1.3 UKC-10 2.2 WBA AW80 1.5 UKC-12 2.3 KC-07 1.9 KA-10 Type1 1.3 KH-70 1.9 KA-12 1.3 KC-08 2.0 Type2 KA-20 1.3 KH-80 2.0
12 /49 TEC: Total Exchange Capacity Performance Basic Economy Performance Basic Economy Type 제품명 강산성양이온교환수지 () TEC (eq/l) 입도분포 Type 제품명 강염기성음이온교환수지 () TEC (eq/l) 입도분포 MC-08 2.0 0.55~0.65mm MA-12 1.3 0.53~0.63mm MC-08H 1.8 0.57~0.67mm MA-12OH 1.0 0.57~0.67mm 균일계 Gel MC-10 2.2 0.60~0.70mm MA-10 1.35 0.50~0.60mm Type1 MC-10H 1.9 0.61~0.71mm MA-10OH 1.0 0.54~0.64mm MC-14 2.5 MA-15 1.4 0.55~0.65mm 0.60~0.70mm MC-14H 2.4 MA-15OH 1.2 0.58~0.68mm Type2 MA-20 1.3 0.53~0.63mm Gaussian Gel (General type) SAR10(MB) 1.3 (General type) 0.3~1.2mm Type1 0.3~1.2mm SCR-B 2.0 (L-type) SAR12 1.3 (L-type) 0.425~1.2mm Type2 SAR20(MB) 1.3 0.425~1.2mm 균일계 Gel UKC-08 2.0 0.60~0.70mm Type1 UKA-12 1.2 0.55~0.65mm UKC-10 2.2 0.60~0.70mm Gaussian Gel 교환기 UKC-12 2.3 0.60~0.70 mm KC-07 1.9 KA-10 1.3 (General type) Type1 KH-70 1.9 KA-12 1.3 (General type) 0.3~1.2mm (L-type) 0.425~1.2mm KC-08 2.0 Type2 KA-20 1.3 KH-80 2.0 (Polystyrene+DVB) + Sulfonate (Polystyrene+DVB) + Type1 : TMA, trimethylamine Type2 : DMEA, dimethylethanolamine Type 약산성양이온교환수지 (WAC) 약염기성음이온교환수지 (WBA) 일반, 균일계 Porous 균일계 Porous Gaussian Porous WCA10L 4.2 0.425~1.2 mm WBA 0.3~1.2 mm (L-type) 0.425~1.2 mm AW90 1.6 0.50~0.60 mm AW80 1.6 0.50~0.60 mm AW30L 1.5 0.425~1.2 mm 교환기 (Polystyrene+DVB) + Carboxylate (Polystyrene+DVB) + Tertiary Amine
13 /49 경수연화장치 시스템 Softening Line (Industrial grade) Softening (Food grade) Performance MC-08 MC-10 Basic SCR-B Economy UKC-08 UKC-10, UKC-12 KC-07, KC-08 Economy KH-70 KH-80 WAC WBA Sodium hypochlorite(naclo), Free chlorine(cl2), Ozone(O3) Food grade softening 차아염소산소다 및 유리염소 등과 같은 산화제/살균제와 함께 경수연화장치를 사용할 경우 내산화성이 우수한 고가교도 강산성 이온교환수지가 추천된다 식품회사 등 Food grade softening이 필요할 경우 이에 적합한 Food grade 이온교환수지를 선택할 필요성이 있으며 사례는 아래와 같다 이온교환수지 선택 Performance MC-08 Basic SCR-B Economy Performance ClO2 농도 Cl2 or O3 농도 0.1ppm 0.2ppm MC-10 0.15ppm Economy Economy UKC-12 SCR-B SCR-BL (NSF 시험 방법) 100 의 이온교환수지를 70 100 의 물에 투입한 후, 시간이 경과하면서 APHA(색도의 단위)를 Visible Spectrophotometer로 측정 KC-07, KC-08 UKC-10 KH-80 0.2ppm 0.3ppm 0.4ppm 제품명 Grade Spec. 1일 2일 3일 4일 7일 KH-80 Food < 25 12 13 13 13 14 SCR-B Tech - 145 149 153 160 183 SCR-BL Tech - 53 55 191 257 347
14 /49 순수장치시스템 Line WAC WBA 2B2T (2Bed 2Tower) Cation Exchanger + Anion Exchanger 2B3T Cation Exchanger + Degasifier + Anion Exchanger D Performance Basic Economy MC-08 MC-10 SCR-B UKC-08 UKC-10 KC-08 MA-12 MA-20 SAR10 SAR20 UKA-12 KA-12 KA-20 Working MB (Mixed Bed) Performance Basic MC-08 SCR-B MA-20P SAR20MB 2B2T or 2B3T + MBP (Mixed Bed Polisher) D Performance Basic MC-08 MC-10 SCR-B MA-10P SAR10MB 3B3T+MBP D WBA Performance Basic Economy MC-08 MC-10 KA18LB AW90 SCR-B KA18LB AW80 UKC-08 UKC-10 KA18LB AW30L 4B3T+MBP WAC D WBA Performance Basic Economy MC-08 MC-10 KA18LB WCA10L AW90 SCR-B KA18LB WCA10L AW80 UKC-08 UKC-10 KA18LB WCA10L AW30L 4B3T+MBP+ CPP(Condensate Polisher) WAC D WBA Condenser Performance MC-10H MC-14H MA-10OH MA-15OH 음이온교환수지제품명뒤에붙는 (P) 는엉킴방지 (anti-clumping treatment) 처리를했다는의미임. 혼상탑에는 P 가붙은제품을사용하는것이추천됨.
