년도 발간등록번호 ( 국립환경과학원 ( 뒷면아래 )

2 0 1 2 년도 발간등록번호 ( 국립환경과학원 http://www.nier.go.kr ( 뒷면아래 )

목차 ⅰ 요약문 ⅻ i ii

iii iv

v vi

vii viii

< 부록 A1 : On-Road mobile source> 161 < 부록 A2 : Oil Station source> 162 < 부록 A3 : Petroleum transport and storage> 165 < 부록 A4 : Municipal waste incineration> 167 < 부록 A5 : Municipal waste landfill source> 169 < 부록 A6 : Surface coating Operations-Solvent-Case Paint> 170 < 부록 A7 : Coil coating> 171 < 부록 A8 : Automobile refinishing coating source> 172 < 부록 A9 : Degreasing composite> 175 < 부록 A10 : Asphaltic concrete-in place Road Asphalt> 176 < 부록 A11 : Printing> 177 < 부록 A12 : Consumer and commercial solvent use> 178 ix x

xi xii

xiii xiv

xv xvi

xvii 1

2 3

4 5

1. 연구목표 2.1 국내외배출량산정방법분석을통한배출량신뢰도향상 6 7

2.2 VOCs 배출원에대한외국정책사례조사및저감방안검토 8 9

2.3 오존관리를위해개선이필요한 VOCs 배출원분류및 VOCs 관리정책에대한향후연구계획 ( 로드맵 ) 검토 1. 국내 VOCs 배출량 1.1 인위적배출원 10 11

1.1.1 에너지산업연소 12 13

1.1.2 비산업연소 14 15

1.1.3 제조업연소 16 17

1.1.4 생산공정 18 19

1.1.5 에너지수송및저장 1.1.6 유기용제사용 20 21

1.1.7 도로이동오염원 22 23

1.1.8 비도로이동오염원 1.1.9 폐기물처리 1.1.10 기타면오염원 24 25

2. 미국 VOCs 배출량 2.1 인위적배출원 1.2 자연배출원 26 27

2.1.1 연료연소 2.1.2 산업공정 28 29

2.1.3 도로이동오염원 2.1.5 유기용제 2.1.4 비도로이동오염원 30 31

2.1.6 화재 2.1.8 원유시설 주유소 2.1.9 기타비산업 2.1.7 농업 32 33

2.1.10 폐기물처리 3. 유럽의 VOCs 배출량 3.1 인위적배출원 2.2 자연배출원 3.1.1 연료연소 34 35

3.1.2 비도로이동오염원 3.1.3 도로이동오염원 36 37

3.1.4 연료에의한비산배출 3.1.5 산업공정 1) 광물공정 2) 화학물질공정 38 39

3) 금속공정 4) 기타생산공정 3.1.6 유기용제사용 1) 도료사용 40 41

2) 세정및세탁 4) 기타유기용제사용 3.1.7 농업 3) 화학제품 1) 분뇨관리 42 43

2) 농업토양 3) 노천소각 4) 기타 3.1.8 폐기물 1) 매립 44 45

2) 폐수처리 4) 기타폐기물 3) 폐기물소각 3.1.9 기타면오염원 3.2 자연배출원 46 47

4. 국내배출량신뢰도평가 4.1.2 생산공정 4.1 인구백만명당배출량비교 4.1.1 연료연소 4.1.3 에너지수송및저장 48 49

4.1.4 유기용제사용 4.1.6 비도로이동오염원 4.1.5 도로이동오염원 4.1.7 폐기물처리 50 51

4.2 국내 VOCs 배출원의 DARS 평가 4.2.1 DARS(Data Attribute Rating System) 평가 4.1.8 기타면오염원 e a e a e a e a e a e a e a e a 52 53

