1. ( ) (1) 2. (CAS ) (1) 3. ( ) (13) 4. ( ) (2519)
10, 2 6 1 476 (1998.3.2 ) ( : ) ( : ) (1997 ).,, HS, UN. 1.. 1997-11 ( 97.12.23). CAS (Chemical Abstracts Service Registry Number ) (ACS; American Chemical Society ).. HS (Harmonized Commodity Description and Coding System ) HS 10,.. RT ECS (Registry of T oxic Effects of Chemical Substances) (NIOSH ) DB.. UN, - -
UN. "National Chemical Inventories" DB UN. 2.,.. 2.. 1) (LD50 LC5 0 ),,,. 2) EU. 1 (Cat. 1) : 2 (Cat. 2) : 3 (Cat. 1) : 3) EU. 1 (Cat. 1) : ). ) 2 (Cat. 2) : ), 2 - -
. ), 2. 3 (Cat. 3) : ), 2 2. ), 2 2. 4) IARC, NT P, EU, EPA (, NT P- b). ) IARC(International Agency for Research on Cancer ) Group 1 : (carcinogenic to humans) Group 2A : (probably carcinogenic to humans) Group 2B : (possibly carcinogenic to humans) Group 3 : (not classifiable as its carcinogenicity to humans) Group 4 : (T he agent is probably not carcinogenic to humans) - -
) NT P (National T oxicology Program ) Group A : (Known to be carcinogen ) Group B : (Reasonably anticipated to be car cinogen s) ) EPA Group A : (Human carcinogen ) Group B : (Probable human carcinogen ) B1 : B2 : Group C : (Prossible human carcinogen) Group D : (Not classifiable as to human carcinogenicity) Group E : (Evidence of noncarcinogenicity for humans) ) ACGIH(American Conference of Governmental Industrial Hygienists) A 1 : (Confirmed human carcinogen ) A2 : (Suspected human carcinogen) A3 : (Animal carcinogen ) A4 : (Not classifiable as a carcinogen ) A5 : (Not suspected as a human carcinogen ) ) EEC- 1 : EEC- 2 : EEC- 3 :..,,,. - -
.,,,,.. " (97-65 ) ACGIH (American Conference of Governmental Industrial Hygienists ) 1 (T ime weighted Average, T WA ), (Short T erm Exposure Limit, ST EL) (Ceilling, C). 3.. 4... [ 2].. ( )... 5. 37. 6. (Department Of T ransportation )..,. - -
.. 7....,,,. - -
1
97-1- 1 [Sodium peroxide ; 1313 : 97-1- 1 CAS : 1313-60- 6 HS : 2815-30- 1000 RTECS : WD3450000 UN : 1504 : [Sodium perox ide; 1313-60- 6] 5% : : Sodium peroxide Sodium dioxide Disodium dioxide Disodium peroxide Sodium oxide (Na2O2) ( ) : Na2O2 (77.98) - : 657 ( ) - : 460 ( ) - : 2.805(20 ) - :. - ( ). - 20%. - (250kcal/ kg ). -. -. - (,,, ). 3
97-1- 1 [Sodium peroxide ; 1313 - /. -,,. - ( ),.. -,,. -,,. - (Hexamethylenetetramine). - 2 (rat ).. *. -,,,. - (primary systemic effects). -.,. - Bluegill(, ) : 24.5ppm/ 24hr Prawns (, LC5 0 ) : 42.5ppm/ 48hr.,,, 4
97-1- 1 [Sodium peroxide ; 1313 - (,, ),,,. -. ( ) -. -. -.,. -,. 24 48. -,.... -,,. -. -. -. -. - 5
97-1- 1 [Sodium peroxide ; 1313. -,, ( ),,,. -, (rail car ),. -. -.. - (,, ). -.,. - (( ), ( ).. -. 6
97-1-2 [Hydrogen Peroxide ; 7722 : 97-1- 2 CAS : 7722-84- 1 HS : 2847-00 RTECS : MX0900000 UN : 2014, 2015, 2984 : : : Hydrogen peroxide Oxidol [Hy dr og en per ox ide ; 7722-84- 1] 6% ( ) : H 2O2 (34.02) - : 152 - : - 0.43 - ph : - : 1mmHg (15.3 ) - :,,. - : 1.463 - : 1.245mPa.s - : 340 -. (3 98%). - ( ). - 1 40%. -. 7
97-1-2 [Hydrogen Peroxide ; 7722 -.. -, (Acetanilide).. -. - As2S3, Cl2 + KOH, CuS, FeS, FeSO4 + 2- Methylpryidine + H2SO4, HNO3, H2Se, HgO + HNO3, KMnO4, P2O5, Alcohols + H2SO4, Alcohols + T in chloride, Acetal + Acetic acid + Heat, Acetic acid + n- heterocycles(50 ), 2- Amino- 4- methyloxazole + Iron(II) catalyst, Antimony trisulfide, Aromatic hydrocarbons + Trifluoroacetic acid, Azeliac acid + Sulfuric acid (45 ), Benzenesulfonic anhydride, tert- Butanol + Sulfuric acid, Carboxylic acids, Chlorosulfonic acid, 5- Dimethyl- 3- hexanol + Sulfuric acid, uns- Dimethyl hydrazine, Dimethylphenylphosphine, Diphenyl diselenide (53 ), 2- thoyxethanol + Polyacrylamide gel + T oluene + Heat, Formic acid + Organic matter, Gadolinium hydroxide(80 ), Gallium + Hydrochloric acid, Hydrazine, Hydrogen + Palladium catalysts, Iron(II) sulfate + 2- Methylpyridine + Sulfuric acid, Iron(II) sulfate + Nitric acid + Sodium carboxymethylcellulose, Ketenes + Nitric acid, Lead dioxide, Lead oxide, Lead sulfide, Manganese dioxide, Mercuric oxide, Mercurous oxide, Methanol + Copper sulfate + Cyanide residues, Methanol + T ert- amines + Platinum catalysts, 2- Methyl- 1- phenyl- 2- propanol + Sulfuric acid, Molybdenum disulfide, Nitric acid + ketones(2- Butanone; 3- Pentanone; Cyclopentanone; Cyclohexanone; 3- Methylcyclohexanone), Nitric acid + Soils, Sodium iodate, Sulfuric acid, T etrahydrothiophene, T hiodiglycol, Trioxane, Water, Water + oxygenated compounds( acetaldehyde; acetic acid; acetone; ethanol; formaldehyde; formic acid; methanol; 2- propanol; propionaldehyde), Vinyl acetatecetic anhydride, Acetone cyanohydrin, Acetone + Nitric acid, Acetone + Potassium 8
97-1-2 [Hydrogen Peroxide ; 7722 dichromate, Acetonitrile, Acrolein, Acrylonitrile, Acrylonitrile + Water, Alcohols + hydrogen peroxide, Allyl alcohol, Allyl chloride, 2- Aminoethanol, Ammonium hydroxide, Ammonium triperchromate, Aniline, Bromates + Metals, Bromine pentafluoride, n- Butyraldehyde, Carbides, Cesium acetylene carbide, Chlorates, Chlorates + Metals, Chlorine trifluoride, Chlorosulfonic acid, Cuprous nitride, Diisobutylene, Dimethylbenzylcarbinol + Hydrogen peroxide, Epichlorohydrin, Ethyl alcohol + Hydrogen peroxide, Ethylene cyanohydrin, Ethylene diamine, Ethylene glycol, Ethylenimine, Fulminates, Hydrochloric acid, Hydrofluoric acid, Iodine heptafluoride, Indane + Nitric acid, Iron - (90% ) : 1,518 / (LD50, rat ) : 2g/ m 3 / 4hr (LC5 0, rat ) : 880 / kg (LD5 0, mouse) - ( hairy tongue ). -. -. - 20 30%. (internal bleeding ). -. - DNA. DNA. - 9
97-1-2 [Hydrogen Peroxide ; 7722. - T WA 1ppm, 1.5mg/ m 3 - ACGIH T WA 1ppm, 1.4mg/ m 3,,,,,,,,,,,,,,,,, - 35. -..,,. ( ),,. -. -.. -. ( ) 10
97-1-2 [Hydrogen Peroxide ; 7722 -... -,.. 20. -,. - 50. -. -. -. - ( ),,,.. -, (rail car ),. -. - 10 25m. -. -. - (,, ) 11
97-1-2 [Hydrogen Peroxide ; 7722. -., - (( ), ( ). -. 100m. 12
97-1-3 [Urea peroxide ; 124 : 97-1- 3 CAS : 124-43- 6 HS : 2847-00 RTECS : YT4850000 UN : 1511 : [Urea peroxide; 124-43- 6] 17% : : Urea peroxide Carbamide peroxide Urea hydrogen peroxide Urea, compound with hydrogen peroxide(1:1) ( ) : CH 4N2O.H 2O2 (94.09) - : 360 - : 0.8(20 ) - : - 300cal/ g - : (82.2g/ 100ml, 20 ) - 34 35%. -. - 75. -. 13
97-1-3 [Urea peroxide ; 124-50,. -,,,. -. -. -. -,.. -, ACGHI (H 2O2 ) -. - 60. -,,,. -. -. ( ). -,,. -, (dust - proof goggle), ( ). -. 14