15 /49 ( 일반적인발전소수처리 Flow 와이온교환수지의선택 ) Boiler 2 nd Superheater Reheater HP Turbine IP Turbine LP Turbine Generator 1 st Superheater Condenser Raw water Evaporator tube HP Heater Deaerator LP Heater Condensate storage WAC Make-up demineralization system Degasi -fier WBA Condensate polisher 수력학적특성이뛰어나고, 물리화학적으로안정하고양 / 음분리성이우수하여발전소의안정적운전을도모할수있다응축수처리용수지 (Condensate polishing resins) 강산성양이온교환수지 () 강염기성음이온교환수지 () Type 제품명 TEC (eq/l) 입도분포 Type 제품명 TEC (eq/l) 입도분포 Gaussian Porous CMP28L 2.05 AMP18L 1.3 Porous 0.425~1.2mm type1 CMP28LH 1.8 AMP18LOH 1.0 0.425~1.2 mm 균일계 Gel MC-10 2.2 0.60~0.70 mm MA-10 1.35 0.50~0.60 mm MC-10H 1.9 0.61~0.71mm Gel MA-10OH 1.0 0.54~0.64mm MC-14 2.5 type1 MA-15 1.4 0.55~0.65mm 0.60~0.70mm MC-14H 2.4 MA-15OH 1.2 0.58~0.68mm
16 /49 ( 일반적인원자력발전소수처리 Flow 와이온교환수지의선택 ) Nuclear grade (OH form) (Li form) Containment structure Nuclear reactor Steam generator HP Turbine LP Turbine Condenser Generator Primary circuit Secondary circuit (H form) Condensate storage Raw water Make-up demineralization system Storage tank HP Heater Deaerator LP Heater Condensate polisher WAC Degasi -fier WBA 고가교도수지는매우높은교환용량및매우낮은 TOC leakage 를나타내어최적의처리수질을조기에얻을수있다 H/OH 전환율이매우우수하고미량금속이온누출이현저하게낮아안정적인발전소가동을도모할수있다 원자력발전소용수지 (Primary circuit) 강산성양이온교환수지 () 강염기성음이온교환수지 () Type 제품명 TEC (eq/l) 입도분포 Type 제품명 TEC (eq/l) 입도분포 균일계 Gel MCN116K 2.4 0.60~0.70 mm Gel type1 MAN210K 1.1 0.58~0.65 mm MMN316K / Mixed Resin ratio = 1 : 1 as same equivalent (MCN116K : MAN210K)
17 /49 TEC: Total Exchange Capacity Gaussian Type Gel catalyst Porous Catalyst 제품명 TEC (eq/l) 촉매용강산성양이온교환수지 입도분포 Type 제품명 TEC (eq/l) 입도분포 PCC30H 1.1 Gel (General type) 균일계 MC-04H 1.2 0.47~0.57mm PCC40H 1.2 catalyst 0.3~1.2mm CMP08H 1.0 (L-type) Porous SPC400H 1.0 (General type) 0.425~1.2mm Catalyst CMP28H 2.0 SPC160H 1.5 0.3~1.2mm (XL-type) Gaussian SPC260H 1.7 SPC180H 1.5 (L-type) 0.7~1.2mm 0.425~1.2mm SPC280H 2.0 SPC320H 1.9 ( 촉매응용분야와촉매수지의선택 ) 응용분야반응 Mechanism 추천촉매수지동등품 Hydrolysis of methyl acetate CH 3 COOCH 3 + H 2 O CH 3 COOH + CH 3 OH CMP08LH Esterification reaction RCOOH + ROH RCOOR + H 2 O PCC40H, MC-08H, CMP08LH, SPC160H, SPC180H, SPC400LH Synthesis of MMA(methyl methacrylate) CH 2 C CH 3 COOH CH 3 OH CH 2 C CH 3 COOCH 3 H 2 O SPC180H Alkylation of phenol OH H 2 C R H OH R CH 3 H SPC260H, SPC320H Amberlyst15Wet Synthesis of Bisphenol A OH O HO H 3 C CH 3 H3 C CH 3 OH PCC30H, PCC40H Methyl tertiary butyl ether(mtbe) H 2 C CH CH 3 3 CH CH 3 OH H 3 C OMe 3 CH 3 SPC280H Amberlyst35Wet t-amyl methyl ether(tame) H 2 C CH CH 3 CH 3 CH 3 3 CH CH 3 OH H 3 C OMe 3 CH 3 SPC160H, SPC180H
18 /49 초순수양이온교환수지 초순수음이온교환수지 균일계 Type Gel 제품명 TEC (eq/l) UPRC100U 1.8 출구수조건입도분포 Type 제품명 TEC (eq/l) 출구수조건 입도분포 UPRC120U 1.9 Guarantee) Resistivity > 0.57~0.67mm UPRA100U 1.0 17.0 MΩ cm (in 10min.) Guarantee) Resistivity > Actual) Resistivity > 18.0 17.0 MΩ cm (in 10min.) MΩ cm (in 10min.) 0.61~0.71mm UPRA120U 1.0 Actual) Resistivity > 18.0 0.57~0.67mm 0.54~0.64mm UPRA140U 1.2 MΩ cm (in 10min.) 0.58~0.68mm Resistivity >18.1 MΩ. cm UPRC200U 1.8 0.57~0.67mm (in 30min) UPRA200U 1.0 0.57~0.67mm Resistivity >18.1 MΩ. cm TOC<5ppb Gel (in 30min) UPRC220U 1.9 (in 120min) 0.61~0.71mm UPRA220U 1.0 0.54~0.64mm type1 TOC<5ppb (in 120min) UPRA240U 1.2 0.58~0.68mm Resistivity >18.2 MΩ. cm UPRC300U 1.8 0.57~0.67mm (in 30min) UPRA300U 1.0 0.57~0.67mm Resistivity >18.2 MΩ. cm TOC<1ppb (in 30min) UPRC320U 1.9 (in 180min) 0.61~0.71mm UPRA320U 1.0 0.54~0.64mm TOC<1ppb (in 180min) UPRA340U 1.2 0.58~0.68mm 초순수혼합수지 균일계 Type Grade Cation TEC Anion TEC H + (%) OH - (%) Cl - (%) 출구수조건 Gel UPRM100U = 1.8 + 1.0 99.0 90.0 1.0 UPRM120U = 1.9 + 1.0 