4.2.2 국내배출원의 DARS 평가결과 54 55

1. 국내배출량산정방법검토 56 57

1.1 에너지산업연소 58 59

1.2 비산업연소 60 61

1.3 제조업연소 62 63

1.4.1 석유산업공정 1.4.2 제품생산 (1) 제철제강공정 1.4 생산공정 64 65

(3) 유기화학제품제조업 (2) 무기화학제품제조업 66 67

68 69

70 71

3) 기타제조업 (1) 목재및펄프제조업 (2) 기타제조업 1.5 에너지수송및저장 4) 식음료가공 72 73

1.6 유기용제사용 1.6.1 도장시설 1.6.2 세정시설 74 75

1.6.3 세탁시설 1.6.4 기타유기용제사용 1) 인쇄시설 2) 가정및산업용유기용제사용 3) 아스팔트도로포장 76 77

1.7 도로이동오염원 78 79

1.8 비도로이동오염원 1.8.2 건설장비 1.8.1 농업기계 80 81

1.8.3 철도 82 83

1.8.4 항공 1.8.5 선박 84 85

1.9 폐기물처리 2. 배출량신뢰도향상을위한배출량산정방법개선방향 2.1 연료연소 2.1.1 배출원목록비교 1.10 기타면오염원 86 87

2.1.2 배출량산정방법비교 88 89

90 91

2.2 생산공정 92 93

2.2.1 배출원목록비교 94 95

2.2.2 배출량산정방법비교 2) 유기화학제품제조업 1) 석유산업공정 96 97

98 99

2.3 에너지수송및저장 2.3.2 배출량산정방법비교 2.3.1 배출원목록비교 100 101

2.4 유기용제사용 2.4.2 배출량산정방법비교 2.4.1 배출원목록비교 1) 도장시설 102 103

104 2) 세정및세탁 105

3) 기타유기용제사용 106 107

108 2.5 폐기물처리 2.5.1 배출원목록비교 109

2.5.2 배출량산정방법비교 2.6 기타면오염원 2.6.1 배출원목록비교 110 111

2.6.2 배출량산정방법비교 2.7 농업 112 113

2.8 배출량산정방법개선방향 114 115

1. 국내 VOC 저감대책 1.1 국내의 VOCs 정의 116 117

1.2 국내의 VOCs 저감대책 1.2.1 사업장부문 1.2.2 면오염원부문 1.2.3 도로이동오염원부문 1.2.4 비도로이동오염원부문 118 119

2. 국외 VOCs 저감대책 2.1 미국의 VOCs 관리현황 120 121

2.2 유럽의 VOCs 관리현황 122 123

2.3 일본의 VOCs 관리현황 124 125

126 127

128 129

1. 국외 POCP 를고려한오존생성기여도 1.2 영국 1.1 미국 130 131

2. 국내 POCP 를고려한오존생성기여도 132 133

3. 수도권의배출원별배출량기여도및 POCP 기여도 3.1 서울시 134 135

3.1.1 도로이동오염원 3.1.2 유기용제사용 136 137

3.2 인천시 3.2.1 도로이동오염원 3.2.2 유기용제사용 138 139

3.3.1 도로이동오염원 3.3 경기도 140 141

3.3.2 유기용제사용 4. 대기중오존농도관리를위한 VOCs 관리방향 142 143

Ⅴ. VOCs 배출량산정개선을위한연구방향및로드맵 1.1 인벤토리업데이트필요성 1. VOCs 인벤토리업데이트주기제안 1.2 업데이트주기제안 144 145

2. 향후연구계획로드맵 2.1 VOCs 배출량산정방법개선연구 (1) 석유제품산업의석유정제공정별배출계수개발연구 1) 개요 2) 추진계획 146 147

(2) 에너지수송및저장부문의배출계수개발연구 (3) 도장시설별배출계수개발을통한배출량신뢰도향상연구 1) 개요 1) 개요 2) 추진계획 2) 추진계획 148 149

(4) 세정시설의부문의배출계수개선연구 (5) 아스팔트도로포장부문의배출계수개선연구 1) 개요 1) 개요 2) 추진계획 2) 추진계획 150 151

(6) 폐기물처리부문의배출계수개선연구 (7) 산림에서의 VOCs 배출계수및자연배출원배출량산정방법개발연구 1) 개요 1) 개요 2) 추진계획 2) 추진계획 152 153

(8) 누락 VOC 배출원및배출계수개발연구 (9) 농업부문의배출계수및배출량산정방법개발연구 1) 개요 1) 개요 2) 추진계획 2) 추진계획 154 155

2.2 POCP 를고려한 VOCs 배출관리방안연구 1) 개요 2) 추진계획 156 2.3 VOCs 관리로드맵 로드맵과제 1단계 2단계 3단계 석유제품산업의석유정제공정별배출계수개발 연구 에너지수송및저장부문의배출계수개발연구 배출계수및 배출목록 개선연구 도장시설별배출계수개발을통한배출량신뢰도향상연구세정시설의부문의배출계수개선연구아스팔트도로포장부문의배출계수개선연구 폐기물처리부문의배출계수개선연구산림에서의 VOCs 배출계수개발및자연배출원배출량산정방안연구누락 VOCs 배출원및배출계수개발연구 VOCs 배출량산정방법개선연구 POCP 를고려한 VOCs 배출원관리방안연구 157

158 159

< 부록 A1 : On-Road mobile source> no. chemical compound Mass fraction(%) Molar mass(g/mole) 1 n-butane 0.1293 58.1222 2 toluene 0.075 92.13842 3 m-xylene and p-xylene 0.0698 106.165 4 1,2,4-trimethylbenzene 0.0614 120.19158 5 ethylene 0.0589 28.05316 6 2-methylpropane; isobutane 0.0579 58.1222 7 1-butene 0.038 56.10632 8 2-methyl-butane 0.0365 70.1329 9 benzene 0.0344 78.11184 10 3-methylpentane 0.0335 86.17536 11 n-pentane 0.0299 72.14878 12 2-methylpentane 0.0296 86.17536 13 propylene 0.0255 42.07974 14 2,3-dimethylbutane 0.0253 86.17536 15 2-methylhexane 0.0228 100.20194 16 n-hexane 0.0205 86.17536 17 acetylene 0.0196 26.03728 18 2,3-dimethylpentane 0.0187 100.20194 19 trans-2-butene 0.0184 56.10632 20 o-xylene 0.0182 106.165 21 n-heptane 0.0152 100.20194 22 methylcyclopentane 0.0132 126.23922 23 ethylbenzene 0.0129 106.165 24 cis-2-pentene 0.0117 70.1329 25 1,3,5-trimethylbenzene 0.0109 120.19158 26 trans-2-pentene 0.0089 70.1329 27 cis-2-butene 0.0088 56.10632 28 ethane 0.0082 30.06904 29 3-methylheptane 0.0081 114.22852 30 3-methylhexane 0.0076 100.20194 31 propane 0.0069 44.09562 32 2-methyl-2-butene 0.0064 70.1329 33 1-pentene 0.006 70.1329 34 2,2,4-trimethylpentane 0.0058 114.22852 35 methylcyclohexane 0.0055 98 36 n-nonane 0.0052 128.2551 37 2,3,4-trimethylpentane 0.0046 114.22852 38 2-methylheptane 0.0046 114.22852 39 n-octane 0.0046 114.22852 40 2,4-dimethylpentane 0.0046 100.20194 41 2,2-dimethylbutane 0.0044 86.17536 42 cyclopentane 0.0043 70.1329 43 styrene 0.0037 104.14912 44 cyclohexane 0.0026 84.15948 45 isoprene 0.0024 68.11702 160 161