97-1-3 [Urea peroxide ; 124 -. -. 15.. -,. - (mouth - to- mouth ). -,. -,.. - (charcoal slurry ), (saline cathartic), (35% ) ( : 30 100g, : 10 15g, 50g.). - (diazepam ).( : 5 10mg, : 0.2 0.5mg/ kg ). -. -. -. -, (positive pressure self- contained breathing apparatus ). -. -,. /. -. 15
97-1-3 [Urea peroxide ; 124 -. - ( ). -.. -. -,,. -, (rail car ),. -. -.. - (,, ).. -. -. - 25 50m., (rail car ) 800m.,.,, (foamed polyurethane), (foamed concrete) (fly ash),. 16
97-1-3 [Urea peroxide ; 124 - (, vermiculite), (( ), ( ).. 17
97-1-4 [Guazat ine ; 13516 : 97-1- 4 CAS : 13516-27- 3 HS : 2925-20- 9000 RTECS : MF3624100 UN : - : [ G u a z a t i n e ; 13516-27- 3] 3.5% : : Guazatine Iminoctadine 1, 17 - D i g u a n i d i n o - 9 - azaheptadecane B i s (8 - g u a n id in ooc t y l ) amine ( ) : C18H4 1N 7 (355.66) - : 140 - : 8 10-9 mbar (20 ) - :. -. -. -. 18
97-1-4 [Guazat ine ; 13516 - : 300m g/ kg (LD5 0, rat ), 300mg/ kg (LD5 0, m ou se) : 73mg/ m 3 / 4hr (LC50, rat ) : 1,500mg/ kg (LD50, mouse) -,,. -. - -, ACGIH -. -. -. ( ) -,,. - (positive pressure selfcontained breathing apparatus). -. 19
97-1-4 [Guazat ine ; 13516 -. -.. 15.. - ( : pocket mask ).. (mouth - to- mouth ).. -. -.. -. -. -. - ( )... -,,,. -, (fog ),. 20
97-1-4 [Guazat ine ; 13516 -, (rail car ),. -. - 100 200m. -. -.. -. -. -,. -., -,.. 21
97-1- 5 [Gl ut ar a l dehyde ; 11 : 97-1- 5 CAS : 111-30- 8 HS : 2912-19- 9000 RTECS : MA2450000 UN : - : [Glu - taraldehyde; 111-30- 8] : 1,5- : Glutaraldehyde 1,5- Pentanedial OH C - (CH 2 )3 - CH O ( ) : CHO(CH 2 )3CHO(100.11) - : 187 189 (100%), 101 (50%) - : - 14 (100%), - 21 (50%) - : 0.72(100%), 1.13(50%) - (20 ) : 17mmHg (100%), 2.04Pa (50%) - ( =1) : 3.4 - : - : - (log Pow ) : 0.01(50% ) - (odour threshold) : 0.04ppm - :,,,.. - ( ). - 22
97-1- 5 [Gl ut ar a l dehyde ; 11. - (strong oxidizer ). -.,,,,. -,,,.. - : 480mg/ m 3 / 4hr (LC50, rat ) : 134mg/ kg (LD5 0,rat ), 100mg/ kg (LD50, mouse) 50mg/ kg (LD5 0, guinea pig ) : 2,500mg/ kg (LD50, rat ), 5840mg/ kg (LD5 0, mouse) : 17900 / kg (LD5 0,rat ), 13900 / kg (LD50, mouse) : 9800 / kg (LD5 0,rat ), 15400 / kg (LD50, mouse) - : 250 / 24hr - [Standard Draize test] : 6mg/ 3D (human ) - [Standard Draize test] 2mg/ 24hr (rabbit) - [Standard Draize test] -,,. -,,,. -,. - 2 10%,,. 23
97-1- 5 [Gl ut ar a l dehyde ; 11 -,.. -. - 508 (ph 5), 102 (ph 7), 46 (ph 9) ph. - (moderately ) (algae). - T WA 0.7mg/ m 3 - ACGIH T WA -, 0.8mg/ m 3 ST EL/ CEILING(C) : 0.2ppm, 0.82mg/ m 3 (0.13 2%), (2% ), (5% ),, X- ray,, (cross- linking reagent ),. -. -. - (,, ), (,, ), (, ). ( ) -, (neoprene), 24
97-1- 5 [Gl ut ar a l dehyde ; 11 (goggles),. -. - 15... -,. (mouth - to- mouth ). -, 15,. -,. (120 240ml) ( : 15ml/ kg.).. (charcoal slurry ), (saline cathartic), ( : 30 100g, : 15 30g ).. -. -,. -. -,,,. 25
97-1- 5 [Gl ut ar a l dehyde ; 11 -.. -.. -., - (soda ash ) (dry lime). 26
97-1-6 [Gl yc i dyl acr yl at e ; : 97-1- 6 CAS : 106-90- 1 HS : 2916-19- 0000 RTECS : AS9275000 UN : - : [Gly cidyl acrylat e; 106-90- 1] : : Glycidyl acrylate 2,3- Epoxypropyl acrylate ( ) : C6H8O3 (128.14) - : - 41.5 - : 57 (2mmHg ) - :. - : 1.1074(20 ) - ( =1) : 4.4 - : 61 (open cup) - : 415 -. 27
97-1-6 [Gl yc i dyl acr yl at e ; -. -,,. -. - : 210mg/ kg (LD5 0, rat ) : 400 / kg (LD5 0, rabbit ) : 125ppm/ 4hr (LCLo, rat ) - : 50 / 24hr (rabbit) - (Standard Draize test ) : 2mg/ 24hr (rabbit) - (Standard Draize test) -. -. - (monomer ),. - (, salivation ),...,, (trialkyltin ester) (crosslinking agent), -. - (monomer ). 28
97-1-6 [Gl yc i dyl acr yl at e ; -. -. -. ( ) -,,, (splash - proof goggle). - (positive pressure selfcontained breathing apparatus). -. -. -.. 15.. - ( : pocket mask ).. (mouth - to- mouth).. -. -.. -. 29
97-1-6 [Gl yc i dyl acr yl at e ; -. -. - ( )... -,,. -, (fog ). -, (rail car ),. -. - 100 200m. -. -.. -. -. -,. -., -,.. 30
97-1- 7 [Sodi um; 7440- : 97-1- 7 CAS : 7440-23- 5 HS : 2805-11- 0000 RTECS : VY0686000 UN : 1428 : : : Sodium Natrium [Sodium ; 7440-23- 5] ( ) : Na (22.99) - : 881.4 - : 97.82 - : 1.2mmHg (400 ) - :,,,. - : 0.968(20 / 4 ) - : 27.4cal/ g -. -. - 115. -. -.. 31
97-1- 7 [Sodi um; 7440- -,.. -. -. -. - Aluminum br omide, Aluminum chloride, Aluminum fluoride, Antimony tribr omide, Antimony trichloride, Antimony triiodide, Ar senic trichloride, Ar senic triiodide, Bismuth tribr omide, Bismuth trichloride, Bismuth triiodide, Bor on tribr omide, Cupric chloride, F errou s chloride, Iodine monobromide, Manganou s chloride, Mercuric br omide, Mercuric chloride, Mercuric fluoride, Mercuric iodide, Mer curou s chloride, Silicon tetr achloride, Silv er fluoride, Stannic chloride, Stannic iodide + Sulfur, Stannou s chloride, Sulfur dibromide, T hallous bromide, Vanadium pentachloride, Zinc bromide - : 4g/ kg (LD50, mouse). - (, ),,.. - 2 3. -,, 200mg 32
97-1- 7 [Sodi um; 7440-.,,, -,,,. -,,. -. -.. ( ). -,,. -,, (dust - proof goggle),. -. -. -. -. -,. - (mouth - to- mouth ). -,. 33
97-1- 7 [Sodi um; 7440- - 15.. -,.. - (charcoal slurry ) (saline cathartic). -. - n -,. -, (positive pressure self- contained breathing apparatus). -. - /. -. -. -. -. -,,. -,,. -, ( ),. -, (rail car ),. 34
97-1- 7 [Sodi um; 7440- -. -.. -. -. -. - 25 50m., (rail car ) 800m., - ( ), ( )... 35
97-1-8 [Na l ed; 300- : 97-1- 8 CAS : 300-76- 5 HS : 2919-00- 1090 RTECS : TB9450000 UN : 2783 : [Naled; 300-76-5] 1% : : Naled Dibrom Dimethyl 1,2- dibromo- 2,2- dichloroethyl phosphate ( ) : C4H7Br2Cl2O4P (380.8) - : 110 - : 27 (100%) - : 0.0002 mmhg (20.8 ) () - : 500 ppm (25 ) (. ) - : 1.96(20 ) - ( =1) : 13.1( ) (48 90 100% ). * DDVP, DCA, BDCA DDVP DCA, BDVA 36
97-1-8 [Na l ed; 300-. -. -. - (15 ). -. -. - : 52mg/ kg (LD50, duck ), 330mg/ kg (LD5 0, mouse) : 156m g/ m 3 / 2hr (LD 5 0, m ou se ), 7700 / kg (LD 5 0, rat ) -. -. -. -. -. -. - : 42mg/ 21D(skin ) -. 1. - Bluegills (, LC5 0 ) : 0.22mg/ l/ 24hr, 0.18mg/ l/ 96hr Brook trout (, LC5 0 ) : 0.078mg/ l/ 48hr. 37
97-1-8 [Na l ed; 300- - T WA 3mg/ m 3 - ACGIH T WA 3mg/ m 3 -, -. - 2.3. -,,. ( ),,,. -. -. -. -... -,.. -,.... 38
97-1-8 [Na l ed; 300- -.... - (clay ) ( ). -. - (Halo Acid) (Acid Scrubber ).. - ( ).. -.. -. -. - ( ),,,. -,,. - ( ). -, (rail car ),. 39
97-1-8 [Na l ed; 300- -. - 50 100. -.. -.. - (,, ). -. -. -.., - (sodium bicarbonate) (soda ash )/ (slaked lime). (( ), ( ).... ( ) -.,, (foamed concrete) 40