99.0 90.0 1.0 UPRM140U = 1.9 + 1.2 99.0 90.0 1.0 UPRM200U = 1.8 + 1.0 99.0 95.0 1.0 UPRM220U = 1.9 + 1.0 99.0 95.0 1.0 UPRM240U = 1.9 + 1.2 99.0 95.0 1.0 UPRM300U = 1.8 + 1.0 99.9 97.0 0.1 UPRM320U = 1.9 + 1.0 99.9 97.0 0.1 UPRM340U = 1.9 + 1.2 99.9 97.0 0.1 Guarantee) Resistivity > 17.0 MΩ cm (in 10min.) Actual) Resistivity > 18.0 MΩ cm (in 10min.) Resistivity >18.1 MΩ. cm (in 30min) TOC<5ppb (in 120min) Resistivity >18.2 MΩ. cm (in 30min) TOC<1ppb (in 180min) Na<1, Fe<1, Ca<1, Zn<0.5, Al<0.5, Cu<0.5 Feed water(100 Series) : Conductivity 10 μs / cm RO outlet, SV36 Feed water(200, 300 Series) : Resistivity >17.5 MΩ. cm, TOC<2ppb, SV=30
19 /49 ( 일반적인초순수생산공정및이온교환수지의선택 ) Raw Water 1 Cation Exchanger RO MDG or VDG Pre- Treatment System Tank Heat Exchanger MF UV-ST Tank 1 Cation Exchanger Degasiifier 2 Anion Exchanger 3 Mixed Bed Tank Heat Exchanger UV-OX 4 Anion Polisher 5 Final Polisher UF 1 Cation Exchanger : MC-08, MC-10 2 Anion Exchanger : MA-12, MA-10, MA-15, MA-20, AW90 3 Mixed Bed Tower : UPRC100U, UPRC120U, UPRA100U, UPRA120U 4 Anion Polisher : UPRA200U, UPRA220U, UPRA240U, UPRA300U, UPRA320U, UPRA340U 5 Final Polisher : UPRM200U, UPRM220U, UPRM240U, UPRM300U, UPRM320U, UPRM340U Point of Use
20 /49 (TRILITE 초순수수지처리수조건 ) Raw Water RO, etc Mixed-bed (UPRM100U) UV-OX, etc Anion Polisher (UPRA200U) Final Polisher (UPRM300U) Outlet condition 1 Resistivity ( MΩ cm ) 18.25 18.20 18.15 18.10 18.05 2 TOC (ppb) 20 15 10 5 18.00 0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 hrs (Mettler Toledo M300) 0 0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 hrs (Anatel A1000S20P)
21 /49 (TRILITE 초순수수지처리수조건 ) 3 Total Silica (ppt) 500 400 300 200 100 4 Boron (ppt) 100 80 60 40 20 0 0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 hrs (HACH Series 5000 Silica Analyzer) 0 0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 hrs (Sievers UPW Boron Analyzer) 5 Metals (ppt) Li Be Na Mg Al K Ca Ti Cr Mn Fe Co Ni Cu < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 Zn Ga As Sr Mo Ag Cd Sn Sb Ba Au Pb Bi < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 6 Particle (0.05 μm / ml ): None (RION XP-L4W)
22 /49 TEC: Total Exchange Capacity 크로마토그래피양이온교환수지 크로마토그래피음이온교환수지 Type 제품명 TEC (eq/l) 이온형입도분포 Type 제품명 TEC (eq/l) 이온형 입도분포 균일계 Gel MCK-30 1.6 Na 210~230μm MA-13J 1.35 Cl 270~330μm Gel type1 MCK-32 1.6 K 205~220μm MA-13F 1.4 Cl 220~240μm MCK-35 1.6 Ca 200~220 μm Gel type2 MA-23F 1.4 Cl 220~240 μm MCK-30J 1.6 Na 290~300 μm MCK-32J 1.6 K 280~295 μm MCK-35J 1.6 Ca 280~285 μm MCK-30L 1.6 Na 310~345 μm MCK-32L 1.6 K 320~340 μm MCK-35L 1.6 Ca 300~330 μm MCK-30K 1.6 Na 340~360 μm MCK-32K 1.6 K 330~360 μm MCK-35K 1.7 Ca 330~360 μm MCK-35M 1.6 Ca 290~320 μm MCK-22K 1.6 K 335~365 μm MCK-22M 1.6 K 290~320 μm MCK-50 1.9 Na 210~220 μm MCK-52 2.0 K 205~225 μm MCK-55 2.0 Ca 200~220 μm 균일계 Gel Type 균일계 Gel Type 이온형제품예용도예 Na MCK-30 올리고당정제 K Ca MCK-22M 당밀에서설탕회수 MCK-55 F/G 분리 (Fructose/Glucose) Type1 MA-13J 바이오디젤정제 Cl Type2 MA-23F 산회수 (Acid purification) 교환기 Sulfonate Type1 : TMA, trimethylamine Type2 : DMEA, dimethylethanolamine
23 /49 ( 크로마토그래피분리를위한최선의선택 MCK Series) TRILITE MCK series 는용도에따라다양한입자크기및이온형으로생산되고있으며, 엄격한품질관리를통하여균일하게생산되어높은크로마토그래피분리성능구현이가능하다. 물리화학적으로매우안정되고사용수명이매우길어경제적인운전이가능하다. 균일계수 (1.05~1.10) 가매우낮음 우수한크로마토그래피분리성능구현 + 더높아진물리화학적강도 더긴사용수명가능 평균입자크기 가교도 이온형 210~220 μm 283~295 μm 305~328 μm 340~350 μm 5% K MCK-22M(305 μm ) MCK-22K(346 μm ) Na MCK-30(220 μm ) MCK-30J(295 μm ) MCK-30L(328 μm ) MCK-30K(350 μm ) 6% K MCK-32(213 μm ) MCK-32J(288 μm ) MCK-32L(320 μm ) MCK-32K(345 μm ) Ca MCK-35(210 μm ) MCK-35J(283 μm ) Na MCK-50(215 μm ) MCK-35M(305 μm ) MCK-35L(315 μm ) MCK-35K(340 μm ) 8% K MCK-52(215 μm ) 입자크기및가교도는참고수치임 Ca MCK-55(210 μm )