< 부록 A2 : Oil Station source> no. chemical compound Mass fraction(%) Molar mass(g/mole) 1 2,3-dimethylbutane 0.0918 86.17536 2 3-methylpentane 0.0723 86.17536 3 n-heptane 0.0589 100.20194 4 n-hexane 0.0562 86.17536 5 methylcyclohexane 0.0556 98 6 3-methylhexane 0.0479 100.20194 7 n-pentane 0.0459 72.14878 8 2-methylhexane 0.0451 100.20194 9 2-methyl-butane 0.0333 70.1329 10 toluene 0.0328 92.13842 11 m,p-ethyltoluene 0.0298 120.19158 12 propane 0.0262 44.09562 13 1,2,4-trimethylbenzene 0.026 120.19158 14 trans-2-pentene 0.0235 70.1329 15 2,3-dimethylpentane 0.0227 100.20194 16 n-octane 0.0227 114.22852 17 1-hexene 0.0201 84.15948 18 2,4-dimethylpentane 0.0197 100.20194 19 2,2,4-trimethylpentane 0.0168 114.22852 20 2-methylheptane 0.0164 114.22852 21 m-xylene and p-xylene 0.0158 106.165 22 3-methylheptane 0.0154 114.22852 23 Benzene 0.0145 78.11184 24 1-butene 0.0142 56.10632 25 n-nonane 0.0141 128.2551 26 1,3,5-trimethylbenzene 0.0138 120.19158 27 n-decane 0.0126 142.28168 28 cis-2-pentene 0.0123 70.1329 29 1-pentene 0.0112 70.1329 30 o-xylene 0.009 106.165 31 o-ethyltoluene 0.0089 120.19158 32 1,2,3-trimethylbenzene 0.0081 120.19158 33 methylcyclopentane 0.008 126.23922 34 ethylbenzene 0.0075 106.165 35 2,3,4-trimethylpentane 0.0073 114.22852 < 부록 A2 : Oil Station source> no. chemical compound Mass fraction(%) Molar mass(g/mole) 36 trans-2-butene 0.0073 56.10632 37 n-undecane 0.0072 156.30826 38 2,2-dimethylbutane 0.0064 86.17536 39 n-butane 0.0059 58.1222 40 isoprene 0.0057 68.11702 41 n-propylbenzene 0.0053 120.19158 42 cis-2-butene 0.0044 56.10632 43 n-dodecane 0.0039 170.33484 44 1,4-diethylbenzene(para) 0.0036 134.21816 45 2-methylpentane 0.0034 86.17536 46 cumene(isopropylbenzene) 0.0032 120.19158 47 1,3-diethylbenzene(meta) 0.0017 134.21816 48 cyclohexane 0.0016 84.15948 49 (1-methylpropyl)benzene(sec-butyl benzene) 0.0007 134.21816 50 n-butylbenzene 0.0007 134.21816 51 trichloroethylene(tce) 0.0007 131.38834 52 napthalene 0.0007 128 53 1-methyl-4-isopropylbenzene 0.0005 134.21816 54 styrene 0.0004 104.14912 55 2-methylpropane; isobutane 0.0003 58.1222 56 1,3-butadiene 0.00005 54.09044 162 163