97-1-8 [Na l ed; 300-. (sodium bicarbonate) (soda ash )/ (slaked lime). *. *. 41
97-1-9 [Lead compoun : 97-1- 9 CAS : - HS : - RTECS : - UN : - : : : Lead compounds [Lead compounds], (Lead tetroxide), (Basic lead sulfate), (Lead carbonate) Che mica l Name CAS HS RTECS UN ( ) Dibasic lead 1344-40- 7 HO5PPb3. H2O 2824-90- 0000 OG2880000 2989 phosphite (742.56) Lead acetate 301-04- 2 C4H6O4.Pb (325.29) 2915-29- 9000 AI5250000 1616 Lead chloride 7758-95- 4 Cl2Pb (278.09) 2827-39- 9000 OF9450000 - Lead chromate 7758-97- 6 CrO4.Pb (323.19) 2841-20- 2000 GB2975000 - Lead dioxide 1309-60- 0 O2Pb (239.19) 2824-90- 0000 OG0700000 1872 Lead nit rate 10099-74- 8 N2O6.Pb (331.21) 2834-29- 9000 OG2100000 1469 Lead oxide 1317-36- 8 OPb (223.19) 2824-10- 0000 OG1750000 - Lead thiocyanate 592-87- 0 Pb(SCN)2 (323.4) 2838-00- 3090 - - Lead acetate - : 280 42
97-1-9 [Lead compoun - : (44.3g/ 100cc, 20 ), (221g/ 100cc, 50 ). - : 3.25(20 / 4 ) Lead chloride - : 950 - : 501 - :,,. - : 5.85 Lead chromate - : 844 - : (0.2mg/ l),,,. - : 6.12(15 ) Lead dioxide - : 290 ( ) - :,,,,,. - : 9.38 Lead nitrate - : 470 ( ) - : (37.65mg/ 100cc, 0 ), (127mg/ 100cc, 100 ), (1g/ 75ml), 43% (8.77mg/ 100cc, 22),. - : 4.53(20 ) Lead oxide - : 888 - : 10mmHg (1085 ) - :,,, 43
97-1-9 [Lead compoun. - : 9.53 - ph :. Lead thiocyanate - : 190 ( ) - : mmhg ( ) - : (0.05g/ 100cc, 20 ), (0.2g/ 100cc, 100 ),. - : 3.82(20 ) Basic lead sulfate -. Lead acetate -. -. - 10, 1.69, 22,. - 3, 2.55, 75 200,,.. - 2,,,, humic acid (,,,, ). Lead chloride -. Lead chromate -.. 44
97-1-9 [Lead compoun. Lead dioxide -. - Pb3O4, PbO. Lead nitrate -. -. Lead oxide - 2. - 300 450. Lead thiocyanate -. Basic lead sulfate -. Lead acetate -,, (incompatibility ) (,,,, ). - ( ). -. - Acids, Sol sulfat es, Citr ates, T artrates, Chlorides, Carbonat es, Alkalies, T annin, Phosphat es, Resor cinol, Salicylic acid, Phenol, Chlor al hy drat e, Sulfit es, Vegetable infu sion s, T inctures. Str ong oxidizer s, Hydr ogen peroxide + A ctive m etals, Sodium + Potassium. Lead chloride -,. -. 45
97-1-9 [Lead compoun Lead chromate -,, ( ). Lead dioxide -,,,,. - (red heat ),, ( ). -,,,,,. Lead nitrate -,. -. Lead oxide -,,,,,, seleninyl chloride. 489. Lead thiocyanate -, /. - Basic lead sulfate : 763mg/ kg (LD5 0, rat ), 145mg/ kg (LD5 0, mouse) : 13390 / kg (LD5 0, rat ), 46200 / kg (LD5 0, mouse) Dibasic lead phosphite : 6g/ kg (LD50, rat ) Lead acetate 46
97-1-9 [Lead compoun : 150m g/ kg (LD5 0, rat ), 140mg/ kg (LD5 0, m ou se) : 104mg/ kg (LD5 0, mose), 25mg/ kg (LD5 0, rabbit ) Lead chloride : 1947mg/ kg (LD5 0, rat ) : 1251mg/ kg (LD5 0, rat ) Lead chromate : 12mg/ kg (LD5 0, mouse) Lead dioxide : 220mg/ kg (LD5 0, guinea pig ) Lead nitrate : 74mg/ kg (LD5 0, mouse) : 93mg/ kg (LD5 0, rat ) - : 100mg/ 24hr (rabbit ) - [Standard Draize test]( ) - : Cat. 1( ) - : EEC- 3( ), EEC- 3, A2( ) -. - 1, 5. -. -,,,,,,,, ( ),,,,,,,, ( ). -,,,, ( ). 47
97-1-9 [Lead compoun - Bluegill sunfish (LC50 ) : 400ppm/ 96hr Rainbow trout (, LC50 ) : 0.14ppm/ 96hr Pink shrimp (LC5 0 ) : 375ppm/ 48hr - -,,,,,,,. - ( ). - T WA 0.05mg/ m 3 (Pb) ST EL - - ACGIH T WA - ST EL/ CEILING(C) -,, ( ),, ( ),,,,,, ( ),,, ( ),, ( ),,, ( ),, ( ) -,,,. -. -. -,,,,,,,,,, ( ). -, ( ). 48
97-1-9 [Lead compoun ( ) -. -,,.,,. -,,,, (dust - proof goggle). -. -. -. -. -,. - (mouth - to- mouth ). -,. 15.. -,.. - (ipecac) (charcoal slurry ), (saline cathartic), (35% ) ( : 30 100g, : 10 15g, 50g.). -. 49
97-1-9 [Lead compoun - (concentration process ),,,.. ( ). -. ( ) ( ). - ( ). -, (positive pressure self- contained breathing apparatus ). - (, ). -,. / ( ). - (, ) ( ). -. -. -. -.. -,,. -,,. -, (rail car ), 50
97-1-9 [Lead compoun -,, (, ).. -. -... - HEPA (high efficiency particulate arrestor ). (bag ). -. -. - 25 50m., (rail car ) 800m.,.,, (foamed polyurethane), (foamed concrete) (fly ash),. ( ), ( ), ( ).. -,,, 10ppm 10 (, ). 51
97-1- 10 [Ni cke l car bonyl ; 134 : 97-1- 10 CAS : 13463-39- 3 : HS : 2931-00- 9090 RTECS : QR6300000 : UN : 1259 Nickel carbonyl Nickel tetracarbonyl : [Nickel carbonyl; 13463-39- 3] 0.1% ( ) : Ni(CO)4 (170.75) - : - 19.3 - : 43 - : 400mmHg (25.8 ) - : 1.32(17 ) - :,,,, (0.018g/ 100mL, 9.8 ). - ( =1) : 5.95(50 ) - : 0.212cP (25 ) - : - 4 - : 60 -. -. 52
97-1- 10 [Ni cke l car bonyl ; 134 -. -. -.. - 60. -. - (Dinitrogen tetraoxide),. - All kinds of acids or acid fumes, All kinds of oxidizing materials, Dinitr ogen tetr aoxide, Br omine (liq.), Mer cury + Oxygen, Oxy gen + But ane, Oxygen + Sodium, Oxygen + Silv er, T etr achlor opropadiene, Nitric acid, Chlorine, Dinitr ogen tetraoxide, n- Butane oxygen mixture - : 235mg/ m 3 / 30min (LC5 0, rat ), 67mg/ m 3 / 30min (LC5 0, mouse), 1,890mg/ m 3 / 30min (LC5 0, cat ) : 63mg/ kg (LD5 0, rat ) : 64mg/ kg (LD5 0, rat ) - : EPA - B2, A 1, EEC- 3 - : Cat. 2 -,,. -,,, 53
97-1- 10 [Ni cke l car bonyl ; 134. - 12 36,,, (cyanosis ). - 3 13,. -.. - T WA 0.12mg/ m 3 ST EL - - AGCIH T WA 0.05mg/ m 3 ST EL/ CEILING(C) -,, -. -. - (, ). -,,,. -. ( ) 54
97-1- 10 [Ni cke l car bonyl ; 134 - (self- contained breathing apparatus ) PVC ().. (mouth- to- mouth ). 20.... -... -, 800m. -. -. -. -. 55
97-1- 10 [Ni cke l car bonyl ; 134 -,,. -,,. - ( ). -, (rail car ),. -. - 100 200m. -. -. -.,. -. -. -., -,. 125m.. -. 300m. 56
97-1- 11 [Nicot ine ; 54 : 97-1- 11 CAS : 54-11- 5 : HS : 2939-70- 0000 RTECS : QS5250000 : UN : 1654 Nicotine 3- (1- M et hy l- 2- pyr r olidinyl)- (S)- pyridine : [Nicotine; 54-11- 5] 1% ( ) : C10H 14N2 (162.23) - : 247 (745mmHg ) - : - 79 - : 1.016(20 ) - ph : 10.2(0.05mol/ sol) - : 1mmHg (61.8 ), 0.0425mmHg (20 ) - ( =1) : 5.61 - : 95 - : 244-60. 57
97-1- 11 [Nicot ine ; 54 -.. -,,,,. -. -. -,. -,. - : 3,340 / kg (LD5 0, mouse), 9,200 / kg (LD5 0, dog ) : 14,560 / kg (LD5 0, rat ), 5,900 / kg (LD50, mouse) : 25mg/ kg (LD50, rat ) -. -. -,,,,,,,,,,,,,. - 40 60mg. - fish ( ) : 3 29ppm w aterfow l(ld5 0 ) : 587m g/ kg - 2ppm. -. 58
97-1- 11 [Nicot ine ; 54 - T WA 0.5mg/ m 3 ( ) - ACGIH T WA 0.5mg/ m 3 ( ) - ( 40% ), -. -,,,,,. -. ( ) - ( ). -. ( ). - 20. -. -..... - ( : pocket mask).. (mouth - to- mouth ). 59
97-1- 11 [Nicot ine ; 54 -. -.. - 820 1,600. -.. -. -.. - ( ).. -,,,. -,,. -, (rail car ),. -. - 50 100. 60