24 /49 (MCK-55 를이용한 F/G 분리, Fructose/glucose separation by MCK-55) 포도당을효소를사용하여이성화시키면높은감미도 ( 설탕의 1.7 배 ) 를가진과당이생산될수있고원료 (Starch sugar) 가설탕보다경제성이있기때문에설탕의대체품으로사용하는것이가능하다. 그러나효소반응은가역반응 (Reversible Reaction) 이기때문에반응평형상 42%( 설탕감미도의 90% 수준 ) 이상이성화시키는것이불가능하다. 따라서설탕의대체품으로사용되기위해서는과당의함유율을 55% 까지끌어올리는것이필요하고, 이목적을달성하기위해고안된것이포도당과과당을분리하는기술이다. 아래그림은일반적인포도당및과당혼합용액을 Ca 형양이온교환수지탑상부로부터처리했을때의모형도이다. 혼합물이수지층을통과하면서과당은 Ca 이온에대하여강한친화도를가지고있기때문에포도당이먼저용출되며과당이뒤에용출된다. 과당은회수되어제품으로판매되며포도당은이성화효소와다시반응하기위하여전 ( 前 ) 공정으로투입된다. Glucose (40~45%) (F/G 분리탑, Fructose/glucose separation tower) Isomerization by enzyme Activated carbon Ion exchanger (for fructose) Filtration, Concentration MCK-55 (Ca form) Fructose Glucose Fructose 42% HFS(High Fructose Syrup) Glucose Fructose Mixing Fructose 90% 55% HFS
25 /49 TEC: Total Exchange Capacity 강산성양이온교환수지 () 강염기성음이온교환수지 () Type 제품명 TEC (eq/l) 입도분포 Type 제품명 TEC (eq/l) 입도분포 Gaussian Gel SCR-B 2.0 Porous CMP18 1.8 (General type) 0.3~1.2 mm (L-type) 0.425~1.2 mm Porous type2 AMP24 1.0 (General type) 0.3~1.2 mm (L-type) 0.425~1.2 mm 균일계 Gel MC-08 2.0 0.55~0.65 mm 교환기 Sulfonate Type2 : DMEA, dimethylethanolamine 약염기성음이온교환수지 (WBA) Type 제품명 TEC (eq/l) /WBA Ratio 입도분포 특징및용도 Gaussian Porous AW30L 1.5 25/75 AW30C 1.6 5/95 (General type) 0.3~1.2 mm (L-type) 0.425~1.2 mm 경제적으로전분당탈색및탈염을할수있어널리사용된다. 단, ( 강염기 ) 비중이다소높아이성화반응이우려되는공정 (Fructose refining) 에는주의하여사용해야한다. WBA( 약염기 ) 비중이높고내열성이우수 (100 ) 하여열교환이필요없으며이성화반응우려되는공정에서도사용가능하다. 균일계 AW90 1.6 17/83 0.50~0.60 mm균일계수가낮아 Upflow 시스템에추천된다. 교환기 Tertiary Amine
26 /49 ( 일반적인전분당정제공정과 F/G 분리 ) Starch (Corn) Emulsion of starch Enzyme liquefaction, saccharification Filtration Activated carbon Concentration 1 st Ion exchanger (for glucose) Concentration Corn syrup SCR-B or CMP18 AW30L or AW30C Countercurrent Cocurrent ph 5~6 5μs / cm ph 8~9 20μs / cm AMP24 CMP18 ph 4~6 2 μs / cm Bx 35~40 CV Max 0.05 Glucose Isomerization by enzyme Activated carbon 2 nd Ion exchanger (for fructose) Filtration Concentration 42% HFS SCR-B or CMP18 AW30L or AW30C Countercurrent Cocurrent ph 5~6 5μs / cm ph 8~9 20μs / cm AMP24 CMP18 ph 4~6 2 μs / cm Bx 45 CV Max 0.05 Fructose/glucose separation 3 rd Ion exchanger (for high fructose) Concentration 90~97% HFS Mixing (Mixture) Fructose (42%) Glucose (52%) Other sugars (6%) MCK-55 (Separation) Fructose (90~97%) Glucose (80~90%) AW30C AMP24 CMP18 ph 4~6 2 μs / cm Bx 40 CV Max 0.05 55% HFS High fructose syrup
27 /49 Gaussian Type Gel type1 Porous type1 (Polystyrene +DVB) 설탕정제용수지 ( 활성탄사용 ) 설탕정제용수지 ( 활성탄미사용 ) 제품명 KA-11 SAR11 TEC (eq/l) AMP14 1.0 0.9 (General type) 0.3~1.2mm (L-type) 0.425~1.2mm 입도분포 Type 제품명 Porous (Polyacrylate +DVB) TEC: Total Exchange Capacity TEC (eq/l) 입도분포 ASP10 0.9 0.425~1.2 mm 교환기 TMA, trimethylamine Quaternary ammonium ( 사탕수수설탕정제공정, Cane sugar) (IER, 활성탄을사용한설탕정제공정 ) (IER 을사용한설탕정제공정 ) Cane B sugar (Raw sugar) 2,000~ 3,000 I.U. C sugar (Raw sugar) 3,000~ 4,000 I.U. Crushing Affination, Melting Affination, Melting Extraction Carbonation, Filtration Carbonation, Filtration 800~1,000 I.U. 800~1,000 I.U. Carbonation Filtration Activated carbon Decolorization by IER (KA11 or SAR11 or AMP14) 300~400 I.U. Decolorization by IER (2 steps) (ASP10 + AMP14) Concentration, Crystallization Concentration, Crystallization 100~150 I.U. Concentration, Crystallization 200~300 I.U. A Sugar B Sugar C Sugar Refined sugar > White sugar Brown sugar Refined sugar < White sugar Brown sugar 500~600 I.U. 2,000~3,000 I.U. 3,000~4,000 I.U. <45 I.U. < 100 I.U. 400~1,000 I.U. <45 I.U. < 100 I.U. 400~1,000 I.U.
