년도 발간등록번호 ( 국립환경과학원 ( 뒷면아래 )

Transcription

1 년도 발간등록번호 ( 국립환경과학원 ( 뒷면아래 )

2 목차 ⅰ 요약문 ⅻ i ii

3 iii iv

4 v vi

5 vii viii

6 < 부록 A1 : On-Road mobile source> 161 < 부록 A2 : Oil Station source> 162 < 부록 A3 : Petroleum transport and storage> 165 < 부록 A4 : Municipal waste incineration> 167 < 부록 A5 : Municipal waste landfill source> 169 < 부록 A6 : Surface coating Operations-Solvent-Case Paint> 170 < 부록 A7 : Coil coating> 171 < 부록 A8 : Automobile refinishing coating source> 172 < 부록 A9 : Degreasing composite> 175 < 부록 A10 : Asphaltic concrete-in place Road Asphalt> 176 < 부록 A11 : Printing> 177 < 부록 A12 : Consumer and commercial solvent use> 178 ix x

7 xi xii

8 xiii xiv

9 xv xvi

10 xvii 1

11 2 3

12 4 5

13 1. 연구목표 2.1 국내외배출량산정방법분석을통한배출량신뢰도향상 6 7

14 2.2 VOCs 배출원에대한외국정책사례조사및저감방안검토 8 9

15 2.3 오존관리를위해개선이필요한 VOCs 배출원분류및 VOCs 관리정책에대한향후연구계획 ( 로드맵 ) 검토 1. 국내 VOCs 배출량 1.1 인위적배출원 10 11

16 1.1.1 에너지산업연소 12 13

17 1.1.2 비산업연소 14 15

18 1.1.3 제조업연소 16 17

19 1.1.4 생산공정 18 19

20 1.1.5 에너지수송및저장 유기용제사용 20 21

21 1.1.7 도로이동오염원 22 23

22 1.1.8 비도로이동오염원 폐기물처리 기타면오염원 24 25

23 2. 미국 VOCs 배출량 2.1 인위적배출원 1.2 자연배출원 26 27

24 2.1.1 연료연소 산업공정 28 29

25 2.1.3 도로이동오염원 유기용제 비도로이동오염원 30 31

26 2.1.6 화재 원유시설 주유소 기타비산업 농업 32 33

27 폐기물처리 3. 유럽의 VOCs 배출량 3.1 인위적배출원 2.2 자연배출원 연료연소 34 35

28 3.1.2 비도로이동오염원 도로이동오염원 36 37

29 3.1.4 연료에의한비산배출 산업공정 1) 광물공정 2) 화학물질공정 38 39

30 3) 금속공정 4) 기타생산공정 유기용제사용 1) 도료사용 40 41

31 2) 세정및세탁 4) 기타유기용제사용 농업 3) 화학제품 1) 분뇨관리 42 43

32 2) 농업토양 3) 노천소각 4) 기타 폐기물 1) 매립 44 45

33 2) 폐수처리 4) 기타폐기물 3) 폐기물소각 기타면오염원 3.2 자연배출원 46 47

34 4. 국내배출량신뢰도평가 생산공정 4.1 인구백만명당배출량비교 연료연소 에너지수송및저장 48 49

35 4.1.4 유기용제사용 비도로이동오염원 도로이동오염원 폐기물처리 50 51

36 4.2 국내 VOCs 배출원의 DARS 평가 DARS(Data Attribute Rating System) 평가 기타면오염원 e a e a e a e a e a e a e a e a 52 53