97-1- 11 [Nicot ine ; 54 -... - (,, ). -. -., - (( ), ( )..... -.,, (foamed concrete).. 61
97-1- 12 [Ni t robenzene ;98 : 97-1- 12 CAS : 98-95- 3 HS : 2904-20- 9010 RTECS : DA6475000 UN : 1662 : : : Nitrobenzene Nitrobenzol [ N i t r o b e n z e n e ; 98-95- 3] ( ) : C6H5NO2 (123.11) - : 6 - : 211 - : 0.245mmHg (25 ) - :,,,,, (0.2 g/ ml, 20 ). - : 1.204(20 ) - ( =1) : 4.1 - : 2.91cP (2.95 ), 2.71cP (5.94 ), 2.48cP (9.92 ), 2.24cP (14.94 ), 2.03cP (20 ) - : 88 - : 480 62
97-1- 12 [Ni t robenzene ;98 -, (Almond). - (20 ). -,,. - 5% (Aluminum chloride). - (e.g. Urea perchlorate). -, 120 ( ). - / (silver perchlorate) - (shock - sensitive solvated salts ).. -,,,,,, (,,,, ). - : 590mg/ kg (LD5 0, mouse), 489mg/ kg (LD50, rat ) : 556ppm/ 4hr (LC5 0, rat ) -,. - ( ). ferrous (Fe +2 ) ferric (Fe +3 ). 63
97-1- 12 [Ni t robenzene ;98 15%. -,,,. -,,,,. - : 1 5g ( ) - Bluegill(, LC5 0 ) : 42,000mcg/ L/ 48hr (5 38% ). - T WA 5mg/ m 3 - ACGIH T WA 5mg/ m 3,,,,,,,. -. -,,,. -. -,,,. ( ),,,, (positive pressure self- contained breathing 64
97-1- 12 [Ni t robenzene ;98 apparatus). -. -,. -... -,. (mouthto- mouth ), ( : pocket mask). - 100%. -,.. (20 ).. -,..... -. -. -. - 88 /. 65
97-1- 12 [Ni t robenzene ;98 -. -.. -. -. -. -,,. -,,. - ( ) -, (rail car ),. -. - 25 50. -. -.. -. -. - (,, ). -. -., 66
97-1- 12 [Ni t robenzene ;98 -,,. -. - (sodium bicarbonate) - (sand- soda ash mixture). (( ), ( )...,, (foamed polyurethane), (foamed concrete). 67
97-1- 13 [Di ami da fos ; 1754 : 97-1- 13 CAS : 1754-58- 1 HS : 2919-00- 9000 RTECS : TD2800000 UN : 1259 : : : Diamidafos Nellite Phenyl N,N ' - dimethylphosphorodiamidate [Diamidafos ; 1754-58 - 1] 1% ( ) : C8H 13N 2O2P (200.2) - : 101 103 - :. -,,,. 50g/L(20 ). -. -. : 140mg/ kg (LD5 0, rat ), 63mg/ kg (LD5 0, rabbit ), 13m g/kg (LD5 0, bir d- wild bir d species ) 68
97-1- 13 [Di ami da fos ; 1754 : 100mg/ kg (LD5 0, rabbit ) - (10ppm 90, ). 50 500mg/ kg. -. -,,,,,,,,,. -. -. -, ACGIH. -. -. - (, ). ( ) - (Self- contained breathing apparatus), PVC ( ) 69
97-1- 13 [Di ami da fos ; 1754.. (mouth- to- mouth ). 20..,.. -. -, 800m. -. -. -. -,, -,,. - ( ) -, (rail car ), 70
97-1- 13 [Di ami da fos ; 1754.. -. - 100 200. -. -. -.,. -. -. -., - (, vermiculite), ( ), ( ). -. 71
97-1- 14 [Di az i non ; 333 97-1- 14 CAS : 333-41- 5 HS : 2920-10- 9000 RTECS TF3325000 UN : 2783 : [Diazinon ; 333-41- 5] 1% : : Diazinon Dimpylate Diethyl 2- isopropyl- 4- methyl- 6- pyrimidinyl phosphorothionate ( ) : C12H2 1N 2O3PS (304.4) - : 83 84 (0.002mmHg ), - : 0.00009mmHg (25 ), 22mmHg (112 ) - :, (0.004%, 20 ). - : 1.117(20 ) - : 82.2 - (volatility ) : 2.4mg/ m 3 (20 ) -. 72
97-1- 14 [Di az i non ; 333 -,. -. - (diazoxon) - 1 (pseudo first - order rate) (ph 3.1 10.9). -, (incompatibility ). - : 250mg/ kg (LD5 0, rat, male), 285mg/ kg (LD5 0, rat, female)17mg/ kg (LD5 0, mou se), 143mg/ kg (LD50, rabbit ), 250mg/ kg (LD5 0, guinea pig ) : 3,500mg/ m 3 / 4hr (LC50, rat ), 1,600mg/ m 3 / 4hr (LC50, mouse), 5,500mg/ m 3 / 4hr (LC5 0, guinea pig ) : 180mg/ kg (LD5 0, rat ), 2,750mg/ kg (LD50, mouse), 3,600mg/ kg (LD50, rabbit ), 633mg/ kg (LD5 0, pig ) : 58mg/ kg (LD5 0, mouse) : 65mg/ kg (LD5 0, rat ), 33mg/ kg (LD5 0, mouse) - : 100mg (rabbit ) - [Standard Draize test] : 500mg (rabbit ) - [Open Draize test] - (organophosphate),,. -. -, (, sweating),,,, (, salivation),,,. - (, rhinorrhea). 73
97-1- 14 [Di az i non ; 333 - (sympathoadrenal discharge), (, miosis ),,, (ocular pain ),, (slurring of speech),,, (disorientation ),.. 0.5mg/ ml 74%. - Goldfish : 0.1mg/ L -,. 20 ph 5 31, ph 7.4 185, ph 9.0 136 ph 6 2 3. - 24 290nm ph 736%. 1m, 1m/ s 3m/ s 46. -. ( : 4.83 ). - ph 6. 3 8.. (3 10% ). - T WA 0.1mg/ m 3 ST EL - 74
97-1- 14 [Di az i non ; 333 - ACGIH T WA 0.1mg/ m 3 ST EL/ CEILING(C) - -. -. -. ( ) -,,. - (positive pressure selfcontained breathing apparatus). -. -,. -. -.. 15.. - ( : pocket mask ).. (mouth - to- mouth ).. -. 75
97-1- 14 [Di az i non ; 333 -, ( ). -,. - ( ). -. -,,.. -. -. -. - ( )... -,,,. -, (fog ),. -, (rail car ),. -. - 25 50m. 76
97-1- 14 [Di az i non ; 333 -. -.. -. -. -,. -., - (, vermiculite), ( ), ( ). -. - (,, ).. 77
97-1- 15 [Di a fent hi ur on ; 8006 : 97-1- 15 CAS : 80060-09- 9 HS : 2030-90- 2090 RTECS : XN9100000 UN : - : [ D i a f e n t h i u r o n ; 80060-09- 9] : : Diafenthiuron 1- t ert - Bu ty l- 3- (2,6- diis opr opyl- 4- ph en ox y - phenyl)thiourea ( ) : C2 3H32N2OS (384.63) - : 144.6 147.8 - : 1.09(20 ) - : < 2 10-6 Pa (25 ) - : (0.06g/ L, 25 ), (320g/ L, 25 ), (330g/ L, 25 ), (43g/ L, 25 ), n - (9.6g/ L, 25 ), n - (26g/ L, 25 ). - (logpow ) : 5.76 -. -,. 78
97-1- 15 [Di a fent hi ur on ; 8006 - : 2,068mg/ kg (LD5 0, rat ), 1,500mg/ kg (LD5 0, duck ), 1,500mg/ kg (LD50, quail) : 558mg/ m 3 / 14hr (LC5 0, rat ) : 2g/ kg (LD5 0, rat ) -. - Mallard duck (LD5 0 ) : 1,500mg/ kg Bobwhite quail(lc50, ) : 1,500mg/ kg/ 8d Rainbow trout (LC5 0 ) : 0.0007mg/ L/ 96hr Bluegill(LC5 0) : 0.0013mg/ L/ 96hr Bee(LD5 0) : 2.1 / 48hr Carp(LC50 ) : 0.0038mg/ L/ 96hr Daphnia (EC50 ) : 0.5mg/ L/ 48hr -,. -. - ( : < 1 1.4 ). -, ACGIH, -. ( ) 79
97-1- 15 [Di a fent hi ur on ; 8006 -,.. -. -.. 20.. - ( : pocket mask).. (mouth - to- mouth ). -. -,,. -. -, (rail car ),. -. - 25 50. -. -.. -. -. 80
97-1- 15 [Di a fent hi ur on ; 8006 -., -. -. 81
97-1- 16 [Di a l i fos ; 1031 : 97-1- 16 CAS : 10311-84- 9 HS : 2920-90- 9000 RTECS :TD5165000 UN : 2783 : [Dialifos ; 10311-84- 9] 1% : : Dialifos S - 2 - Ch lor o - 1- ph t h a l - imidoethyl O,O- diethylphosphorodithioate ( ) : C14H 17ClNO4PS2 (393.85) - : 67 69 - :. - : 6.2 10-8 mmhg (20 25 ) () - :, 20(76%), (40%), (62%), (57%), (50%), (< 1%), (< 1%). - (log Pow ) : 4.69 82
97-1- 16 [Di a l i fos ; 1031 -,. 50% ph 8 2.5. -. -,,,. -. - : 5mg/ kg (LD5 0, female rat ), 43 54mg/ kg (LD50, m ale rat ), 65m g/ kg (LD5 0, female m ou se), 39m g/ kg (LD5 0, mou se, male), 94mg/ kg (LD50, dog ), 35mg/ kg (LD5 0, r abbit ) : 28mg/ kg (LD5 0, rat ), 145mg/ kg (LD5 0,,rabbit ) -,. -. - (organophosphate poisoning ), (phosphate) (cholinesterase). - (organophosphate poisoning ) (muscarinic effect ), (nicotinic effect ), (central effect ). - ( ),, ( ), ( ), ( ),,,, ( ),,,,,, ( ). -,. 83
97-1- 16 [Di a l i fos ; 1031-2.3mcg/ cm 3 0.66mcg/ cm 3 65. -,. -, ACGIH, ( ),,,. -. -,,,. -. - 2. ( ), ( ),, (positive pressure self- contained breathing apparatus). -. -, 24. -,,. - 20... 84