< 부록 A3 : Petroleum transport and storage> no. chemical compound Mass fraction(%) Molar mass(g/mole) 1 2,3-dimethylbutane 0.1052 86.17536 2 2-methyl-butane 0.1051 70.1329 3 n-pentane 0.0919 72.14878 4 3-methylpentane 0.0902 86.17536 5 n-hexane 0.0641 86.17536 6 trans-2-pentene 0.0548 70.1329 7 3-methylhexane 0.0436 100.20194 8 2-methylhexane 0.0406 100.20194 9 1-butene 0.0331 56.10632 10 cis-2-pentene 0.0308 70.1329 11 methylcyclopentane 0.0295 126.23922 12 1-pentene 0.0282 70.1329 13 1-hexene 0.0272 84.15948 14 n-heptane 0.0269 100.20194 15 2,3-dimethylpentane 0.0218 100.20194 16 toluene 0.0202 92.13842 17 methylcyclohexane 0.0193 98 18 2,4-dimethylpentane 0.0173 100.20194 19 benzene 0.0166 78.11184 20 2,2-dimethylbutane 0.0132 86.17536 21 n-butane 0.0124 58.1222 22 m-xylene and p-xylene 0.0118 106.165 23 isoprene 0.0113 68.11702 24 trans-2-butene 0.0096 56.10632 25 3-methylheptane 0.0074 114.22852 26 cis-2-butene 0.0073 56.10632 27 2,2,4-trimethylpentane 0.0069 114.22852 28 m,p-ethyltoluene 0.0069 120.19158 29 2-methylheptane 0.0068 114.22852 30 1,2,4-trimethylbenzene 0.0059 120.19158 31 ethylbenzene 0.005 106.165 32 o-xylene 0.0047 106.165 33 2-methylpentane 0.004 86.17536 34 n-octane 0.0035 114.22852 35 cyclohexane 0.0027 84.15948 < 부록 A3 : Petroleum transport and storage> no. chemical compound Mass fraction(%) Molar mass(g/mole) 36 1,3,5-trimethylbenzene 0.0025 120.19158 37 2,3,4-trimethylpentane 0.0023 114.22852 38 o-ethyltoluene 0.0015 120.19158 39 n-propylbenzene 0.0013 120.19158 40 1,2,3-trimethylbenzene 0.0013 120.19158 41 2-methylpropane; isobutane 0.0013 58.1222 42 n-nonane 0.0007 128.2551 43 1,4-diethylbenzene(para) 0.0005 134.21816 44 styrene 0.0005 104.14912 45 cumene(isopropylbenzene) 0.0004 120.19158 46 n-decane 0.0004 142.28168 47 propane 0.0002 44.09562 48 1,3-butadiene 0.0002 54.09044 49 propylene 0.0002 42.07974 50 n-undecane 0.0002 156.30826 51 1,3-diethylbenzene(meta) 0.0002 134.21816 52 napthalene 0.0002 128 53 n-dodecane 0.0001 170.33484 54 n-butylbenzene 0.0001 134.21816 55 (1-methylpropyl)benzene(sec-butyl benzene) 0.00004 134.21816 56 1-methyl-4-isopropylbenzene 0.00004 134.21816 164 165

< 부록 A4 : Municipal waste incineration> no. chemical compound Mass fraction(%) Molar mass(g/mole) 1 toluene 0.21 92.13842 2 n-butane 0.0818 58.1222 3 m-xylene and p-xylene 0.0751 106.165 4 propylene 0.0615 42.07974 5 m,p-ethyltoluene 0.0472 120.19158 6 n-decane 0.0395 142.28168 7 ethylbenzene 0.0345 106.165 8 2-methyl-butane 0.0321 70.1329 9 2-methylpropane; isobutane 0.0289 58.1222 10 o-xylene 0.0267 106.165 11 n-octane 0.0239 114.22852 12 n-nonane 0.0239 128.2551 13 methylcyclopentane 0.0216 126.23922 14 chloroform 0.0213 119.37764 15 2,3-dimethylbutane 0.0201 86.17536 16 1,3,5-trimethylbenzene 0.0195 120.19158 17 n-pentane 0.0185 72.14878 18 1,2,3-trimethylbenzene 0.0164 120.19158 19 cyclohexane 0.0146 84.15948 20 n-dodecane 0.0134 170.33484 21 n-heptane 0.0131 100.20194 22 1-butene 0.0129 56.10632 23 trichloroethylene(tce) 0.0117 131.38834 24 methylcyclohexane 0.0113 98 25 n-hexane 0.0113 86.17536 26 trans-2-butene 0.0106 56.10632 27 cis-2-butene 0.0094 56.10632 28 styrene 0.0087 104.14912 29 n-propylbenzene 0.0066 120.19158 30 2-methylheptane 0.0066 114.22852 31 ethylenedichloride 0.0062 98.95916 32 1,4-diethylbenzene(para) 0.006 134.21816 33 3-methylhexane 0.0058 100.20194 34 2-methylhexane 0.0053 100.20194 35 3-methylpentane 0.0052 86.17536 < 부록 A4 : Municipal waste incineration> no. chemical compound Mass fraction(%) Molar mass(g/mole) 36 carbontetrachloride 0.0048 153.8227 37 3-methylheptane 0.0042 114.22852 38 1,3-diethylbenzene(meta) 0.0039 134.21816 39 perchloroethylene 0.0035 165.8334 40 benzene 0.0031 78.11184 41 cumene(isopropylbenzene) 0.0028 120.19158 42 napthalene 0.0027 128 43 2,2,4-trimethylpentane 0.0024 114.22852 44 1-pentene 0.0018 70.1329 45 1-methyl-4-isopropylbenzene 0.0018 134.21816 46 2,3-dimethylpentane 0.0016 100.20194 47 cis-1,2-dichloroethene 0.0015 112.21264 48 1,1,1-trichloroethane 0.0014 133.40422 49 n-butylbenzene 0.0011 134.21816 50 2,4-dimethylpentane 0.0005 100.20194 51 n-undecane 0.0004 156.30826 52 (1-methylpropyl)benzene (sec-butylbenzene) 0.0004 134.21816 53 o-ethyltoluene 0.0003 120.19158 54 1,2,4-trimethylbenzene 0.0003 120.19158 55 isoprene 0.0002 68.11702 166 167