37 4.2.2 국내배출원의 DARS 평가결과 54 55

38 1. 국내배출량산정방법검토 56 57

39 1.1 에너지산업연소 58 59

40 1.2 비산업연소 60 61

41 1.3 제조업연소 62 63

42 1.4.1 석유산업공정 제품생산 (1) 제철제강공정 1.4 생산공정 64 65

43 (3) 유기화학제품제조업 (2) 무기화학제품제조업 66 67

44 68 69

45 70 71

46 3) 기타제조업 (1) 목재및펄프제조업 (2) 기타제조업 1.5 에너지수송및저장 4) 식음료가공 72 73

47 1.6 유기용제사용 도장시설 세정시설 74 75

48 1.6.3 세탁시설 기타유기용제사용 1) 인쇄시설 2) 가정및산업용유기용제사용 3) 아스팔트도로포장 76 77

49 1.7 도로이동오염원 78 79

50 1.8 비도로이동오염원 건설장비 농업기계 80 81

51 1.8.3 철도 82 83

52 1.8.4 항공 선박 84 85

53 1.9 폐기물처리 2. 배출량신뢰도향상을위한배출량산정방법개선방향 2.1 연료연소 배출원목록비교 1.10 기타면오염원 86 87

54 2.1.2 배출량산정방법비교 88 89

55 90 91

56 2.2 생산공정 92 93

57 2.2.1 배출원목록비교 94 95

58 2.2.2 배출량산정방법비교 2) 유기화학제품제조업 1) 석유산업공정 96 97

59 98 99

60 2.3 에너지수송및저장 배출량산정방법비교 배출원목록비교

61 2.4 유기용제사용 배출량산정방법비교 배출원목록비교 1) 도장시설

62 104 2) 세정및세탁 105

63 3) 기타유기용제사용

64 폐기물처리 배출원목록비교 109

65 2.5.2 배출량산정방법비교 2.6 기타면오염원 배출원목록비교

66 2.6.2 배출량산정방법비교 2.7 농업

67 2.8 배출량산정방법개선방향

68 1. 국내 VOC 저감대책 1.1 국내의 VOCs 정의

69 1.2 국내의 VOCs 저감대책 사업장부문 면오염원부문 도로이동오염원부문 비도로이동오염원부문

70 2. 국외 VOCs 저감대책 2.1 미국의 VOCs 관리현황

71 2.2 유럽의 VOCs 관리현황

72 2.3 일본의 VOCs 관리현황

73

74

75 1. 국외 POCP 를고려한오존생성기여도 1.2 영국 1.1 미국

76 2. 국내 POCP 를고려한오존생성기여도

77 3. 수도권의배출원별배출량기여도및 POCP 기여도 3.1 서울시

78 3.1.1 도로이동오염원 유기용제사용

79 3.2 인천시 도로이동오염원 유기용제사용

80 3.3.1 도로이동오염원 3.3 경기도

81 3.3.2 유기용제사용 4. 대기중오존농도관리를위한 VOCs 관리방향

82 Ⅴ. VOCs 배출량산정개선을위한연구방향및로드맵 1.1 인벤토리업데이트필요성 1. VOCs 인벤토리업데이트주기제안 1.2 업데이트주기제안

83 2. 향후연구계획로드맵 2.1 VOCs 배출량산정방법개선연구 (1) 석유제품산업의석유정제공정별배출계수개발연구 1) 개요 2) 추진계획

84 (2) 에너지수송및저장부문의배출계수개발연구 (3) 도장시설별배출계수개발을통한배출량신뢰도향상연구 1) 개요 1) 개요 2) 추진계획 2) 추진계획

85 (4) 세정시설의부문의배출계수개선연구 (5) 아스팔트도로포장부문의배출계수개선연구 1) 개요 1) 개요 2) 추진계획 2) 추진계획

86 (6) 폐기물처리부문의배출계수개선연구 (7) 산림에서의 VOCs 배출계수및자연배출원배출량산정방법개발연구 1) 개요 1) 개요 2) 추진계획 2) 추진계획

87 (8) 누락 VOC 배출원및배출계수개발연구 (9) 농업부문의배출계수및배출량산정방법개발연구 1) 개요 1) 개요 2) 추진계획 2) 추진계획

88 2.2 POCP 를고려한 VOCs 배출관리방안연구 1) 개요 2) 추진계획 VOCs 관리로드맵 로드맵과제 1단계 2단계 3단계 석유제품산업의석유정제공정별배출계수개발 연구 에너지수송및저장부문의배출계수개발연구 배출계수및 배출목록 개선연구 도장시설별배출계수개발을통한배출량신뢰도향상연구세정시설의부문의배출계수개선연구아스팔트도로포장부문의배출계수개선연구 폐기물처리부문의배출계수개선연구산림에서의 VOCs 배출계수개발및자연배출원배출량산정방안연구누락 VOCs 배출원및배출계수개발연구 VOCs 배출량산정방법개선연구 POCP 를고려한 VOCs 배출원관리방안연구 157

89

90 < 부록 A1 : On-Road mobile source> no. chemical compound Mass fraction(%) Molar mass(g/mole) 1 n-butane toluene m-xylene and p-xylene ,2,4-trimethylbenzene ethylene methylpropane; isobutane butene methyl-butane benzene methylpentane n-pentane methylpentane propylene ,3-dimethylbutane methylhexane n-hexane acetylene ,3-dimethylpentane trans-2-butene o-xylene n-heptane methylcyclopentane ethylbenzene cis-2-pentene ,3,5-trimethylbenzene trans-2-pentene cis-2-butene ethane methylheptane methylhexane propane methyl-2-butene pentene ,2,4-trimethylpentane methylcyclohexane n-nonane ,3,4-trimethylpentane methylheptane n-octane ,4-dimethylpentane ,2-dimethylbutane cyclopentane styrene cyclohexane isoprene

91 < 부록 A2 : Oil Station source> no. chemical compound Mass fraction(%) Molar mass(g/mole) 1 2,3-dimethylbutane methylpentane n-heptane n-hexane methylcyclohexane methylhexane n-pentane methylhexane methyl-butane toluene m,p-ethyltoluene propane ,2,4-trimethylbenzene trans-2-pentene ,3-dimethylpentane n-octane hexene ,4-dimethylpentane ,2,4-trimethylpentane methylheptane m-xylene and p-xylene methylheptane Benzene butene n-nonane ,3,5-trimethylbenzene n-decane cis-2-pentene pentene o-xylene o-ethyltoluene ,2,3-trimethylbenzene methylcyclopentane ethylbenzene ,3,4-trimethylpentane < 부록 A2 : Oil Station source> no. chemical compound Mass fraction(%) Molar mass(g/mole) 36 trans-2-butene n-undecane ,2-dimethylbutane n-butane isoprene n-propylbenzene cis-2-butene n-dodecane ,4-diethylbenzene(para) methylpentane cumene(isopropylbenzene) ,3-diethylbenzene(meta) cyclohexane (1-methylpropyl)benzene(sec-butyl benzene) n-butylbenzene trichloroethylene(tce) napthalene methyl-4-isopropylbenzene styrene methylpropane; isobutane ,3-butadiene