97-1- 16 [Di a l i fos ; 1031 -,. (mouthto- mouth ), ( : pocket mask).. -.., 95%,.. -,.. (charcoal slurry ), (saline cathartic), (35% ) ( : 50 100g, : 1.0 1.5g/ kg, 50g.). ( )(12 : 20 30g, 12 : 250mg/ kg ), (4ml/ kg, 300ml.). - ( : 10 15 0. 4 2.0mg, : 10 15 0.02 0.05mg/ kg )... -. -. -. -.. -. 85
97-1- 16 [Di a l i fos ; 1031 -. -. -,,. -,. - ( ). -, (rail car ),. -. - 25 50. -. -.. -. -. - (,, ). -. -. - (bag )., - ( ), ( ) ph, (chlorine- 86
97-1- 16 [Di a l i fos ; 1031 active compound, ) ( )., ( )(chloramine). - (sodium bicarbonate) 3 (sodium hypochlorite, ),. ( ), ( ),.. - / (clay/ bentonite sw ale), (polyethylene- lined dams). (sodium hypochlorite),, (slaked lime),. (powdered activated carbon ) (granular activated carbon ). 87
97-1- 17 [WSCP; 31512-74 : 97-1- 17 CAS : 31512-74- 0 : HS : 2921-29- 9000 RTECS : TR1650000 : UN : - W SCP P o l y [ o x y e t h y l e n e : (dim ethylimin o)ethylen e (dim et h y lim in o )- [WSCP; 31512-74- 0] ethylene dichloride] 1% Poly [oxy - 1,2- ethanediyl- (dim ethy lim inio)- 1,2- et h an ediy l (dim et hy l- iminio)- 1,2- ethanediyl dichloride] ( ) : (C10H24N2O)n.2Cl - : 100 - :. - : 1.15g/ ml(25 ) - : 135 -. 88
97-1- 17 [WSCP; 31512-74 - (anionic polymer s)(incom - patibility ). - : 1850mg/ kg (LD5 0, rat ) : 2g/ kg (LD50, rabbit ) -. -,,,. -,. -,, ( ). -,,,,,,,,,, ( ),,,,, ( ). - Rainbow trout (LC5 0 ) : 0.47mg/ L/ 96hr Bluegill sunfish (LC50 ) : 0.34mg/ L/ 96hr Fathead minnow (LC50 ) : 0.43mg/ L/ 96hr Daphnia magna (LC5 0) : 0.37mg/ L/ 96hr Sheepshead minnow (LC50 ) : 600mg/ L/ 96hr My sid shrimp(lc50 ) : 13.0mg/ L/ 96hr Mallard duck (, LD50 ) : 805.0mg/ kg Bobwhite quail(, LC5 0) : 1,100.0mg/ kg -. 89
97-1- 17 [WSCP; 31512-74 -, ACGIH, (, ) -. -,,,. -. -. ( ). -,,. -, (splash - proof goggle), ( ). -. -. -. 15.. -,. - (mouth - to- mouth ). -,. -,. 90
97-1- 17 [WSCP; 31512-74. - (charcoal slurry ), (saline cathartic), (35% ) ( : 30 100g, : 10 15g, 50g.). - (diazepam ).( : 5 10mg, : 0.2 0.5mg/ kg ). -. -. -. -, (positive pressure self- contained breathing apparatus ). -. -. - ( ). -.. -. -,,. -,,. -, (rail car ),. 91
97-1- 17 [WSCP; 31512-74 -. -... -. -. - 25 50m., (rail car ) 800m.,.,, (foamed polyurethane), (foamed concrete) (fly ash),. - (, vermiculite), (( ), ( ).. 92
97-1- 18 [Decamethr ine ; 52918 : 97-1- 18 CAS : 52918-63- 5 HS : 2916-20- 9000 RTECS : GZ1233000 UN : - : [ D e c a m e t h r i n e ; 5 2 9 1 8-6 3-5 ] : : Decamethrine Deltamethrine - C y a n o - 3 - p h e n ox y - benzyl [1R- [1 (S * ),3 ]]- 3- (2,2- dibromovinyl)- 2,2- dim et hy lcy clopr opan ecarb oxylate ( ) : C2 2H 19Br 2NO3 (505.24) - : 300 ( ) - : 98 101 - : - : 0.002mmPa (25 ) - : 1.5 10-8 mmhg (25 ) - (log Pow ) : 5.43 - : (2 / L), (15g/ L), (500g/ L), (450g/ L), (900g/ L), (250g/ L), (750g/ L). 93
97-1- 18 [Decamethr ine ; 52918 - (40 6 ). -. -. -,,. - : 785mg/ m 3 / 2hr (LC50, rat ) : 9360 / kg (LD5 0, rat ), 20mg/ kg (LD5 0, mouse), 4640m g/ kg (LD5 0, duck), 300g/ kg (LD50, dog ) : 10mg/ kg (LD5 0, mouse) : 3440 / kg (LD5 0, dog ), 2526 / kg (LD5 0, rat ) -. -,. -. -,. - 100 -, 10 94
97-1- 18 [Decamethr ine ; 52918. -, ACGIH (,, ) - 15 30.. ( ) -,,. -,,. -. -,. -. -. - 15. -, -. -,.. 95
97-1- 18 [Decamethr ine ; 52918 -. -. -. -,,. -. - 50 100.. -.. -.,..,, (foamed concrete). -. - (pyrethrins ) 10ppm, 10. 96
97-1- 19 [Dodine ; 2439- : 97-1- 19 CAS : 2439-10- 3 HS : 2925-20- 9000 RTECS : MF1750000 UN : - : [Dodine; 2439-10-3] : : Dodine Cyprex Dodecylgu anidine acet ate C2H4O2 ( ) : C13H 29N 3 C2H 4O2 (287.44) - : 136 - : 1.5 10-7 mmhg (25 ) - : 9.01 10-1 1 m 3 / mol ( ) - : -, (7 23% ). 640mg/ L (25 ). -.. - (incompatibility ). -. 97
97-1- 19 [Dodine ; 2439- (moderately alkaline). -. - : 660mg/ kg (LD50, rat ), 266mg/ kg (LD50, mouse), 535mg/ kg (LD50, r abbit ), 176mg/ kg (LD5 0, guinea pig ), 1142mg/ kg (LD5 0, duck ), 788mg/ kg (LD5 0, quail) : 129mg/ m 3 / 2hr (LD5 0, mouse) : 6g/ kg (LD50, rat ), 2100mg/ kg (LD5 0, rabbit ) - 2 800mg/ kg rat ( ). - mouse 0.05% ( ), ( ),. rat AT P. -,. - 50%,. -. - 2, 3 ph ( )(nitrite). - 5%68. 98
97-1- 19 [Dodine ; 2439-. BCF 0.33. -, ( 1 2hr ). -, ACGIH -. -. ( ) -,.. (mouth - to- mouth ). (charcoal slurry ) (isotonic saline).. -. 99
97-1-20 [Dr azoxol on ; 5707 : 97-1- 20 CAS : 5707-69- 7 HS : 2921-49- 0000 RTECS : NY2800000 UN : - : [ D r a z o x o l o n ; 5707-69- 7] 1% : : Drazox olon 4 - ( 2 - C h l o r o p h e n y l - hy dr azono)- 3- methyl- 5- isox azolone ( ) : C10H8ClN 3O2 (237.66) - : 167 - : 533 Pa (30 ) - : (40g/ kg ), (100g/ kg ), (10g/ kg ), (50g/ kg ). -. 100
97-1-20 [Dr azoxol on ; 5707 - : 126m g/ kg (LD5 0, r at ), 129m g/ kg (LD5 0, m ou se), 100mg/ kg (LD5 0, rabbit ), 12,500 / kg (LD50, guinea pig ) : 20mg/ kg (LD5 0, rat ) : 20mg/ kg (LD5 0, rabbit ) -,,. -. - Brown tr out (LC50 ) : 0.55mg/ L/ 96hr. -, ACGIH -. -. -. ( ) -,,. - (positive pressure self- 101
97-1-20 [Dr azoxol on ; 5707 contained breathing apparatu s). -. -. -.. 15.. - ( : pocket mask ).. (mouth - to- mouth).. -... -. -. -. - ( )... 102
97-1-20 [Dr azoxol on ; 5707 -,,. -, (fog ),. -, (rail car ),. -. -. -.. -. -. -,. -., -,.. 103
97-1-21 -n- [Di -n-but yl ami ne ; : 97-1- 21 CAS : 111-92- 2 HS : 2921-19- 9090 RTECS : HR7780000 UN : 2248 : - n- [D i - n - b u t y l a m i n e ; 111-92- 2] : - n - : Di- n- butylamine N- Butyl- 1- butanamine n- Dibutylamine n - Bu - N H - Bu - n ( ) : C8H 19N (129.24) - : 159 160 - : - 60-59 - : 0.7601(4 ) - : 22mmHg (20 ) - ( =1) : 4.46(1 ) - : 57 - : (3.5g/ L, 25 ),,,,. -. -. 104
97-1-21 -n- [Di -n-but yl ami ne ; -. -. - : 550mg/ kg (LD5 0, rat ), 290mg/ kg (LD5 0, mouse), 230mg/ kg (LD5 0, guinea pig ) : 1,010 / kg (LD5 0, rabbit ) : 110 / kg (LD5 0, rat ) - : 250 (rabbit ) - : 10mg/ 24hr (rabbit) - (Open Draize test) 20mg/kg(rabbit) - (Standard Draize test) -,,,,.,,. - 2 3. -. -. - 14.3. - 4.4.. -. 105
97-1-21 -n- [Di -n-but yl ami ne ; -, ACGIH 2-, (Dibu ty l am m on iu m oleat e ),. -. -, (acid chlorides), (acid anhy - drides),,. -. ( ) -. -,. -. -. -. -,. ( : pocket mask ).. (mouth - to- mouth ). -. - 30... -,. 106
97-1-21 -n- [Di -n-but yl ami ne ; -.... -. -. -,, /. - ( ). -. -,. -,,,. -,,. *. -, (rail car ),. -. -. - 50 100. -. 107
97-1-21 -n- [Di -n-but yl ami ne ; -. -.. - (,, ). -. -., - ( ), ( ).. -.,, (foamed concrete). *. 108