< 부록 A5 : Municipal waste landfill source> no. chemical compound Mass fraction(%) Molar mass(g/mole) 1 n-decane 0.0801 142.28168 2 n-nonane 0.0791 128.2551 3 n-dodecane 0.0774 170.33484 4 n-undecane 0.0756 156.30826 5 toluene 0.073 92.13842 6 m-xylene and p-xylene 0.0624 106.165 7 n-heptane 0.0466 100.20194 8 o-xylene 0.0377 106.165 9 1-methyl-4-isopropylbenzene 0.0352 134.21816 10 1,4-diethylbenzene(para) 0.034 134.21816 11 ethylbenzene 0.0329 106.165 12 m,p-ethyltoluene 0.0304 120.19158 13 1,2,4-trimethylbenzene 0.027 120.19158 14 1,2,3-trimethylbenzene 0.0238 120.19158 15 1,3,5-trimethylbenzene 0.0205 120.19158 16 cumene(isopropylbenzene) 0.0202 120.19158 17 benzene 0.02 78.11184 18 o-ethyltoluene 0.0197 120.19158 19 methylcyclohexane 0.0189 98 20 styrene 0.0179 104.14912 21 propane 0.0172 44.09562 22 napthalene 0.0154 128 23 n-propylbenzene 0.0148 120.19158 24 1,3-diethylBenzene(meta) 0.0139 134.21816 25 2-methylheptane 0.0109 114.22852 26 3-methylheptane 0.0102 114.22852 27 n-butylbenzene 0.0094 134.21816 28 n-octane 0.0081 114.22852 29 2-methyl-butane 0.0075 70.1329 30 (1-methylpropyl)benzene (sec-butylbenzene) 0.0074 134.21816 31 n-hexane 0.0071 86.17536 32 2,3-dimethylButane 0.0064 86.17536 33 2-methylhexane 0.0058 100.20194 34 1-Butene 0.0052 56.10632 < 부록 A5 : Municipal waste landfill source> no. chemical compound Mass fraction(%) Molar mass(g/mole) 35 n-pentane 0.0046 72.14878 36 n-butane 0.004 58.1222 37 o-dichlorobenzene 0.0029 147.00196 38 trans-2-butene 0.0027 56.10632 39 3-methylpentane 0.0025 86.17536 40 cis-1,2-dichloroethene 0.0022 112.21264 41 cis-2-butene 0.0015 56.10632 42 trans-2-pentene 0.0014 70.1329 43 methylcyclopentane 0.0013 126.23922 44 2,4-dimethylpentane 0.0009 100.20194 45 cis-2-pentene 0.0008 70.1329 46 1-hexene 0.0008 84.15948 47 isoprene 0.0007 68.11702 48 1-pentene 0.0007 70.1329 49 trichloroethylene(tce) 0.0007 131.38834 50 2,2-dimethylbutane 0.0006 86.17536 51 2,2,4-trimethylpentane 0.0001 114.22852 52 2,3-dimethylpentane 0.0001 100.20194 53 3-methylhexane 0.0001 100.20194 54 cyclohexane 0.00004 84.15948 168 169

< 부록 A6 : Surface coating Operations-Solvent-Case Paint> no. chemical compound Mass fraction(%) Molar mass(g/mole) 1 toluene 37.88 92.13842 2 n-butylacetate 9.5 116.15828 3 2,4-dimethylhexane 7.2 114.22852 4 butylcellosolve{2-cutoxyethanol} {egce} 6.48 118.17416 5 o-xylene 4.47 106.165 6 dimethylcyclohexanes 4.01 154.29238 7 2-methyl-3-hexanone 3.75 114.18546 8 isomers of xylene 3.7 106.165 9 methylcyclohexane 3.61 98 10 n-heptane 2.94 100.20194 11 isomers of nonane(c9paraffin) 2.79 128.2551 12 ethylacetate 2.04 88.10512 13 2,4-dimethylpentane 1.7 100.20194 14 trimethylcyclohexanes 1.66 126.23922 15 ethylcyclohexane 1.43 112.21264 16 acetone 1.27 58.07914 17 c5ester 1.26 102.1317 18 methylamylketone 0.83 114.18546 19 dimethylheptanes 0.67 128.2551 20 ethylbenzene 0.54 106.165 21 methylethylketone(mek) (2-butanone) 0.54 72.10572 22 cyclohexane 0.52 84.15948 23 methylisobutylketone 0.36 100.15888 24 ethylcyclopentane 0.22 98.18606 25 ethyltoluenes {methylethylbenzenes} 0.2 120.19158 26 trimethylcyclopentane 0.17 112.2144 27 methylheptene 0.15 112.21264 28 trimethylbenzenes 0.11 120.19158 < 부록 A7 : Coil coating> no. chemical compound Mass fraction(%) Molar mass(g/mole) 1 toluene 47.07 92.13842 2 m-xylene and p-xylene 29.48 106.165 3 ethylbenzene 11.48 106.165 4 o-xylene 9.55 106.165 5 Benzene 1.23 78.11184 6 styrene 0.33 104.14912 7 cumene(isopropylbenzene) 0.09 120.19158 8 n-butane 0.09 58.1222 9 n-hexane 0.09 86.17536 10 n-octane 0.08 114.22852 11 methylcyclopentane 0.07 126.23922 12 propylene 0.06 42.07974 13 1,3,5-trimethylbenzene 0.04 120.19158 14 2-methyl-Butane 0.04 70.1329 15 n-nonane 0.04 128.2551 16 1,2,4-trimethylbenzene 0.03 120.19158 17 2,3-dimethylbutane 0.03 86.17536 18 cyclohexane 0.03 84.15948 19 methylcyclohexane 0.03 98 20 n-pentane 0.03 72.14878 21 2-methylpropane; isobutane 0.02 58.1222 22 m-ethyltoluene 0.02 120.19158 23 1,2,3-trimethylbenzene 0.01 120.19158 24 2-methylhexane 0.01 100.20194 25 2-methylpentane 0.01 86.17536 26 3-methylhexane 0.01 100.20194 27 3-methylpentane 0.01 86.17536 28 p-ethyltoluene 0.01 120.19158 170 171