92 < 부록 A3 : Petroleum transport and storage> no. chemical compound Mass fraction(%) Molar mass(g/mole) 1 2,3-dimethylbutane methyl-butane n-pentane methylpentane n-hexane trans-2-pentene methylhexane methylhexane butene cis-2-pentene methylcyclopentane pentene hexene n-heptane ,3-dimethylpentane toluene methylcyclohexane ,4-dimethylpentane benzene ,2-dimethylbutane n-butane m-xylene and p-xylene isoprene trans-2-butene methylheptane cis-2-butene ,2,4-trimethylpentane m,p-ethyltoluene methylheptane ,2,4-trimethylbenzene ethylbenzene o-xylene methylpentane n-octane cyclohexane < 부록 A3 : Petroleum transport and storage> no. chemical compound Mass fraction(%) Molar mass(g/mole) 36 1,3,5-trimethylbenzene ,3,4-trimethylpentane o-ethyltoluene n-propylbenzene ,2,3-trimethylbenzene methylpropane; isobutane n-nonane ,4-diethylbenzene(para) styrene cumene(isopropylbenzene) n-decane propane ,3-butadiene propylene n-undecane ,3-diethylbenzene(meta) napthalene n-dodecane n-butylbenzene (1-methylpropyl)benzene(sec-butyl benzene) methyl-4-isopropylbenzene

93 < 부록 A4 : Municipal waste incineration> no. chemical compound Mass fraction(%) Molar mass(g/mole) 1 toluene n-butane m-xylene and p-xylene propylene m,p-ethyltoluene n-decane ethylbenzene methyl-butane methylpropane; isobutane o-xylene n-octane n-nonane methylcyclopentane chloroform ,3-dimethylbutane ,3,5-trimethylbenzene n-pentane ,2,3-trimethylbenzene cyclohexane n-dodecane n-heptane butene trichloroethylene(tce) methylcyclohexane n-hexane trans-2-butene cis-2-butene styrene n-propylbenzene methylheptane ethylenedichloride ,4-diethylbenzene(para) methylhexane methylhexane methylpentane < 부록 A4 : Municipal waste incineration> no. chemical compound Mass fraction(%) Molar mass(g/mole) 36 carbontetrachloride methylheptane ,3-diethylbenzene(meta) perchloroethylene benzene cumene(isopropylbenzene) napthalene ,2,4-trimethylpentane pentene methyl-4-isopropylbenzene ,3-dimethylpentane cis-1,2-dichloroethene ,1,1-trichloroethane n-butylbenzene ,4-dimethylpentane n-undecane (1-methylpropyl)benzene (sec-butylbenzene) o-ethyltoluene ,2,4-trimethylbenzene isoprene

94 < 부록 A5 : Municipal waste landfill source> no. chemical compound Mass fraction(%) Molar mass(g/mole) 1 n-decane n-nonane n-dodecane n-undecane toluene m-xylene and p-xylene n-heptane o-xylene methyl-4-isopropylbenzene ,4-diethylbenzene(para) ethylbenzene m,p-ethyltoluene ,2,4-trimethylbenzene ,2,3-trimethylbenzene ,3,5-trimethylbenzene cumene(isopropylbenzene) benzene o-ethyltoluene methylcyclohexane styrene propane napthalene n-propylbenzene ,3-diethylBenzene(meta) methylheptane methylheptane n-butylbenzene n-octane methyl-butane (1-methylpropyl)benzene (sec-butylbenzene) n-hexane ,3-dimethylButane methylhexane Butene < 부록 A5 : Municipal waste landfill source> no. chemical compound Mass fraction(%) Molar mass(g/mole) 35 n-pentane n-butane o-dichlorobenzene trans-2-butene methylpentane cis-1,2-dichloroethene cis-2-butene trans-2-pentene methylcyclopentane ,4-dimethylpentane cis-2-pentene hexene isoprene pentene trichloroethylene(tce) ,2-dimethylbutane ,2,4-trimethylpentane ,3-dimethylpentane methylhexane cyclohexane

95 < 부록 A6 : Surface coating Operations-Solvent-Case Paint> no. chemical compound Mass fraction(%) Molar mass(g/mole) 1 toluene n-butylacetate ,4-dimethylhexane butylcellosolve{2-cutoxyethanol} {egce} o-xylene dimethylcyclohexanes methyl-3-hexanone isomers of xylene methylcyclohexane n-heptane isomers of nonane(c9paraffin) ethylacetate ,4-dimethylpentane trimethylcyclohexanes ethylcyclohexane acetone c5ester methylamylketone dimethylheptanes ethylbenzene methylethylketone(mek) (2-butanone) cyclohexane methylisobutylketone ethylcyclopentane ethyltoluenes {methylethylbenzenes} trimethylcyclopentane methylheptene trimethylbenzenes < 부록 A7 : Coil coating> no. chemical compound Mass fraction(%) Molar mass(g/mole) 1 toluene m-xylene and p-xylene ethylbenzene o-xylene Benzene styrene cumene(isopropylbenzene) n-butane n-hexane n-octane methylcyclopentane propylene ,3,5-trimethylbenzene methyl-Butane n-nonane ,2,4-trimethylbenzene ,3-dimethylbutane cyclohexane methylcyclohexane n-pentane methylpropane; isobutane m-ethyltoluene ,2,3-trimethylbenzene methylhexane methylpentane methylhexane methylpentane p-ethyltoluene