97-1-22 [Di nex ; 131- : 97-1- 22 CAS : 131-89- 5 : HS : 2908-90- 1000 RTECS : SK6650000 : UN : 2588 Dinex 2,4- Dinitro- 6- cyclohexylphenol : 2- Cyclohexyl- 4,6- dinitrophenol [Dinex ; 131-89- 5] 0.5% ( ) : C12H 14N2O5 (266.25) - : 106.5 107.5 - : 9.2 - : (15ml/ L, 25 ), (48%), (40%), (1.9%), (2.5 6%). -. -. -. 109
97-1-22 [Di nex ; 131- -. -. -. - : 50mg/ kg (LD5 0, gunea pig ), 65mg/ kg (LD50, rat ), 50mg/ kg (LD5 0, m ou se), 81mg/ kg (LD5 0, r abbit ), : 25mg/ kg (LD5 0, mouse) - : 105mg/ 9D (I, rabbit ) - [Standard Dr aize test] -. -. -. - 3 5mg/ kg,,,,,. -,.... 110
97-1-22 [Di nex ; 131- -.,. -, 6.8. -, ACGIH (, ) -,. -,. ( ) -,,. -. -,.. -,,. 111
97-1-22 [Di nex ; 131- -,.. -. 20.. -,.. -.. - rotary kiln incineration (820 1600 ), fluidized bed incineraion (450 980 ). -. -. -,,. -. -,. -,,,. 112
97-1-22 [Di nex ; 131- -.. - (,, ). -. -,. - 250m 800m., -,. 113
97-1-23 [Di nobut on ; 973 : 97-1- 23 CAS : 973-21- 7 HS : 2918-90- 0000 RTECS : FF9100000 UN : - : [Dinobuton ; 973-21- 5] 1% : : Dinobuton Carbonic acid, 2- secbutyl- 4,6- dinitrophenyl isopropyl ester Isopropyl 2,4- dinitro-6- secbutylphenyl carbonate ( ) : C14H 18N2O7 (326.30) - : 56 57 - : 10mbar (20 ) - : (0.1mg/ 100ml, 20 ), (120mg/ 100ml, 20 ), (8.3mg/ 100ml, 20 ), (89mg/ 100ml, 20 ). -. -. 114
97-1-23 [Di nobut on ; 973 -, dinoseb. -,,,. -. - (dinoseb). -. - : 80mg/ m 3 / 4hr (LC50, rat ) : 59mg/ kg (LD5 0, rat ), 108mg/ kg (LD5 0, mouse) : 125mg/ kg (LD5 0, mouse) : 3200mg/ kg (LD5 0, rabbit ) -. -. - 2 (neutrophils ). - 1 5, 5,. - ruminal fluid. dinoseb. 1.6 10-8 atm - cu m/ mole. 115
97-1-23 [Di nobut on ; 973 (BCF 580). - (Koc 6800). - 1.1 10-6 mmhg, 2. -, ACGIH, - 0. -,,. ( ) -,. -. -,,. -,. -,.. 20.. -,. 116
97-1-23 [Di nobut on ; 973 -.. - NOx 2 1000. -. -. -. -,,. -. -,. -,,,. -.. - (,, ). -,. - 250m 800m., -. 117
97-1-24 [Di noseb ; 88- : 97-1- 24 CAS : 88-85- 7 HS : 2908-90- 1000 RTECS : SJ9800000 UN : 2779, 2780, 3013 : [ D i n o s e b ; 88-85- 7] 1% : : 2,4- Dinitro- 6- sec- butylphenol 2- (1- M ethylpr opy l)- 4,6- dinitrophenol Dinoseb DNDP ( ) : C10H 12N2O5 (240.24) - : 38 42 - : 1.2647(4 ) - : 1mmHg (151.1 ) - : 27 - : (0.0052g/ 100g ), (48g/ 100g ), n - (27g/ 100g),,,. - ph : (acidic phenol) -. 118
97-1-24 [Di noseb ; 88- -. -. - (mild steel). -. - : 16mg/ kg (LD5 0, mouse), 9mg/ kg (LD50, duck ), 7,100 / kg (LD5 0, bird), 20mg/ kg (LD5 0, guinea pig ) : 80mg/ kg (LD50, rat ), 80mg/ kg (LD5 0, rabbit ) : 20,368 / kg (LD5 0, rat ) : 10mg/ kg (LD50, mouse) - : 50 / 24hr (rabbit ) - [Standard Draize test] -,,. -,.. -, (tachypnea ),.. - Goldfish : 0.4ppm/ 24hr (LC10 0). 119
97-1-24 [Di noseb ; 88- - ph. - ( : 14 18 ). - 4.1. - BCF = 68(50ml/ L, w ater ) -, ACGIH ( ),. -. ( ) -. -. - 30... -,.... -. 120
97-1-24 [Di noseb ; 88- -,,,,. -. -.. -,,. -,. - ( ). -, (rail car ),. - 25 50. -.. -.. - (,, ). -. -. -., - (( ), ( ). 121
97-1-24 [Di noseb ; 88-.. -.,,, (foamed concrete). (fly ash). -. (,, ).. 122
97-1-25 [Di nocap ; 39300- : 97-1- 25 CAS : 39300-45- 3 HS : 2914-70- 9000 RTECS : GQ5775000 UN : - : [ D i n o c a p ; 39300-45- 3] 1% : : Dinocap Crotothane DPC 2- Butenoic acid, 2(or 4)- isooctyl- 4,6(or 2,6)- dinitrophenyl ester ( ) : C18H24N2O6 (364.44) - : 138 140 - : 4 10-8 mmhg (20 ), 5.6 10-10 mmhg (25 ) - : 1.10(20 ) - :,, (4mg/ L, 25 ). -. -. - (caprylphenol) 123
97-1-25 [Di nocap ; 39300-. -. -, - (incompa - tibility ). - : 1,102mg/ kg (LD5 0, rat ), 49,500 / kg (LD50, mouse), 3g/ kg (LD5 0, r abbit ), 100mg/ kg (LD5 0, dog ) : 360mg/ m 3 / 4hr (LC50, rat ) : 9,400mg/ kg (LD50, rabbit ) : 23mg/ kg (LD5 0, rat ) -., (tachycardia ), (cyanosis) ( ).. -,... - 124
97-1-25 [Di nocap ; 39300- Lake trout (, LC50 ) : 75 / L (15, ph 7.2 7.5) Goldfish (, LC50 ) : 33 / L (18, ph 7.2 7.9) - 2 4.. - (gravitational settling ). ( 9.3 10.3, 1 2 ). -, ACGIH,... 20. - (systemic). -,. - (cerebral edema ). -... 125
97-1-25 [Di nocap ; 39300- -. -,. -, NOx. (dinitrophenol derivatives ). * (binapacryl), (dinitro cresol), (dinoseb ), (dinobuton ) (dinitrocyclohexylphenol). -. -. -. -. -. -, 800m. -. - ( ). -, (rail car ),. -. - 100 200m. 126
97-1-25 [Di nocap ; 39300- -. -. -.,. -. -., -,. -,. -. 127
97-1-26 [Di not er b ; 1420 : 97-1- 26 CAS : 1420-07- 1 HS : 2908-90- 1000 RTECS : SK0160000 UN : 1599 : [Dinoterb; 1420-07- 1] 1% : : Dinoterb 2- tert - Butyl- 4,6- dinitrophenol 2,4- Dinitro- 6- tert - butylphenol DNT BP ( ) : C10H 12N2O5 (240.24) - : 125.5 126.5 - : 165 166 - : 1.5 10-6 mbar (20 ) - : - (log Pow ) : 3.51 - : (100g/ kg ), (100g/ kg ), (100g/ kg ), (200g/ kg ), (200g/ kg ), (200g/ kg ) 128
97-1-26 [Di not er b ; 1420 -. -,. -. - (incompatibility ). - : 26mg/ kg (LD5 0, rat ), 9500 / kg (LD5 0, mouse), 28300 / kg (LD5 0, rabbit ) : 150mg/ kg (LD5 0, guinea pig ) -. -, (, sweating ),,,,,,,,,,, (, rhinorrhea). -. - Gammarus fasciatus (LC50 ) : 2600 / L/ 96hr Rainbow trout (LC5 0 ) : 31 / L/ 96hr Largemouth bass (LC5 0) : 142 / L/ 96hr Bluegill(LC5 0) : 23 / L/ 96hr Goldfish (LC5 0 ) : 497 / L/ 96hr Fathead Minnow (LC5 0 ) : 6.0mg/ L/ 96hr - 1. 129
97-1-26 [Di not er b ; 1420 -, ACGIH, (1) -. -,,. -. ( ). -,,. - (Self- contained breathing appratus),,. -. -. -,. - (mouth - to- mouth ). -,. 15.. -,.. 130
97-1-26 [Di not er b ; 1420 -... -. -. - ( ). -. -. -. -.. -,,. -,. -, (rail car ),. -. -.. 131
97-1-26 [Di not er b ; 1420 -. - 200m. 800m. -,.,, (foamed polyurethane), (foamed concrete) (fly ash),. (, ) (gelling agent ) (solidify ). 10ppm 10. 132
97-1-27 [DDT; 50-29 : 97-1- 27 CAS : 50-29- 3 HS : 2903-62- 2000 RTECS : KJ3325000 UN : 2761, 2765 : [DDT ; 50-29- 3] 1% : : DDT 1,1- Bis (4- chloroph enyl)- 2,2,2- trichloroethane 2,2- Bis (p- chlor ophenyl)- 1,1,1- trichloroethane ( ) : C14H9Cl15 (354.48) - : 260 - : 108.5 - : 0.99 - : 1.6 10-7 mmhg (20 ) - : 72 77 (162 171, closed cup) - : 110 - : (2.5 10-2 mg/ L), (100,000ppm ). (58g/ 100ml), (78g/ 100ml), (45g/ 100ml), (74g/ 100ml), (116g/ 100ml), (28g/ 100ml), (10g/ 100ml), (3g/ 100ml), (8 10g/ 100ml), (75g/ 100ml), 133