< 부록 A8 : Automobile refinishing coating source> no. chemical compound Mass fraction(%) Molar mass(g/mole) 1 m-xylene and p-xylene 0.3032 106.165 2 o-xylene 0.1876 106.165 3 ethyl benzene 0.1272 106.165 4 toluene 0.1137 92.13842 5 1,2,4-trimethyl Benzene 0.0364 120.19158 6 m,p-ethyltoluene 0.0305 120.19158 7 styrene 0.0265 104.14912 8 cyclohexane 0.0244 84.15948 9 methylcyclopentane 0.0132 126.23922 10 2,3-dimethylbutane 0.0115 86.17536 11 n-hexane 0.0115 86.17536 12 propane 0.0113 44.09562 13 1,3,5-trimethylbenzene 0.0102 120.19158 14 1,2,3-trimethylbenzene 0.0102 120.19158 15 3-methylpentane 0.0094 86.17536 16 o-ethyltoluene 0.0087 120.19158 17 propylene 0.007 42.07974 18 n-decane 0.0069 142.28168 19 n-propylbenzene 0.0058 120.19158 20 1-butene 0.0054 56.10632 21 1,4-diethylbenzene(para) 0.0049 134.21816 22 n-nonane 0.0047 128.2551 23 n-pentane 0.0044 72.14878 24 n-undecane 0.0038 156.30826 25 benzene 0.0038 78.11184 26 2-methyl-butane 0.0035 70.1329 27 n-dodecane 0.0021 170.33484 28 1-methyl-4-isopropylbenzene 0.0016 134.21816 29 1,3-diethylbenzene(meta) 0.0016 134.21816 30 napthalene 0.0016 128 31 cumene(isopropylbenzene) 0.0015 120.19158 32 n-octane 0.0014 114.22852 33 methylcyclohexane 0.0012 98 34 trans-2-pentene 0.0008 70.1329 35 (1-methylpropyl)benzene (sec-butylbenzene) 0.0008 134.21816 36 n-butylbenzene 0.0008 134.21816 37 2-methylheptane 0.0007 114.22852 38 cis-2-pentene 0.0004 70.1329 < 부록 A9 : Degreasing composite> no. chemical compound Mass fraction(%) Molar mass(g/mole) 1 1,1,1-trichloroethane 22.28 133.40422 2 trichloroethylene(tce) 21.09 131.38834 3 n-heptane 8.44 100.20194 4 toluene 8.29 92.13842 5 perchloroethylene 7.4 165.8334 6 dichloromethane {methylenechloride} 4.1 84.93258 7 trichlorotrifluoroethane-f113 4.1 187.3756096 8 isomers of xylene 3.4 187.3756096 9 methylcyclohexane 1.83 98 10 acetone 1.4 58.07914 11 isomersofdecane(c10paraffins) 1.33 142.28168 12 2-methylhexane 1.27 100.20194 13 methylethylketone(mek) (2-butanone) 1.1 72.10572 14 benzene 1 78.11184 15 isomersofundecane(c11paraffins) 0.93 156.30826 16 n-nonane 0.87 128.2551 17 ethylether 0.8 74.1216 18 methylnonane 0.75 142.28168 19 methyloctanes 0.73 128.2551 20 dimethylcyclopentane 0.71 98.18606 21 sec-butylalcohol 0.7 74.1216 22 ethylmethylcyclohexanes 0.69 126.23922 23 methyldecanes 0.45 156.30826 24 butylbenzeneisomers 0.41 134.21816 25 trimethylcyclopentane 0.36 112.2144 26 c10olefins 0.35 140.2658 27 dimethylhexanes 0.33 114.22852 28 c8olefins 0.31 112.21264 29 trimethylbenzenes 0.31 120.19158 172 173