96 < 부록 A8 : Automobile refinishing coating source> no. chemical compound Mass fraction(%) Molar mass(g/mole) 1 m-xylene and p-xylene o-xylene ethyl benzene toluene ,2,4-trimethyl Benzene m,p-ethyltoluene styrene cyclohexane methylcyclopentane ,3-dimethylbutane n-hexane propane ,3,5-trimethylbenzene ,2,3-trimethylbenzene methylpentane o-ethyltoluene propylene n-decane n-propylbenzene butene ,4-diethylbenzene(para) n-nonane n-pentane n-undecane benzene methyl-butane n-dodecane methyl-4-isopropylbenzene ,3-diethylbenzene(meta) napthalene cumene(isopropylbenzene) n-octane methylcyclohexane trans-2-pentene (1-methylpropyl)benzene (sec-butylbenzene) n-butylbenzene methylheptane cis-2-pentene < 부록 A9 : Degreasing composite> no. chemical compound Mass fraction(%) Molar mass(g/mole) 1 1,1,1-trichloroethane trichloroethylene(tce) n-heptane toluene perchloroethylene dichloromethane {methylenechloride} trichlorotrifluoroethane-f isomers of xylene methylcyclohexane acetone isomersofdecane(c10paraffins) methylhexane methylethylketone(mek) (2-butanone) benzene isomersofundecane(c11paraffins) n-nonane ethylether methylnonane methyloctanes dimethylcyclopentane sec-butylalcohol ethylmethylcyclohexanes methyldecanes butylbenzeneisomers trimethylcyclopentane c10olefins dimethylhexanes c8olefins trimethylbenzenes

97 < 부록 A9 : Degreasing composite> no. chemical compound Mass fraction(%) Molar mass(g/mole) 30 dimethyloctanes isomersofdodecane(c12paraffins) Isomers of propylbenzene trimethylcyclohexanes m-xylene and p-xylene trimethylheptanes dimethylnonanes methylpropylcyclohexanes o-xylene butylcyclohexane isomersofc9h methylhexenes dimethylcyclohexanes cyclohexane c11olefins diethylcyclohexane ethylcyclohexane methyldecenes ethylmethyloctane tetramethylcyclopentane decalins(mixedcis,trans) dimethylcyclobutanone methyl-2-isopropylcyclohexane ethylhexane n-pentylcyclohexane n-propylbenzene trimethyloctanes ethyloctenes n-hexane c3/c4/c5alkylbenzenes ethylheptene < 부록 A9 : Degreasing composite> no. chemical compound Mass fraction(%) Molar mass(g/mole) 61 isomers of tetradecane(c14paraffins) cumene(isopropylbenzene) methyldecalins methylnonenes methylpropylnonane methylundecane napthalene Cicyclo[4.3.0]nonane (octahydroindene) c12olefins dimethylbenzylalcohol dimethylheptanes ethyloctane methyldodecanes nonadiene propenylcyclohexane isomers of tridecane(c13paraffins) tetramethylthiourea misc./othervoc

98 < 부록 A10 : Asphaltic concrete-in place Road Asphalt> no. chemical compound Mass fraction(%) Molar mass(g/mole) 1 methane 15.70% methylpropane; isobutane 11.20% n-butane 10.10% benzene 9.50% n-hexane 8.80% isomers of hexane 8.10% butene 5.90% isomers of pentane 5.70% propane 5.50% n-pentane 5.30% ethane 4.60% propylene 3.90% c7 cycloparaffins 3.70% ethylene 2.00% < 부록 A11 : Printing> no. chemical compound Mass fraction(%) Molar mass(g/mole) 1 toluene n-decane n-nonane n-undecane m-xylene and p-xylene ,2,4-trimethylbenzene m,p-ethyltoluene n-dodecane o-xylene ,2,3-trimethylbenzene propane ethylbenzene methylheptane methylheptane o-ethyltoluene ,4-diethylbenzene(para) ,3-dimethylbutane ,3,5-trimethylbenzene n-propylbenzene cyclohexane n-octane n-hexane ,3-diethylbenzene(meta) methylpentane cumene(isopropylbenzene) methylcyclopentane butene benzene n-butylbenzene n-pentane (1-methylpropyl)benzene (sec-butylbenzene)

99 < 부록 A12 : Consumer and commercial solvent use> no. chemical compound Mass fraction(%) Molar mass(g/mole) 1 n-butane 23% methylpropane; isobutane 12% propane 10% distillates/naphtha/mineralspirits 8% isopropyl alcohol 7% methyl alcohol 5% n-heptane 3% n-hexane 3% ethylcyanoacrylate 3% ,1,1-trichloroethane 3% methylalcohol 3% acetone 2% fragrances 2% other,lumpedvocs, individually <2% of category 2% volatilemethylsiloxanes(vms) 2% p-dichlorobenzene 2% toluene 1% perchloroethylene 1% vocingredients<0.1% 1% ethanolamine 1% misc./othervoc 1% hydrocarbonpropellant{lpg} 1% methylethylketone(mek) (2-butanone) 1% ,1-difluoroethane(hfc-152a) 0.38% orangeterpenes 0.25% vinylacetate 0.24% otherexemptpropellants 0.24% methylpentane 0.23% d-limonene 0.22% dichloromethane {methylenechloride} 0.18% dimethylether 0.17% < 부록 A12 : Consumer and commercial solvent use> no. chemical compound Mass fraction(%) Molar mass(g/mole) 32 other,lumpedexempts,individually< 2% of category 0.15% lemonoil 0.13% ethylacetate 0.12% terpene 0.11% ,2,4,6,6-pentamethylheptane 0.11% butane, branched&linear 0.09% orangeoil 0.09% butylcellosolve{2-butoxyethanol} {egbe} 0.06% isomers of xylene 0.06% n-butylacetate 0.05% witchhazel 0.04% benzylalcohol 0.01% t-butylacetate 0.01% di(propyleneglycol)methylether 0.01% misc.lvpvocdistillates 0.01% methylisobutylketone 0.01% o-dichlorobenzene 0.01% cyclohexane 0.01% ethylbenzene 0.01% n-pentane 0.005% dexpanthenol 0.005% glyceryltriacetate 0.004% b-pinene 0.004% glutaraldehyde(adialdehyde) 0.004% propyleneglycolmethylether {1-methoxy-2-propanol} 0.003% methylcarbitol{2-(2-methoxyethoxy) ethanol}{degme} 0.003% methyl-butane 0.003%