97-1-27 [DDT; 50-29 (60g/ 100ml). - (Pow ) : 6.91 -. -, (iron ). - (lipophilic). -, (iron ),,. - DDT,,. 0.1Ndehydrochlorination. (sodium dichromate)/. (active metals ). - : 87mg/ kg (LD5 0, rat ), 250mg/ kg (LD5 0, rabbit ), 150mg/ kg (LD5 0, guinea pig ) : 1,931mg/ kg (LD50, rat ), 300mg/ kg (LD5 0, rabbit ), 1g/ kg (LD50, guinea pig ) : 9,100 / kg (LD5 0, rat ), 32mg/ kg (LD50, mouse), : 1500mg/ kg (LD5 0, rat ), 250mg/ kg (LD5 0, rabbit ) : 50mg/ kg (LD5 0, rat ), 184mg/ kg (LD5 0, mouse), 900mg/ kg (LD5 0, guinea pig ) - : EPA - B2, NT P - b, IARC- 2B, EEC- 3 -,,. 134
97-1-27 [DDT; 50-29 -,.. -. -. -,,,,,,,,,,.,, ( ).. - Bluegill(, LC5 0 ) : 26 / L/ 24hr Goldfish (, LC50 ) : 180 / L/ 24hr Rainbow trout (, LC50 ) : 42 / L/ 24hr - ( : 2 ). ( :100 ). - ( :50 ).. - (wet and dry deposition ). ( : 2 ). -. - (BCF : 10 3 10 5 ). - T WA 1mg/ m 3 ST EL - - ACGIH T WA 1mg/ m 3 ST EL/ CEILING(C) - 135
97-1-27 [DDT; 50-29. -. -,,,.. -,,. ( ),, ( ),, (positive pressure self- contained breathing apparatus). -. - 20... -,. (mouthto- mouth ), ( : pocket mask). -,.. (20 ).. -,... 136
97-1-27 [DDT; 50-29 - rotary kiln 820 1600. - DDT / /. -.. -. -. -. -,,,. -,,. - ( ). -, (rail car ),. -. - 25 50. -. -,. -.. -. -. 137
97-1-27 [DDT; 50-29, - ( ), ( )..,,. 10ppm 10. HEPA (high - efficiency particulate arrestor ),. -,, (foamed concrete). 138
: 97-1- 28 CAS : 122-15- 6 HS : 2924-29- 9090 RTECS : FA1500000 UN : - : [ D i m e t a n ; 122-15- 6] 1% 97-1-28 [Di met an ; 122- : : Dimetan 5,5 - D i m e t h y l - 3 - o x o - cyclohex- 1-enyl dimethylcarbamate ( ) : C1 1H 17NO3 (211.29) - : 170 180 (11mmHg ) - : 45 46 - :,, (3.15g/ 100mL, 20 ). -. - : 120mg/ kg (LD50, rat ), 90mg/ kg (LD5 0, mouse) 139
97-1-28 [Di met an ; 122- -,. -. -,,,, (mydriasis) (urinary incontinence), ( ),,, (cellulitis ), (stupor ), (hypotonicity ), (tachycardia). -, ACGIH -. -,,,. -. ( ) -,. -. -..... 140
97-1-28 [Di met an ; 122-20. -. - (protopam )... - (charcoal slurry ). ( ) (). - (pralidoxime). - (diazepam ) (lorazepam ).. -. -. -. -. -. -, 800m. -. - ( ). -, (rail car ), 141
97-1-28 [Di met an ; 122-. -. - 100 200m. -. -. -.,. -. -. -., -,. -,. 142
97-1-29 [Dimethoat e ; 60- : 97-1- 29 CAS : 60-51- 5 HS : 2920-90- 9000 RTECS : TE1750000 UN : - : : : Dimethoate Phosphorodithioic acid, O,Odimethyl S- [2- (methylamino)- [Dimethoate; 60-51- 5] 2- oxoethyl] ester 1% ( ) : C5H 12NO3PS2 (229.2) - : 117 (0.1mmHg ) - : 51 52, 45 47 (96%) - : 1.277(65 ) - : 8.5 10-6 mmhg (25 ) - : 107 (closed cup) - : 20(>300g/ kg), (>300g/ kg ), (>300g/ kg), (>300g/ kg), (>300g/kg), (>300g/kg), (>50g/kg), (ph 5 23.3g/ L, ph 7 23.8g/ L, ph 9 25g/ L). - (logpow ) : 0.78 143
97-1-29 [Dimethoat e ; 60- -. -. ph 9, ph 2 0.8, 21. -. - (dithio- isomer ),,,,. -. - : 152mg/ kg (LD5 0, rat ), 60mg/ kg (LD5 0, mouse), 152mg/ kg (LD5 0, rabbit ), 350mg/ kg (LD5 0, guinea pig ), 30mg/ kg (LD5 0, human ) : 353mg/ kg (LD5 0, rat ), 1g/ kg (LD5 0, mouse), 1g/ kg (LD50, r abbit ), 965m g/ kg (LD5 0, guinea pig ) : 350mg/ kg (LD5 0, rat ), 60mg/ kg (LD5 0, mouse) -,,. -. - (organophosphate poisoning ) (muscarinic effect ), (nicotinic effect ), (central effect ). -,,,,,,. -. -. 144
97-1-29 [Dimethoat e ; 60- -,. - Bluegill(LC5 0) : 6.0mg/ L/ 96hr, 58mg/ L/ 24hr Rainbow trout (LC5 0 ) : 6.2mg/ L/ 96hr Carp(LC50 ) : 22.39mg/ L/ 168hr -, ( : 2.5 16 ). -,, ( : 8 ). -, ( : 2.83 ).. -. -, ACGIH (,, ) -. -,,,.. - 25, - 13.9. -,,. - 1. ( ), (), 145
97-1-29 [Dimethoat e ; 60-,. -. -,,. -. -,. - 15... -,.. -,.... -,... -. ph 2, ph 9 21 (70 ), 0.8 (70 ). (soda ash ) 3 5%. - (, vermiculite). -,,,. -. 146
-. -. -. -.. -,,. -,,. - ( ). -, (rail car ),. -. - 25 50. -. -... - (bag). -. 97-1-29 [Dimethoat e ; 60-, -, ( ), ph, (chlorineactive compound, ) 147
97-1-29 [Dimethoat e ; 60- ( )., (chloramine). - ( ), ( ),.. - / (clay/ bentonite sw ale), (polyethylene- lined dams). ( ) ( ). 148
97-1-30 -S- [Demet on-s-met hyl sul fone ; 17 : 97-1- 30 CAS : 17040-19- 6 HS : 2920-10- 9000 RTECS : TF9050000 UN : - : - S - [Demeton - S- methylsulfone; 17040-19- 6] 1% : - S- : Demeton- S- methylsulfone O,O- Dimethyl S- 2- (ethylsulfonyl)ethyl phosphorothioate ( ) : C6H 15O5PS 2 (262.30) - : 120 (0.003mmHg ) - : 60 - : 660 Pa (20 ) - : (10g/ kg, 20 ), (600g/ kg, 20 ). -. - 149
97-1-30 -S- [Demet on-s-met hyl sul fone ; 17. - : 32,400 / kg (LD50, rat ), 30mg/ kg (LD50, mouse), 50mg/ kg (LD5 0, rabbit ), : 195mg/ m 3 / 4hr (LC50, rat ) : 500mg/ kg (LD5 0, rat ) : 21mg/ kg (LD5 0, rat ) : 22mg/ kg (LD5 0, rat ) -.,,,,, (giddiness),,,,,. - (organophosphate), (cholinesterase). - (muscarinic effect), (nicotine effect ), (central effect). - ( ),, ( ), ( ), ( ),,,, ( ),,,,,,.,. -, ACIGH 150
97-1-30 -S- [Demet on-s-met hyl sul fone ; 17 -.,,,.. ( ) -,,. -. - (positive pressure self- contained breathing apparatus )., 2 3 ( : 15 0.4 2.0mg, : 15 0.05mg/ kg ) - 2 12 ( : 0.02 0.05mg/ kg ). - (, ). -, (pralidoxime)( : 1.0g, : 20 30mg/ kg - ). - (charcoal slurry ) (35% ) ( : 50 100g, : 1 1.5-300 800ml). ( ) ()( : 20 30g, : 250mg )... - ( ) (furosemide). 151
97-1-30 -S- [Demet on-s-met hyl sul fone ; 17 -. -. -,. - /. (, ). -.. -.. -. -. -. -. - ( )... - CO2,. - (fog ),. -, (rail car ),. 152
97-1-30 -S- [Demet on-s-met hyl sul fone ; 17 -. -. - 25 50m., (rail car ) 800m. -. -. -. - (,, ). -. -,. -. -., -,, (foamed concrete). - ( ), ( )... -. 153
97-1-31 - [Demet on-met hyl ; 802 : 97-1- 31 CAS : 8022-00- 2 HS : 2920-10- 9000 RTECS : TG1760000 UN : - : - [D e m e t o n - m e t h y l ; 8022-00- 2] 1%. : - : Demeton- methyl Metasy stox Phosphorothioic acid, O- [2- (ethylthio)ethyl] O,Odim ethyl ester, mixt. with S- [2- (ethylthio) ethyl] O,O-dimethyl ester ( ) : C6H 15O3PS 2 (230.30) - : 89 ( ) - : 1.2 - : 0.0004mmHg ( ) - : (330ppm, 25 ) 154
97-1-31 - [Demet on-met hyl ; 802 -. -. - (thiono-, thiolo- ). - 300ppm, ph 9.0 (synergistic effect ). -,,. - : 75mg/ kg (LD5 0, rat ), 26mg/ kg (LD5 0, mouse) : 300mg/ kg (LD5 0, rat ) : 12mg/ kg (LD5 0, rat ) -. -. -. -,,,,,. ( ). -. - Fish (, LC10 0 ) : 5.0ppm/ 288hr Harlequin fish (, LC50 ) : 6.5ppm/ 48hr 155
97-1-31 - [Demet on-met hyl ; 802 Carp(LC50 ) : 10 40 mg/ L/ 48hr - 7.6 (ph 6, 70, ). - T WA 0.5mg/ m 3 - ACGHI T WA 0.5mg/ m 3 ( ) (, ) -. -,,,. - (,, ). ( ) -, (splash - resistant glass ),,. -. -,,.. -,. - (mouth - to- mouth ). 15.. -, 156
97-1-31 - [Demet on-met hyl ; 802... -.. -. -. -,,. -.. -. -.. -.. - (,, ). -., -, ( ). 157