< 부록 A9 : Degreasing composite> no. chemical compound Mass fraction(%) Molar mass(g/mole) 30 dimethyloctanes 0.3 142.28168 31 isomersofdodecane(c12paraffins) 0.28 170.33484 32 Isomers of propylbenzene 0.28 120.19158 33 trimethylcyclohexanes 0.24 126.23922 34 m-xylene and p-xylene 0.23 106.165 35 trimethylheptanes 0.22 142.28168 36 dimethylnonanes 0.21 156.30826 37 methylpropylcyclohexanes 0.2 140.2658 38 o-xylene 0.17 106.165 39 butylcyclohexane 0.16 140.2658 40 isomersofc9h16 0.12 124.22334 41 methylhexenes 0.12 98.18606 42 dimethylcyclohexanes 0.11 154.29238 43 cyclohexane 0.1 84.15948 44 c11olefins 0.09 154.29238 45 diethylcyclohexane 0.08 140.2658 46 ethylcyclohexane 0.08 112.21264 47 methyldecenes 0.08 154.29238 48 ethylmethyloctane 0.07 156.30826 49 tetramethylcyclopentane 0.07 126.23922 50 decalins(mixedcis,trans) 0.06 138.24992 51 dimethylcyclobutanone 0.06 98.14 52 1-methyl-2-isopropylcyclohexane 0.06 140.2658 53 ethylhexane 0.05 114.22852 54 n-pentylcyclohexane 0.05 154.29238 55 n-propylbenzene 0.05 120.19158 56 trimethyloctanes 0.05 156.30826 57 ethyloctenes 0.04 140.2658 58 n-hexane 0.04 86.17536 59 c3/c4/c5alkylbenzenes 0.03 133.3939371 60 ethylheptene 0.03 126.23922 < 부록 A9 : Degreasing composite> no. chemical compound Mass fraction(%) Molar mass(g/mole) 61 isomers of tetradecane(c14paraffins) 0.03 198.388 62 cumene(isopropylbenzene) 0.03 120.19158 63 methyldecalins 0.03 152.2765 64 methylnonenes 0.03 140.2658 65 methylpropylnonane 0.03 184.36142 66 methylundecane 0.03 170.33484 67 napthalene 0.03 128 68 Cicyclo[4.3.0]nonane (octahydroindene) 0.03 124.22334 69 c12olefins 0.02 168.31896 70 dimethylbenzylalcohol 0.02 136.19098 71 dimethylheptanes 0.02 128.2551 72 ethyloctane 0.02 142.28168 73 methyldodecanes 0.02 184.36142 74 nonadiene 0.02 124.22334 75 propenylcyclohexane 0.02 126.23922 76 isomers of tridecane(c13paraffins) 0.01 184.36142 77 tetramethylthiourea 0.01 132.22718 78 misc./othervoc 0.14 137.1921245 174 175

< 부록 A10 : Asphaltic concrete-in place Road Asphalt> no. chemical compound Mass fraction(%) Molar mass(g/mole) 1 methane 15.70% 16.04246 2 2-methylpropane; isobutane 11.20% 58.1222 3 n-butane 10.10% 58.1222 4 benzene 9.50% 78.11184 5 n-hexane 8.80% 86.17536 6 isomers of hexane 8.10% 86.17536 7 1-butene 5.90% 56.10632 8 isomers of pentane 5.70% 72.14878 9 propane 5.50% 44.09562 10 n-pentane 5.30% 72.14878 11 ethane 4.60% 30.06904 12 propylene 3.90% 42.07974 13 c7 cycloparaffins 3.70% 98.18606 14 ethylene 2.00% 28.05316 < 부록 A11 : Printing> no. chemical compound Mass fraction(%) Molar mass(g/mole) 1 toluene 0.8837 92.13842 2 n-decane 0.0269 142.28168 3 n-nonane 0.0223 128.2551 4 n-undecane 0.0107 156.30826 5 m-xylene and p-xylene 0.0067 106.165 6 1,2,4-trimethylbenzene 0.0062 120.19158 7 m,p-ethyltoluene 0.0059 120.19158 8 n-dodecane 0.005 170.33484 9 o-xylene 0.0034 106.165 10 1,2,3-trimethylbenzene 0.003 120.19158 11 propane 0.0029 44.09562 12 ethylbenzene 0.0028 106.165 13 2-methylheptane 0.0026 114.22852 14 3-methylheptane 0.0025 114.22852 15 o-ethyltoluene 0.0024 120.19158 16 1,4-diethylbenzene(para) 0.0023 134.21816 17 2,3-dimethylbutane 0.0016 86.17536 18 1,3,5-trimethylbenzene 0.0016 120.19158 19 n-propylbenzene 0.0014 120.19158 20 cyclohexane 0.0014 84.15948 21 n-octane 0.0012 114.22852 22 n-hexane 0.0008 86.17536 23 1,3-diethylbenzene(meta) 0.0007 134.21816 24 3-methylpentane 0.0006 86.17536 25 cumene(isopropylbenzene) 0.0004 120.19158 26 methylcyclopentane 0.0002 126.23922 27 1-butene 0.0002 56.10632 28 benzene 0.0002 78.11184 29 n-butylbenzene 0.0001 134.21816 30 n-pentane 0.0001 72.14878 31 (1-methylpropyl)benzene (sec-butylbenzene) 0.0001 134.21816 176 177