100 < 부록 A12 : Consumer and commercial solvent use> no. chemical compound Mass fraction(%) Molar mass(g/mole) 59 hydrocarbonpropellant {lpg,sweetened} 0.002% amino-2-methyl-1-propanol 0.002% a-pinene 0.002% trichloroethylene(tce) 0.001% styrene 0.001% carbitol{degee}{2-(2-ethoxyethoxy)e thanol} 0.001% o-chlorotoluene % terpinene(1-isopropyl-4-methyl-1,4 -cyclohexadiene) % propylacetate % sec-butylalcohol % methylundecane{isododecane} % ,2,4-trimethylbenzene % methyl-2-pyrrolidinone % camphor % methyl-4-isopropylbenzene % propyleneglycol-t-butylether{1-(1,1, -dimethylethoxy)-2-propanol} % myrcene % ,4-dimethyl-2-neopentyl -1-pentene % methylsalicylate(anester) % propyleneglycolbutylether {1-butoxy-2-propanol} % cyclohexamine % dimethylformamide % propyleneglycoln-propylether % diacetonealcohol(4-hydroxy-4-meth yl-2-pentanone) % morpholine(tetrahydro-1,4-oxazin) % < 부록 A12 : Consumer and commercial solvent use> no. chemical compound Mass fraction(%) Molar mass(g/mole) 84 propylene 0.002% n-propylalcohol 0.002% mineraloil 0.002% (2-butoxyethoxy)ethanol {butylcarbitol} 0.001% c3-c4alkanepropellant 0.001% cresols 0.001% triisopropanolamine % misc.hydrocarbonpropellants % other,misc.voc % methoxyethanol {methylcellosolve}{egme} % pineoil % phenoxyethanol % isopropylacetate % diacetonealcohol(4-hydroxy-4-meth yl-2-pentanone) % ,3,5-trimethylbenzene % santosoldimethylester % methylcyclohexane % methoxypropanolacetate % benzene % carene % dl-limonene{dipentene} % polypropyleneglycol %

101 < 부록 A12 : Consumer and commercial solvent use> no. chemical compound Mass fraction(%) Molar mass(g/mole) 106 propyleneglycolmonoethylether % tert-butylalcohol % ethyleneglycolpropylether{2-propox yethanol} % glycoletherdpnb{1-(2-butoxy-1-met hylethoxy)-2-propanol} % benzenederivates % dimethoxymethane(methylal) % ,5-dimethyl-1-hexyne-3-ol % cumene(isopropylbenzene) % propyleneglycolmonomethyletherac etate{2-(1-methoxy)propylacetate} % formaldehyde % isophorone{3,5,5-trimethyl-2-cycloh exenone} %

102 Species POCP Method Reference (1-methylethyl)cyclohexane (1-methylpropyl)cyclohexane (2-methyl-1-propyl)acetate (2-methylbutyl)cyclohexane (2-methylpropyl)cyclohexane ,1,1-trichloroethane Derwentetal.,1998 1,1,1-trichlorotrifluoroethane 0 1 Cydefinition 1,1,2,2-tetrachloroethane ,1,2-trichloroethane ,1,2-trimethylcyclohexane ,1,2-trimethylcyclopentane ,1,3-trimethylcyclohexane ,1,4,4-tetramethylcyclohexane ,1-dichloroethane ,1-dichloroethene ,1-dichlorotetrafluoroethane 0 1 Cydefinition 1,1-dimethylcyclohexane ,1-dimethylcyclopentane ,2,3,4-tetrahydronaphthalene ,2,3,4-tetramethylbenzene ,2,3,5-tetramethylbenzene ,2,3,5-tetramethylcyclohexane ,2,3-trichlorobenzene ,2,3-trimethylbenzene Derwentetal.,1998 1,2,3-trimethylcyclohexane ,2,3-trimethylcyclopentane ,2,4,4-tetramethylcyclopentane ,2,4,5-tetramethylbenzene ,2,4-trichlorobenzene ,2,4-trimethlycyclopentane ,2,4-trimethylbenzene Derwentetal.,1998 1,2,4-trimethylcyclohexane ,2,4-trimethylcyclopentane ,2-diaminoethane ,2-diCromoethane ,2-dichlorobenzene ,2-dichloroethane 7 2 1,2-dichloroethene 42 1 Derwentetal.,1998 1,2-dichlorotetrafluoroethane 0 1 Cydefinition 1,2-dimethyl-3-isopropylcyclopentane ,2-dimethylcyclohexane ,2-dimethylcyclopentane ,2-ethanedioldiacetate ,2-ethylmethylcyclopentane ,2-propanediol JenkinandHayman,1999 1,3,4,5,6-pentahydroxy-2-hexanone 0 3 1,3,5-trichlorobenzene ,3,5-trimethylbenzene Derwentetal.,1998 1,3,5-trimethylcyclohexane Species POCP Method Reference 1,3-Cutadiene Derwentetal.,1998 1,3-dichlorobenzene ,3-diethylbenzene ,3-dimethyl-4-ethylbenzene ,3-dimethyl-5-propylbenzene ,3-dimethylcyclohexane ,3-dimethylcyclopentane ,3-dioxolane ,3-ethylmethylcyclopentane ,3-hexadiene ,4-Cutyrolacetone ,4-dichlorobenzene 5 2 1,4-diethylbenzene ,4-dimethyl-2-isopropylbenzene ,4-dimethylcyclohexane ,4-dimethylpiperazine ,4-dioxane (2-Cutoxy-1-methyl-ethoxy)-2-propanol (2-ethoxy-1-methyl-ethoxy)-2-propanol (2-methoxy-1-methyl-ethoxy)-2-propanol (Cutoxyethoxy)-2-propanol butanal Derwentetal., butanol 62 1 JenkinandHayman, butene Derwentetal., Cutoxy-2-propanol JenkinandHayman, Cutyne chloro-2,3-epoxypropane chloro-4-nitrobenzene chloropropane decene ethoxy-2-propanol ethoxy-2-propylacetate ethyl-1,4-dimethylcyclohexane ethyl-2,2,6-trimethylcyclohexane ethyl-2,3-dimethylbenzene ethyl-2,3-dimethylcyclohexane ethyl-2-methylcyclopentane ethyl-2-propylbenzene ethyl-2-propylcyclohexane ethyl-3,5-dimethylbenzene ethyl-3-methylcyclohexane ethyl-3-methylcyclopentane ethyl-4-methylcyclohexane ethylpropylbenzene heptene hexanal hexene Derwentetal., hydrophenol methoxy-2-butanol