28 /49 TEC: Total Exchange Capacity 핵산정제용수지 라이신정제용수지 Type 제품명 TEC (eq/l) 입도분포 Type 제품명 TEC (eq/l) 입도분포 Gaussian Gel tailored Porous tailored NAC4 1.2 (General type) 0.3~1.2mm (L-type) AMP26N 1.2 0.425~1.2mm 균일계 Gel MC-04NH 1.2 0.47~0.57 mm Gel tailored MC-08LS 2.0 0.55~0.65 mm ( 핵산흡착 / 용리공정 ) ( 라이신흡착 / 용리공정 ) Cultivation of yeast Extraction of nucleic acids Decomposition of nucleic acids Cultivation of microorganism Broth with lysine Adsorption & separation with IER Crystallization Evaporation Adsorption & separation with IER Crystallization Evaporation Neutralization, Filtration AMP26N NAC4 or MC-04NH AMP26N MC-08LS Adsorption of nucleic acids Separation of GMP, IMP Concentration Adsorption of lysine GMP : Guanosine monophosphate IMP : Inosine monophosphate Lysine : 필수아미노산
29 /49 킬레이트수지 (Chelating resins) Gaussian 제품명교환기이온형 CLR-08 Iminodiacetate Na CLR-09 Aminomethyl phosphonate TEC (eq/l) Cu 2+ 0.5 Ca 2+ 0.4 입도분포용도동등품 0.4~1.0 mm염수 2 차정제 Na Ca 2+ 0.6 0.4~1.0 mm염수 2 차정제 CLR-10 Thiouronium H 1.1 0.3~1.25 mm수은제거 CLR-20 Polyamine OH CLR-B3 Glucamine Free base 4mol as copper 0.6eq/l as boron 0.4~1.25 mm중금속제거 0.3~1.25 mm보론 (Boron) 제거 Lewatit TP208 Amberlite IRC748 Diaion CR11 Purolite S930 Lewatit TP260 Amberlite IRC747 Purolite S940 Eporous-Z7 Purolite S924 Diaion CR20 Eporous MX-8C Diaion CRB03 Amberlite IRA743 Purolite S108 CLR-B3UP Glucamine Free 0.6eq/l Boron polisher 0.3~1.25mm base as boron (TOC 5ppb ) Diaion CRBT03 CLR-F Aminophosphonate Al 11g as fluorine 0.3~1.0mm 불소제거 Eporous-K1 CLR-N Triethylamine Cl 1.0 0.3~1.25mm 질산염 (Nitrate) 제거 Amberlite IRA996 Purolite A520E (Chloro-alkali process) ( 염수 2 차정제탑 ) Salt Salt saturation Primary brine purification Chlorine Secondary brine purification Water CLR-08 or CLR-09 Ca 2+ 0.01ppm Mg 2+ 0.01ppm Sr 2+ 0.02ppm Ba 2+ 0.01ppm Gas liquid separation Ion exchange membrane electrolysis cell Hydrogen Vaporization Dechlorination 50% NaOH
30 /49 ( 일반적인중금속제거폐수처리프로세스 ) 다양한중금속을포함하는폐수 ( 중금속중수은이있을경우 ) 중화응집침전처리 다양한중금속을포함하는폐수 ( 중금속중수은이없을경우 ) CLR-10 ( 수은제거 ) CLR-20 ( 중금속제거 ) 중화제 응집제 중금속을포함하는폐수 M P Clarifier P Sand filter Activated carbon filter 폐수저장조 중화반응조 중화제 P 중화제 M CLR-10 (Optional) CLR-20 M 방류또는재활용 ph 조정조 킬레이트수지탑 ph 조정조
31 /49 TEC: Total Exchange Capacity 합성흡착제 (Synthetic adsorbents) 제품명 화학구조 Specific surface area( m2 /g) Pore volume ( ml /g) Pore radius (A ) 입도분포용도동등품 GSH-20 -CH 2 -CH-CH 2 -CH- 750 1.0~1.5 50~80 0.31~1.25mm Diaion HP20 Styrene type Chemically modified styrene type GSP-25 1,100 1.2~1.6 45~55 0.25~0.7 mm Diaion SP825 GSP-50 CH 2 -CH- 1,000 0.9~1.1 30~50 0.25~0.7mm 단백질, 항생물질, Diaion SP850 식품등의 -CH 2 -CH-CH 2 -CH- 분리 / 정제 / 탈색 GSP-07 600 0.8~1.0 50~70 0.25~0.7 mm Diaion SP207 CH 2 -CH- Br ( 합성흡착제의반응 Mechanism 및실험방법 ) Feeding solution Target molecules Pore radius (A ) Specific surface area( m2 /g) synthetic adsorbents Pure water Pure water Eluent Detector Regenerant Fraction collector
32 /49 ( 합성흡착제의선택가이드 ) Aromatic standard type GSH-20 Aromatic special type GSP-25, GSP-50 Aromatic chemically modified GSP-07 비교적큰세공 (Pore) 를가짐 세공이비교적크기때문에큰분자의흡착에적합 (> 1,000mw) 흡착물질의용리 (Elution) 가쉽다 비표면적 (Specific surface area) 이크고, 세공이 GSH20 보다작다 작은분자를선택성있게흡착할수있다 (< 1,000mw) 흡착물질의용리 (Elution) 가쉽다 소수성 (Hydrophobicity) 이크고매우강한흡착능력을가짐 재생제가다량필요할수있다 비중이커서고밀도액에서사용가능하다 ( 합성흡착제사용사례 ) 사용준비흡착 (Adsorption), 용리 (Elution) 재생 공정 Flow rate (SV) Flow volume (BV) 역세 - - 불순물및기포를제거 전처리 1~5 5~10 Alcohol or aqueous alcoholic solution 수세 1~5 3~4 Water of buffer solution (same ph as feed solution) 흡착 0.5~3 통액량은합성흡착제의최대흡착용량보다적어야한다 수세 1~5 0.5~1 Feed solution 의제거 용리 0.5~3 2~10 비고 합성흡착제로부터 Target 물질을분리하는공정용리제로알코올, 아세톤, 알칼리, 산 (Acid) 수용액등이사용되며 Target 물질에따라적합한용리제를선택해야한다 수세 1~5 3~4 Water of buffer solution (same ph as feed solution) 재생 0.5~3 3~4 수세 1~5 3~4 사용준비를위하여수세 불순물이침착하여흡착능력이감소할때알코올, 아세톤, IPA, NaOH 등을사용하여불순물을제거하는공정