97-1-32 [Demet on ; 8065- : 97-1- 32 CAS : 8065-48- 3 HS : 2920-10- 9000 RTECS : TF3150000 UN : - : [Demeton ; 8065-48- 3] 1% : : Demeton Systox Phosphorothioic acid, O,Odiethyl O- [2- (ethylthio) ethyl] ester, mixt. with O,O- diethyl S- [2- (ethylthio)ethyl] phosphorothioate ( ) : C8H 19O3PS 2C8H 10 (258.34) - : 134 (2mmHg ) - : 1.1183(20 ) - : 3.4 10-4 mmhg (20 ) - : 94.8 (closed cup) 158
97-1-32 [Demet on ; 8065- - : 513.7 - : - : 200ppm ( - S ), 60ppm ( - O),,. - O, - S. -. -. -. - - O : 123 (1mmHg ) : 1.119(21 ) : 38mmHg (20 ) : (60mg/ L, 20 ). - - S : 128 (1mmHg ) : 1.132(21 ) : 35mmHg (20 ) : (2g/ L, 20 ). - - O - S. -,, (incompatibility ). -,. - (compatible). -. - ph 9(70 ) 1.25. - (leptophos) 159
97-1-32 [Demet on ; 8065-. -,,. - : 1700 / kg (LD5 0, rat ), 7850 / kg (LD5 0, mouse), 7190 / kg (LD5 0, duck ), 8480 / kg (LD50, pigeon), 8480 / kg (LD5 0, quail) : 8200 / kg (LD5 0, rat ), 24mg/ kg (LD5 0, rabbit ) : 2500 / kg (LD5 0, rat ), 4mg/ kg (LD5 0, mouse), 3250 / kg (LD5 0, rabbit ) : 1750 / kg (LD5 0, rat ), 3900 / kg (LD5 0, mouse) -. -.. -. -. - Bluegill(, ) : 0.1ppm/ 2 8hr - Rainbow trout (LC5 0 ) : 1 10mg/ L/ 24hr Coturnix jponica (LC5 0 ) : 275ppm/ 5D Anas platyrhynchos (LC5 0 ) : 598ppm/ 5D - T WA 0.1mg/ m 3 ( ) 160
97-1-32 [Demet on ; 8065- - ACGHI T WA 0.11mg/ m 3 ( ) (,, ) -. - 24.. -. ( ). -,,. -,,. -. -,.. 20.. -,.. - (charcoal slurry ) ( : 50 100g/ 300 161
97-1-32 [Demet on ; 8065-800ml, : 1.0 1.5g/ kg ). ( ), (). - 15 0.4 20mg, 2 3. - ( ) (Furosemide). -. - (, vermiculite), ( ), ( ). - thiono-, thiolo- 20 75 50% ph 13 0.85 50%. -,. - /. - (, ). - (, ) (flashback). -,,. -,,. -. -,,. 162
97-1-32 [Demet on ; 8065- -. -. -.. -.. - - 200m. 800m., -. 163
97-1-33 [Di met i l an ; 64 : 97-1- 33 CAS : 644-64- 4 HS : 2924-29- 9090 RTECS : EZ9084000 UN : : [D im e t il a n ; 644-64- 4] 1% : : Dimetilane 1- [(Dimethylamino)carbonyl]- 5- methyl- 1H- pyrazol- 3- yl dimethylcarbamate ( ) : C10H 16N4O3 (240.30) - : 200 201 (13mmHg ) - : 68 - : 1 10-4 mmhg (20 ) - : 24% (25, water ),,,,,.. -. 164
97-1-33 [Di met i l an ; 64. - : 25mg/ kg (LD50, rat ), 60mg/ kg (LD5 0, mouse), 9mg/ kg (LD50, bird) : 600mg/ kg (LD5 0, rat ), 90mg/ kg (LD5 0, mouse), 2m g/ kg (LD5 0, r abbit ) : 12mg/ kg (LD50, mouse) : 4mg/ kg (LD50, mouse) -.,,,,,,, (miosis ),,,,,,,,. - (carbametes). - (carbametes). -, ACGIH ( ) 165
97-1-33 [Di met i l an ; 64 -.,,,.. ( ) - (splash- resistant glass). - (MSDS),. -. -,. - 2 3 ( : 15 0.4 2.0mg, : 15 0.05mg/ kg ). - 2 12 ( 0.02 0.05mg/ kg). -,, (phenothiazine), (reserpine). - (adrenergic amine). - (ipecac) ( : 30ml, : 15ml). -. -. 166
97-1-33 [Di met i l an ; 64 -,. /. -. -.. - CO2,,. - (fog ),. -. -, (rail car ),. -. - 25 50. -. -.. -. 167
97-1-33 [Di met i l an ; 64 -. - (,, ). -.., - (( ), ( )... -.,, (foamed concrete).. 168
97-1-34 [Dimethylvinphos ; 227 : 97-1- 34 CAS : 2274-67- 1 HS : 2919-00- 1090 RTECS : TB8805000 UN : - : [D i m e t h y l v i n p h o s ; 2274-67- 1] 1% : : Dimethylvinphos Dimethylvinfos 2- Chloro- 1- (2,4- dichlorophenyl)vinyldim ethyl phosphate ( ) : C10H 10Cl3O4P (331.52) - : 69 70 - : 1.26(25 ) - : 1.333 10-3 mmhg (25 ) - (logkow ) : 3.12 - : (300 350g/ L, 20 ), (350 400g/ L, 20 ), (450 500g/ L, 20 ) (130ppm, 20 ). 169
97-1-34 [Dimethylvinphos ; 227 -. -. - : 97,500 / kg (LD5 0, rat ), 167mg/ kg (LD5 0, mouse) : 970 1,186mg/ m 3 / 4hr (LC50, male rat ), 4,900 mg/ kg/ 4hr (LC5 0, fem ale r at ) - Carp (, LC50 ) : 2.3ppm/ 24hr -, ACGIH -. -,,,. -. ( ) -,. -. - 170
97-1-34 [Dimethylvinphos ; 227..... 20.. -. -. -. -. -. -, 800m. -. - ( ). -, (rail car ),. -. - 100 200m. -. -. -.,. 171
97-1-34 [Dimethylvinphos ; 227 -. -. -., -,. -,. 172
97-1-35 [Di me fox ; 115- : 97-1- 35 CAS : 115-26- 4 HS : 2919-00- 9000 RTECS : TD4025000 UN : : [ D i m e f o x ; 115-26- 4] 1% : : Dimefox BFPO Bis (dimethylamino)fluorophosphine oxide Bis (dim ethylamido)flu orophosphate ( ) : C4H 12FN 2OP (154.15) - : 67 (4mmHg ), 86 (15mmHg ) - : 1.1151(4 ) - : 0.36mmHg (25 ) - :,,.. -. -. -. - 173
97-1-35 [Di me fox ; 115-. - (vigorous oxidizing agent ).. - (leptophos). - ( ). - : 1mg/ kg (LD5 0, rat ), 2mg/ kg (LD50, mouse), 3m g/ kg (LD5 0, r abbit ), 2mg/ kg (LD50, cat ), 2mg/ kg (LD5 0, monkey ) : 2mg/ kg (LD5 0, rat ) -.,,,,, (giddiness),,,,,. -, ACIGH., - 25 30. ( ) -. -,,. 174
97-1-35 [Di me fox ; 115- -, 2 3 ( : 15 0.4 2.0mg, : 15 0.05mg/ kg ) - 2 12 ( : 0.02 0.05mg/ kg ). - (, ). -, (pralidoxime)( : 1.0g, : 20 30mg/ kg - )... - (ipecac) ( : 30ml, : 15ml). - 15. (emesis ) ( : 100g [8 100oz], : 30g [3 4oz]). - ( ),. *. ( ). -. -. -. -. - ( ). -. 175
97-1-35 [Di me fox ; 115- -.. - CO2,. - (fog ),. -, (rail car ),. -. - 25 50. -.. -.. - (,, ). -., - (( ), ( ).. (sodium carbonate), (sodium bicarbonate), (slaked lime), (crushed limestone). 176
97-1-35 [Di me fox ; 115-. -.,, (foamed concrete). 177
97-1-36 [Diquat dibromide ; 8 : 97-1- 36 CAS : 85-00- 7 HS : 2933-39- 9000 RTECS : JM5690000 UN : - : [Diqu at dibromide; 85-00- 7] 1%. : : Diqu at dibromide 1,l' - Ethylene- 2,2' - dipyridylium dibromide Reglone ( ) : C12H 12Br 2N 2 (344.07) - : 335 340 - : 1.22 1.27(20 ) - : 1.33 10-5 mmhg (20 ) - : - : - : (70g/ 100ml, 20 ). - (logpow ) : - 3.05 178
97-1-36 [Diquat dibromide ; 8 -. ph 9 12 ( ) (complex ). - (inert clay ) (anion sur - factant ),. - (, ). -, (HBr ). - (cation ). - (charge- transfer complex ) (ion - exchange mechanism ). - (hydrophobic- hydrophilic interation ) (dissociation constants). - (bentonite, ph 4.1, 8.2) (, ph 3.2, 5.3). - ph 8.14, ph 7.12 (ClO, chlorine oxide). - : 194 274mg/ kg (LD50, rat ), 100 200mg/ kg (LD50, dog ), 106 146mg/ kg (LD5 0, mouse),72 138mg/ kg (LD5 0, r abbit ), 564m g/ kg (LD5 0, duck), 30mg/ kg (LD5 0, cattle, goat, sheep), 100m g/ kg (LD5 0, guinea pig ), 200 400mg/ kg (LD50, hen) : 433mg/ kg (LD5 0, rat ), 500mg/ kg (LD5 0, rabbit ) - : 10mg (rabbit ) - [Standard Draize test] : 400mg/ kg/ 20D(rabbit ) - [Standard 179
97-1-36 [Diquat dibromide ; 8 Draize test] -,.. -,,,,,. -, ( ), ( ),., BUN (blood urea nitrogen )(creatinine) ( ). - (soft ). -, ( ). - : 100mg/ kg ( ) - Bluegill(, LD50 ) : 245mg/ L/ 96hr - Rainbow trout (, LD5 0) : 90mg/ L/ 24hr -. 22 80% 2 4. CO2. 1%, 19%. 4.48kg/ ha 0.05ppm 8.,.. - (aerosol), ( : 48hr ),., (clay ). 180
97-1-36 [Diquat dibromide ; 8. - 310nm, 48 96hr 50 75%. -. - T WA 0.5mg/ m 3 - ACGIH T WA 0.5mg/ m 3 (dust ), 0.1mg/ m 3 (particulate material) ST EL/ CEILING(C) 1.0mg/ m 3 (,. ),,,. -. -,,,.. ( ) (goggles),,,. -. -. -... 181