103 Species POCP Method Reference 1-methoxy-2-propanol JenkinandHayman, methoxy-2-propylacetate methyl-1-phenylcyclopropane methyl-1-propylbenzene methyl-1-propylcyclohexane methyl-1-propylcyclopentane methyl-2-isopropylbenzene methyl-2-propylbenzene methyl-3-(isopropyl)benzene methyl-3-isopropylcyclopentane methyl-3-propylbenzene methyl-4-isopropylbenzene methyl-4-isopropylcyclohexane methyl-4-tertbutylbenzene methylbutylbenzene methylcyclohexene methylindan methylindene nonene octene pentanal Derwentetal., pentanol pentene Derwentetal., propanal Derwentetal., propanol JenkinandHayman, methyl-1-dodecanol ,2'-iminodi(ethylamine) ,2'-iminodiethanol ,2,3,3-tetramethylbutane ,2,3,3-tetramethylhexane ,2,3-trimethylbutane ,2,3-trimethylpentane ,2,4,6,6-pentamethylheptane ,2,4-trimethyl-1,3-pentanediol monoisocutyrate 2,2,4-trimethylpentane ,2,5-trimethylhexane ,2-dimethylbutane Derwentetal.,1998 2,2-dimethylhexane ,2-dimethylpentane ,2-dimethylpropane Derwentetal.,1998 2,3,3,4-tetramethylpentane ,3,3-trimethyl-1-butene ,3,3-trimethylpentane ,3,4-trimethylhexane ,3,4-trimethylpentane ,3,5-trimethylhexane ,3-dimethylbutane Derwentetal.,1998 2,3-dimethylfuran Species POCP Method Reference 2,3-dimethylhexane ,3-dimethylnonane ,3-dimethyloctane ,3-dimethylpentane ,3-dimethylundecane ,4,4-trimethyl-1-pentene ,4,6-trichloro-1,3,5-triazine ,4-difluoroaniline 0 3 2,4-dimethyl-1-(1-methylethyl)benzene ,4-dimethyl-1-isopropylbenzene ,4-dimethylfuran ,4-dimethylheptane ,4-dimethylhexane ,4-dimethylpentane ,4-toluenediisocyanate ,5-dimethyldecane ,5-dimethylfuran ,5-dimethylheptane ,5-dimethylhexane ,5-dimethyloctane ,6-dimethyldecane ,6-dimethylheptane ,6-dimethyloctane ,6-dimethylundecane ,6-toluenediisocyanate ,7-dimethyloctane (2-aminoethylamino)ethanol (2-Cutoxyethoxy)ethanol (2-Cutoxyethoxy)ethylacetate (2-ethoxyethoxy)ethanol (2-ethoxyethoxy)ethylacetate (2-hydroxy-ethoxy)ethanol (2-hydroxy-propoxy)-1-propanol (methoxyethoxy)ethanol [2-(2-ethoxy-ethoxy)-ethoxy]ethanol acetoxy-propylacetate aminoethanol butanol JenkinandHayman, butanone Derwentetal., butanoneoxime butene Derwentetal., Cutoxyethanol JenkinandHayman, Cutoxyethylacetate chloroethanol chloropropane chlorotoluene ethoxyethanol JenkinandHayman, ethoxyethylacetate ethoxypropanol