33 /49 ( 혼합수지의선택가이드 ) 제품명특징및적용분야 Components 처리수수질 SM200 SM210 SM300 UPRM100U ( 균일계 ) UPRM200U ( 균일계 ) UPRM300U ( 균일계 ) 상수에서간편하게순수제조가능 실험실순수제조, Wire-cutting 상수에서간편하게순수제조가능 실험실순수제조, Wire-cutting 높은비저항및 SiO 2 제거능력우수 RO, EDI 후단 MB 매우높은비저항 전기전자 Grade, 초순수생산 매우높은비저항, 낮은수준 ΔTOC LCD, OLED 초순수, Final polisher 매우높은비저항, 매우낮은수준 ΔTOC Metal ion < 0.1ppt 반도체초순수, Final polisher KC-08H(H + 99.0% ) KA-12OH(OH - 90.0% ) Mixed ratio(volume) : 45:55 SCR-BH(H + 99.0% ) SAR12OH(OH - 95.0% ) Mixed ratio(volume) : 45:55 SCR-BH(H + 99.0% ) SAR12OH(OH - 95.0% ) Mixed ratio(volume) : 40:60 UPRC100U(H + 99.0% ) UPRA100U(OH - 95.0% ) Mixed ratio(capacity) : 50:50 UPRC200U(H + 99.0% ) UPRA200U(OH - 95.0% ) Mixed ratio(capacity) : 50:50 UPRC300U(H + 99.9% ) UPRA300U(OH - 97.0% ) Mixed ratio(capacity) : 50:50 Out Feed Out Feed Out Feed Out Feed Out Feed Out Feed Guarantee) Resistivity > 10.0 MΩ cm (in 10min.) Actual) Resistivity > 15.0 MΩ cm (in 10min.) Conductivity 150 μs / cm Potable water, SV36 Guarantee) Resistivity > 10.0 MΩ cm (in 10min.) Actual) Resistivity > 15.0 MΩ cm (in 10min.) Conductivity 150 μs / cm Potable water, SV36 Guarantee) Resistivity > 15.0 MΩ cm (in 10min.) Actual) Resistivity > 17.0 MΩ cm (in 10min.) Conductivity 10 μs / cm RO outlet, SV36 Guarantee) Resistivity > 17.0 MΩ cm (in 10min.) Actual) Resistivity > 18.0 MΩ cm (in 10min.) Conductivity 10 μs / cm RO outlet, SV36 Resistivity >18.1 MΩ cm (in 30min.) TOC<5ppb (in 120min.) Resistivity >17.5 MΩ cm, TOC<2ppb, SV30 Resistivity >18.2 MΩ cm (in 30min.) TOC<1ppb (in 180min.) Metal ion < 0.1ppt Resistivity >17.5 MΩ cm, TOC<2ppb, SV30 (Pressure vessel for RO unit) (Cartridge polisher for wire-cutting)
34 /49 TEC: Total Exchange Capacity 복층상용음이온교환수지 불활성수지 Type 제품명 TEC (eq/l) 입도분포제품명 Matrix 겉보기밀도 (g/l) 입도분포 용도 균일계 Porous WBA AW90LB 1.6 0.5~0.6 mm TR70 Polyethylene 500 1.2~1.8 mm 팩베드용불활성수지 ( 상부수지유출방지 ) Gaussian Gel type1 KA18LB 1.3 0.6~1.2 mm TR30 Polystyrene +DVB 725 0.7~0.9 mm Triobed 용불활성수지 ( 양, 음이온분리 ) Service (Layered bed) (Packed bed) Service (Triobed) NaOH AW90LB KA18LB Freeboard TRILITE AW90LB TRILITE KA18LB TRILITE AW90LB TRILITE KA18LB Freeboard Freeboard TRILITE TR70 IER TRILITE TR30 Freeboard Middle distributor Regeneration Regeneration HCl
35 /49 TEC: Total Exchange Capacity 강산성양이온교환수지 () 강염기성음이온교환수지 () Type 제품명 TEC (eq/l) 입도분포 Type 제품명 TEC (eq/l) 입도분포 Gaussian Cation Exchanger SPC260EGH 1.7 0.3~1.2 mm ARR AMP16EG 1.2 0.3~1.2 mm 약염기성음이온교환수지 (WBA) Type 제품명 TEC (eq/l) 입도분포 균일계 Anion Exchanger AW90EG 1.6 0.50~0.60 mm (MEG 생산공정 ) Ethylene + O 2 With Silver Oxide as catalyst EO (Ethylene Oxide) Scrubber Stripping Column Glycol Adsorption Column NaOH (ph adjustment) (Impurities in cycle water) Sodium Acetate CO 2 HCOOH CH 3 COOH (Cation Exchanger) EO/EG cycle water (ARR) Aldehyde Removal Resin (Anion Exchanger) Vacuum Degasifier WBA Evaporator Dry Column MEG (Mono-ethylene glycol)
8. Product analysis / Quality control 36 /49 Basic Performance ( 기본분석 ) ( 울산공장 ) ( 군산공장 ) 겉보기밀도수분교환용량입도분석외관분석 ( 완구율 ) 제품 Hopper ( 제품별선택분석 (H/OH 형촉매, 초순수 ) 샘플채취 H/OH 전환율비저항 ΔTOC 샘플보관 (4 년 ) ISO9001 ( 정기분석 ) 화학적강도 (Osmotic shock stability) 압착강도 (Friability) 합격판정 N Y 공정분석 출하 시험성적서 (From DB) 포장 Customer
9. Product analysis / Quality control (OEM) 37 /49 TRILITE OEM 제품은 삼양사의 기술지도 및 제공된 Recipe에 의거하여 생산되며 엄격한 품질 관리 시스템을 준수하여 최종 품질을 신뢰의 삼양사가 보증합니다. Economy (① 생산 지시) OEM 생산 계약 생산 계획 관리 수입 진행 (② 생산 완료 및 Batch별 샘플 송부) (OEM Plant A) Recipe 제공 Specification 관리 Technical data 분석 Seoul Headquarter (④ 포장 및 출하 지시) Technical Center Daejeon (OEM Plant B) Plant Ulsan 공정 분석 포장 제품 분석 최종 제품 검사 재고관리, 재포장, 출하 등 N Y 선적 (⑤ 최종 제품 검사) (③ 제품 분석) 합격 판정 샘플 보관 (4년) (DB) 반품 시험성적서 N 합격 판정 Y 출하/선적 Customer ISO9001
10. Quality assurance system 38 /49 ISO9001 엄격한품질관리를실시하고있으며이슬람권식품용도수출을위한 HALAL 인증, 발전소납품을위한 Veritas 인증등공신력있는품질기관으로부터의지속적인 Audit 실시 ISO9001 인증 HALAL 인증 Veritas 인증 MUI JAKIM KMF
11. Packing line, packing type 39 /49 ( 자동포장 : 25l PE Bag) ( 수동포장 : 1,000lBag, plastic/fiber drum) 25Liters PE bag 1,000Liters Ton bag 50Liters Plastic drum 5 or 7ft 3 Fiber drum 5Liters Vacuum bag Palletizing, container loading
12. Technical service 40 /49 1 사용수지분석서비스 (Ion exchange resin analysis report) 2 이온교환수지량계산프로그램배포 (Ion exchange resin calculation program) 3 설비진단및개조제안 (Facilities diagnosis, retrofit proposal) 4 신규응용프로세스개발 (Application process development)
13. Major customers 41 /49 삼양트리라이트는전기전자, 석유화학, 발전소, 식품, 의약등다양한분야의국내외 Major 업체에납품되고있으며, 우수한성능, 엄격한품질관리및납기준수로호평을받고있습니다. Oil & Petrochemical Electronics Power Food Steel Korea Electric Power Corp. Korea Hydro & Nuclear Co. Engineering
14. Major References Power & UPW 42 /49 Customer Name Location Application Resin Type Web Site KOREA ELECTRIC POWER Seoul, Korea Indonesia South Afreeca Demineralization Condensate Polishing SCR-B / SAR10 /SAR20 / CMP / AMP / AW90 / UPRM / TR70 http://cyber.kepco.co.k r/kepco/main.do KOREA HYBRID & NUCLEAR POWER Seoul, Korea Demineralization Condensate Polishing SCR-B / SAR10 / SAR20 / MC08 / MA12 / MA20 / UPRM http://cms.khnp.co.kr SAMSUNG ELECTRONICS Hwasung, Korea Demineralization Chemical Purification MC / MA / UPR Series www.samsungsvc.co.kr SAMSUNG DISPLAY Asan, Korea Suzhou, China Demineralization UPW MC / MA / UPR Series http://www.samsungdi splay.com SAMSUNG ELECTRO- MECHANICS Ulsan, Korea Demineralization SCR / SAR Series http://www.samsungs em.co.kr SK HYNIX Incheon, Korea Demineralization Ultra Pure Water MC / MA / UPR Series http://skhynix.com LG DISPLAY Gumi, Korea Paju, Korea China Demineralization UPW MC / MA / UPR Series http://www.lgdisplay. com
14. Major References Power (China & Taiwan) 43 /49 Region Customer Name (for Condensate polishing) Products Cation Anion JIANGSU SHAZHOU Power Plant China (16.6~) NEIMENGGU TUOKETUO Power Plant TRILITE MC-10H TRILITE MA-10OH SHILIQUAN Power Plant (Test result passed) Taiwan (17.01~) Maanshan Nuclear Power plant TRILITE MC-10HUP TRILITE MA-10OHUP
14. Major References Power (Overseas, 2016~) 44 /49 Company Type Capacity(MW) Start Year Resin Types Delivery Date MAANSHAN NUCLEAR POWER PLANT (Taiwan) Nuclear CPP (PWR) 951 X 2 1985 MC-10HUP, MA-10OHUP 2017.02 Thermal Power Station-9 (Russia Angarsk) Thermal Make-up 475 1958 MA-12 AW-90 2017.05 TUKETUO POWER PLANT (China Inner Mongol) Thermal CPP 600 X 8 300 X 2 1995 MC-10H MA-15OH 2016.11 SHAZHOU POWER PLANT (China Zhangjiagang) Thermal CPP 1.000 X 2 630 X 2 2006 MC-10H MA-10OH 2017.03 ZAOZHUANG POWER PLANT (China Shandong) Thermal CPP 300 X 2 2015 MC-10H MA-10OH 2017.02 FUSHUN POWER PLANT (China Liaoning) Thermal CPP 50 X 2 2016 MC-10H MA-10OH 2017.01 WUJIANFANG POWER PLANT (China Inner Mongol) Thermal CPP 660 X 2 2017 MC-10H MA-10OH 2017.04 Tanjung Jati Power Plant - Unit 3&4 (PT. KPJB) Thermal Make-up 660 MWⅹ2 2017 MC-08, MA-20, MA-12 2017.04 Tanjung Power Indonesia KALSEL-1 Coal Fired Power Plant Demi. Make-up 1,000MW x 2 2017 MC-08H, MA-12 2017.05
14. Major References Oil & Petrochemicals 45 /49 Customer Name Location Application Resin Type Web Site GS CALTEX Yeosu, Korea Demineralization MC / MA Series / TR70 http://www.gscaltex. com Ulsan, Korea Demineralization, Methanol Purification MC Series / MA Series / TR70 SPC Series http://eng.skinnovati on. com S-OIL Ulsan, Korea Demineralization MC Series / MA Series / TR70 AW Series http://www.soil.com HYUNDAI OILBANK HANWHA CHEMICAL KUMHO P&B Daesan, Korea Demineralization MC Series / MA Series/ TR70 Yeosu, Korea Demineralization MC / MA / SCR / SAR Series Yeosu, Korea BPA Catalyst PCC Series http://www.oilbank. co.kr http://hcc.hanwha.c o.kr http://www.kpb.co. kr HYOSUNG Jiaxing, China Ulsan, Korea Catalyst (PTMEG / PTMA) / Demineralization SPC / SCR / SAR Series http://www.hyosun g.co.kr