104 Species POCP Method Reference 2-ethyl-1,3-dimethylbenzene ethyltoluene Derwentetal., hexoxyethanol hydrophenol isopropoxyethanol methoxy-2-methylpropane JenkinandHayman, methoxyethanol JenkinandHayman, methoxyethylacetate methoxypropane methylCenzaldehyde methyl-1,3-dioxolane Species POCP Method Reference 2-methyl-1-butene Derwentetal., methyl-1-butylbenzene methyl-1-pentene methyl-1-propanol 36 1 JenkinandHayman, methyl-2,4-pentanediol methyl-2-butene Derwentetal., methyl-2-hexene methyl-2-pentene methyl-2-propanol JenkinandHayman, methyl-5-ethyloctane methylbutanal methylbutane Derwentetal., methyldecalin methyldecane methylfuran methylheptane methylhexane Derwentetal., methylnonane methyloctane methylpentane 42 1 Derwentetal., methylpropanal Derwentetal., methylpropane Derwentetal., methylpropenal methylpropene Derwentetal., methylpropylacetate methylpyridine methylundecane pentanone Derwentetal., pentene Derwentetal., phenoxyethanol phenylpropene propanol JenkinandHayman, propen-1-ol propylacetate JenkinandHayman,1999 3,3,4-trimethylhexane ,3,5-trimethylheptane ,3-dimethylheptane Species POCP Method Reference 3,3-dimethyloctane ,3-dimethylpentane ,4-dimethylheptane ,4-dimethylhexane ,5,5-trimethylhexane ,5-dimethyloctane ,6-dimethyloctane ,7-dimethylnonane (2-hydroxy-propoxy)-1-propanol chloro-4-fluoropicoline chloropropene chloropyridine ethyl-2-methylheptane ethyl-2-methylhexane ethyl-2-methylpentane ethylheptane ethylhexane ethyloctane ethylpentane ethyltoluene Derwentetal., heptene hydrophenol methylCenzaldehyde methyl-1-butene Derwentetal., methyl-T-2-pentene methylbutanal methylbutanol JenkinandHayman, methyldecane methylfuran methylheptane methylhexane Derwentetal., methylnonane methyloctane methylpentane Derwentetal., methylundecane pentanone Derwentetal.,1998 3A,4,7,7A-tetrahydro-4,7-methanoindene ,4'-methylenedianiline ,4-dimethylheptane ,5-dimethylnonane ,6-dimethylindan ,7-dimethylindan '-methylenediphenyldiisocyanate Cromophenylacetate chlorotoluene ethylmorpholine ethyl-1,2-dimethylbenzene ethyloctane ethyltoluene Derwentetal.,

105 Species POCP Method Reference Cenzo(g,h,i)perylene 0 3 Cenzo(k)fluoranthene 0 3 Cenzophenone Cenzopyrenes 0 3 benzylalcohol benzylchloride Ciphenyl Cis(2-hydroxyethyl)ether Cis(chloromethyl)ether Cis(tributyltin)oxide 0 3 Cromoethane Cromoethene Cromomethane butane Derwentetal.,1998 butanethiols 0 3 butene Cutoxyl butylacetate JenkinandHayman,1999 butylacrylate butylglycolate butyllactate butylbenzene 69 2 butylcyclohexane Cutyrolactone C10alkanes C10alkenes C10aromatichydrocarCons C10cycloalkanes C11alkanes C11alkenes C11aromatichydrocarCons C11cycloalkanes C12alkanes C12cycloalkanes C13alkanes C13+alkanes C13+aromatichydrocarCons C14alkanes C15alkanes C16alkanes C2-alkyl-anthracenes C2-alkyl-Cenzanthracenes 0 3 C2-alkyl-Cenzophenanthrenes 0 3 C2-alkyl-chrysenes 0 3 C2-alkyl-phenanthrenes C5alkenes C6alkenes C7alkanes C7alkenes Species POCP Method Reference C8alkanes C8alkenes C8cycloalkanes C9alkanes C9alkenes C9aromatichydrocarCons C9cycloalkanes camphor/fenchone carcondisulphide 0 3 carcontetrachloride 0 1 Cydefinition carconylsulphide 0 3 chlorobenzene chlorobutane chlorocyclohexane chlorodifluoromethane chloroethane chloroethylene chlorofluoromethane chlorofluoropicolines chloromethane Derwentetal.,1998 chloroprene chrysene 0 3 cis-1,3-dimethylcyclopentane cis-2-butene Derwentetal.,1998 cis-2-hexene Derwentetal.,1998 cis-2-octene cis-2-pentene Derwentetal.,1998 coronene 0 3 crotonaldehyde 70 2 cycloheptane cyclohexanamine cyclohexane 29 1 Derwentetal.,1998 cyclohexanol JenkinandHayman,1999 cyclohexanone Derwentetal.,1998 cyclooctane cyclopenta(c,d)pyrene 0 3 cyclopenta-anthracenes 0 3 cyclopenta-phenanthrenes 0 3 cyclopentane cyclopentene decalin decane Derwentetal.,1998 diacetoneketogulonicacid 0 3 diaminotoluene diazinon dicenzanthracenes 0 3 dicenzo(a,h)anthracene 0 3 dicenzophenanthrenes 0 3 dicenzopyrenes