14. Major References Chemicals, Steel/Fertilizer 46 /49 Customer Name Location Application Resin Type Web Site LG CHEM Seoul, Korea Demineralization MC Series / MA Series/ TR70 /SCR Series / SAR Series http://www.lgchem. com LG MMA Yeosu, Korea MMA Catalyst PCC / SPC Series https://www.lgmma.com LOTTE CHEMICAL Malaysia, Ulsan/ Yeosu/ Seosan, Korea Demineralization EO/EG, Catalyst SPC /MC / MA Series http://www.lottech em. com POSCO Pohang, Korea Jakarta, Indonesia Ultra Pure Water Demineralization MC Series / MA Series/ TR70 /SCR Series / SAR Series /UPRM Series www.posco.co.kr HYUNDAI STEEL Dangjin, Korea Demineralization SCR Series / SAR Series https://www.hyunda i-steel.com WUHAN Engineering Wuhuan, CHINA Catalyst (PTMEG / PTMA) SPC / CMP / AMP Series PT. Petrokimia Indonesia Gresik, Indonesia Demineralization MC-08, AMP16 www.petrokimiagresik.com
14. Major References Food & Bio 47 /49 Customer Name Location Application Resin Type Web Site Cheil Jaedang Liaocheng, China Shenyang, China Jombang, Indonesia Incheon, Korea Nucleic Acid / Lysine Sugar / Sweetener Demineralization NAC4 / AMP / MC / MA Series / SCR-B / SAR10 / SAR11 / SAR20 http://cj.net Daesasng (Miwon) Gresik, Indonesia Gunsan, Korea MSG / Lysine Sweetener/ DI Water MC Series / SCR-B / SAR20 / AW90 http://www.daesan g.co.kr Ingredion Incorporated Iecheon, Korea Bupyoung, Korea Sweetener CMP / AMP / SCR-B / SAR10 / MCK series http://www.ingredio n. com LG House hold and Ulsan, Korea Sorbitol purification Demineralization SCR / SAR Series http://www.lgcare.c om
14. Major References - Eng g Projects 48 /49 Customer Name (EPC) Location (Project Name) Saudi Arabia, (Saudi ma aden Ammonia Project) Application Capacity Web Site Demineralization / Condensate Polishing System (ACF+2B2T+MBP) 280 m3 /h x 2 trains 350 m3 /h x 3 trains Samsung Engineering Saudi Arabia, (APPC PDH/PP Project) India (IOCL MEG Project) Demineralization (ACF+2B3T+MBP) MEG Purification System / Cycle water treating unit 120 m3 /h x 2 trains 39 m3 /h x 2 trains http://www.samsun gengineering.co.kr Thailand EO/EG Purification System / Cycle water treating unit 39 m3 /h x 2 trains Daelim Ind. Saudi Arabia, (Umm Wu al Ammonia Project) Demineralization / Condensate Polishing System (ACF+2B2T+MBP) 280 m3 /h x 2 train 350 m3 /h x 3 train https://www.daelim.co. kr/eng/main.do Mitsubishi Heavy Ind. Saudi Arabia, (Ar-Razi Saudi Methanol Project) Algeria (Algeria Oman Fertilizerp Project) Demineralization (S/F+ACF+2B3T+MBP) Demineralization / Condensate Polishing System (ACF+2B3T+MBP) 100 m3 /h x 2 trains 325 m3 /h x 4 trains 480 m3 /h x 5 trains https://www.mhiglobal.com/
15. Cross reference guide 49 /49 세계 이온교환수지 Maker 중 균일계수 1.1 생산기술을 보유한 회사는 3사 뿐입니다 ①Samyang & Mitsubishi, ②Dow, ③Lanxess Mitsubishi DIAION Type (Chromatography) UC 1.1 MC-08 MC-08H MC-10 MC-10H UC 1.1 UBK08 UBK08H UBK10 UBK10H MCK series UBK500 series MA-12 MA-12OH MA-10 _Type 1 MA-10OH MA-15 MA-15OH _Type 2 MA-20 UPRM100U UPW_Mixed Bed UPRM200U UPRM300U 균일계 Porous WBA AW90 UC 1.6 SCR-B(KC-08) _Food grade KH-70/KH-80 Gaussian Gel SAR10(KA-10) SAR11(KA-11) SAR12(KA-12) SAR20(KA-20) Mixed Bed SM200/210/300 CMP/SPC Series Gaussian Porous AMP Series WAC WCA10L WBA AW30 Chelating CLR series Inert resin TR series 균일계 Gel UBA120 UBA120OH UBA100 UBA100OH UBA150 UBA150OH UBA200 UC 1.6 SK1B SA10 SA11 SA12 SA20 PK series PA series WK40/WK60L WA30 CR series DOW Dowex Amberjet/lite UC 1.1 Marathon C Marathon CH Mono 650 C Mono 650 C H UC 1.2 1200 1200H 1500 1500H Lanxess Lewatit UC 1.1 MP S100 MP S100H MP S108 MP S108H Purolite UC 1.2 PFC/PPC100 PFC/PPC100H SGC-650C SGC-650CH MDS series Marathon A Marathon A OH Mono 550A Mono 550A OH Mono 550A Mono 550A OH Marathon A2 4200 Cl 4200 OH 4400 Cl 4400 OH 4400 Cl 4400 OH 4600 Cl MR-450 UPW MR-3 UPW Monosphere 66 UP6150 UP6040 HCR-S HCR-S/S SBRP SAR MSA MWC-1 IF-62 MP M500 MP M500 OH MP M800 MP M800OH MP M800 MP M800OH MP M600 1292MD 1294MD MP64/MP68 UC 1.6~1.8 IR120Na C249/C267 IRA400 IRA401S IRA402 IRA416 MB20 IRA900 OH IRC86 IRA93SP PFA/PPA400 PFA/PPA400 OH SGC-550A SGC-550A OH SGC-550A SGC-550A OH PFA/PPA200 UCW 3600 UCW 3700 UCW 9966 ASB1 C100 C100E A400 ASB1 NM91 SP120 MP500 CNP80 MP62 TP207/208 IN49 A600 A200 MB400 C150, C160 A500 C105 A100 S930Puls IP1
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