106 Species POCP Method Reference dichlorodifluoromethane 0 1 Cydefinition dichlorofluoromethane dichloromethane Derwentetal.,1998 dichlorvos diethyldisulphide 0 3 diethylether JenkinandHayman,1999 diethylsulphate 0 3 diethylamine diethylbenzene difluoromethane dihydroxyacetone diisopropylether JenkinandHayman,1999 diisopropylbenzene dimethoxymethane JenkinandHayman,1999 dimethyldisulphide 0 3 dimethylesters dimethylether JenkinandHayman,1999 dimethylfurans dimethylsulphate 0 3 dimethylsulphide 0 3 dimethylamine dimethylbutene dimethylcyclohexane dimethylcyclopentane dimethylformamide dimethylhexene dimethylnonane dimethylpentane dipentene dipropylether dodecane Derwentetal.,1998 ethane Derwentetal.,1998 ethanethiol 0 3 ethanol JenkinandHayman,1999 ethofumesate ethylacetate JenkinandHayman,1999 ethylacrylate ethylbutanoate ethylchloroformate ethylhexanol ethyllactate ethylpentanoate ethylpropionate ethylamine ethylbenzene 73 1 Derwentetal.,1998 ethylcyclohexane ethylcyclopentane ethyldimethylbenzene ethylene Derwentetal.,1998 Species POCP Method Reference ethyleneoxide ethylisopropylbenzene fenitrothion fluoranthene 0 3 fluorene formaldehyde Derwentetal.,1998 formanilide 0 3 formicacid Derwentetal.,1998 fumaricacid glycerol glyoxal 58 2 heptadecane heptane Derwentetal.,1998 hexachlorocyclohexane hexachloroethane 0 1 Cydefinition hexadecane 26 2 hexafluoropropene hexamethylcyclotrisiloxane 0 3 hexamethyldisilane 0 3 hexamethyldisiloxane 0 3 hexamethylenediamine hexane Derwentetal.,1998 hexylcyclohexane indan indene indeno(1,2,3-c,d)pyrene 0 3 iodomethane isobutylbenzene isobutylcyclohexane isopentylbenzene isophorone isoprene Derwentetal.,1998 isoprene+cvoc 90 3 isopropanolamine isopropylbenzene 50 1 Derwentetal.,1998 isopropylcyclohexane 38 2 isopropylcyclopentane limonene m-cresol 68 2 m-xylene Derwentetal.,1998 malathion maleicanhydride menthene methacrylicacid methanethiol 0 3 methanol 14 1 JenkinandHayman,1999 methoxy-2-propoxy-2-propanol methylacetate JenkinandHayman,1999 methylacrylate

107 Species POCP Method Reference methylethylether methylformate JenkinandHayman,1999 methylfurans methylglyoxal 72 2 methylmethacrylate methylnaphthalenes methylpentanoate methylstyrene methyl-anthracenes 0 3 methyl-cenzanthracenes 0 3 methyl-cenzphenanthrenes 0 3 methyl-chrysenes 0 3 methyl-fluoranthenes 0 3 methyl-phenanthrenes methylamine 0 3 methylcyclodecane methylcycloheptane 47 2 methylcyclohexane 51 2 methylcyclopentane methylethylbenzene methylhexane methylindane 80 2 methylpropene Derwentetal.,1998 methylpropylbenzene methyltetralin monohydricphenols N,N-diethylCenzenamine N,N-dimethylCenzenamine N-(hydroxymethyl)acrylamide N-methylpyrrolidone naphthalene naphthol NedocromilSodium 0 3 nitrobenzene 0 3 nitromethane 0 3 nitropentane nitropropane 0 3 nonane Derwentetal.,1998 o-cresol o-xylene Derwentetal.,1998 octahydroindan octamethylcyclotetrasiloxane 0 3 octane Derwentetal.,1998 octylamine p-cenzoquinone p-cresol p-xylene Derwentetal.,1998 palmiticacid pentadecane Species POCP Method Reference pentane Derwentetal.,1998 pentanethiols 0 3 pentylbenzene pentylcyclohexane permethrin perylene 0 3 phenanthrene phenol phenoxyaceticacid(phenoxyacid) phenylaceticacid phenylacetonitrile phenylnaphthalenes phorate 0 3 phthalicanhydride pineoil polyethyleneglycol 0 3 polyisobutene 0 3 polyvinylchloride 0 3 potassiumphenylacetate propadiene propane Derwentetal.,1998 propanetriol propanoicacid 15 1 Derwentetal.,1998 propionitrile 0 3 propylacetate JenkinandHayman,1999 propylbutanoate propylpropionate propylamine propylbenzene Derwentetal.,1998 propylcyclohexane propylcyclopentane propylene Derwentetal.,1998 propyleneoxide propyne pyrene 0 3 pyridine salicylicacid sec-butylbenzene sec-butylcyclohexane simazine 0 3 sodium2-ethylhexanoate sodiumacetate 0 3 sodiumphenylacetate styrene Derwentetal.,1998 styreneacrylate 0 3 sulphanilamide 0 3 terpenes tert-butylamine tert-butylbenzene

108 Species POCP Method Reference tert-butylcyclopropane tert-pentylbenzene tetrachloroethene Derwentetal.,1998 tetradecane tetrafluoroethene tetrahydrofuran 57 2 tetrahydrofurylalcohol tetramethylcyclohexane toluene Derwentetal.,1998 toluene-2,3-diamine toluene-2,4-diamine toluene-2,4-diisocyanate toluene-2,5-diamine toluene-2,6-diamine toluene-2,6-diisocyanate toluene-3,4-diamine toluene-3,5-diamine trans-2-butene Derwentetal.,1998 trans-2-hexene Derwentetal.,1998 trans-2-pentene Derwentetal.,1998 trans-3-hexene tri-n-butylphosphate 0 3 trialkylphosphate 0 3 trichloroethene Derwentetal.,1998 trichlorofluoromethane 0 1 Cydefinition trichloromethane Derwentetal.,1998 tridecane triethanolamine triethylamine trifluoroethene trifluoromethane 0 3 trifluralin trimethylamine trimethylfluorosilane 0 3 undecane Derwentetal.,1998 unspeciated unspeciatedalcohols unspeciatedaliphatichydrocarcons unspeciatedalkanes unspeciatedalkenes unspeciatedamines unspeciatedaromatichydrocarcons unspeciatedcarcoxylicacids unspeciatedcycloalkanes unspeciatedhydrocarcons unspeciatedketones 42 3 urea 0 3 vinylacetate