< 부록 A12 : Consumer and commercial solvent use> no. chemical compound Mass fraction(%) Molar mass(g/mole) 1 n-butane 23% 58.1222 2 2-methylpropane; isobutane 12% 58.1222 3 propane 10% 44.09562 4 distillates/naphtha/mineralspirits 8% 128 5 isopropyl alcohol 7% 60.09502 6 methyl alcohol 5% 32.04186 7 n-heptane 3% 100.20194 8 n-hexane 3% 86.17536 9 ethylcyanoacrylate 3% 125.12528 10 1,1,1-trichloroethane 3% 133.40422 11 methylalcohol 3% 32.04186 12 acetone 2% 58.07914 13 fragrances 2% 137.1921245 14 other,lumpedvocs, individually <2% of category 2% 137.1921245 15 volatilemethylsiloxanes(vms) 2% 296.61576 16 p-dichlorobenzene 2% 147.00196 17 toluene 1% 92.13842 18 perchloroethylene 1% 165.8334 19 vocingredients<0.1% 1% 137.1921245 20 ethanolamine 1% 61.08308 21 misc./othervoc 1% 137.1921245 22 hydrocarbonpropellant{lpg} 1% 44.14080355 23 methylethylketone(mek) (2-butanone) 1% 72.10572 24 1,1-difluoroethane(hfc-152a) 0.38% 66.0499664 25 orangeterpenes 0.25% 136.23404 26 vinylacetate 0.24% 86.08924 27 otherexemptpropellants 0.24% 187.3756096 28 2-methylpentane 0.23% 86.17536 29 d-limonene 0.22% 136.23404 30 dichloromethane {methylenechloride} 0.18% 84.93258 31 dimethylether 0.17% 46.06844 < 부록 A12 : Consumer and commercial solvent use> no. chemical compound Mass fraction(%) Molar mass(g/mole) 32 other,lumpedexempts,individually< 2% of category 0.15% 187.3756096 33 lemonoil 0.13% 137.1921245 34 ethylacetate 0.12% 88.10512 35 terpene 0.11% 136.23404 36 2,2,4,6,6-pentamethylheptane 0.11% 170 37 butane, branched&linear 0.09% 58.1222 38 orangeoil 0.09% 137.1921245 39 butylcellosolve{2-butoxyethanol} {egbe} 0.06% 118.17416 40 isomers of xylene 0.06% 106.165 41 n-butylacetate 0.05% 116.15828 42 witchhazel 0.04% 137.1921245 43 benzylalcohol 0.01% 108.13782 44 t-butylacetate 0.01% 116.15828 45 di(propyleneglycol)methylether 0.01% 148.20014 46 misc.lvpvocdistillates 0.01% 110.1142573 47 methylisobutylketone 0.01% 100.15888 48 o-dichlorobenzene 0.01% 147.00196 49 cyclohexane 0.01% 84.15948 50 ethylbenzene 0.01% 106.165 51 n-pentane 0.005% 72.14878 52 dexpanthenol 0.005% 205.25146 53 glyceryltriacetate 0.004% 218.20386 54 b-pinene 0.004% 136.23404 55 glutaraldehyde(adialdehyde) 0.004% 100.11582 56 propyleneglycolmethylether {1-methoxy-2-propanol} 0.003% 90.121 57 methylcarbitol{2-(2-methoxyethoxy) ethanol}{degme} 0.003% 120.14698 58 2-methyl-butane 0.003% 70.1329 178 179

< 부록 A12 : Consumer and commercial solvent use> no. chemical compound Mass fraction(%) Molar mass(g/mole) 59 hydrocarbonpropellant {lpg,sweetened} 0.002% 44.14080355 60 2-amino-2-methyl-1-propanol 0.002% 89.13624 61 a-pinene 0.002% 136.23404 62 trichloroethylene(tce) 0.001% 131.38834 63 styrene 0.001% 104.14912 64 carbitol{degee}{2-(2-ethoxyethoxy)e thanol} 0.001% 134.17356 65 o-chlorotoluene 0.0010% 126.58348 66 terpinene(1-isopropyl-4-methyl-1,4 -cyclohexadiene) 0.0007% 136.24 67 propylacetate 0.0007% 102.1317 68 sec-butylalcohol 0.0007% 74.1216 69 2-methylundecane{isododecane} 0.0006% 170.33484 70 1,2,4-trimethylbenzene 0.0006% 120.19158 71 1-methyl-2-pyrrolidinone 0.0006% 99.13106 72 camphor 0.0004% 152.23344 73 1-methyl-4-isopropylbenzene 0.0004% 134.21816 74 propyleneglycol-t-butylether{1-(1,1, -dimethylethoxy)-2-propanol} 0.0004% 132.20074 75 myrcene 0.0004% 136.23404 76 4,4-dimethyl-2-neopentyl -1-pentene 0.0003% 168.31896 77 methylsalicylate(anester) 0.0003% 152.14732 78 propyleneglycolbutylether {1-butoxy-2-propanol} 0.0002% 132.20074 79 cyclohexamine 0.0002% 99.17412 80 dimethylformamide 0.0002% 73.09378 81 propyleneglycoln-propylether 0.0002% 118.17416 82 diacetonealcohol(4-hydroxy-4-meth yl-2-pentanone) 0.0002% 116.15828 83 morpholine(tetrahydro-1,4-oxazin) 0.0002% 87.12036 < 부록 A12 : Consumer and commercial solvent use> no. chemical compound Mass fraction(%) Molar mass(g/mole) 84 propylene 0.002% 42.07974 85 n-propylalcohol 0.002% 60.09502 86 mineraloil 0.002% 110.1142573 87 2-(2-butoxyethoxy)ethanol {butylcarbitol} 0.001% 162.22672 88 c3-c4alkanepropellant 0.001% 44.14080355 89 cresols 0.001% 108.13782 90 triisopropanolamine 0.0010% 191.26794 91 misc.hydrocarbonpropellants 0.0007% 44.14080355 92 other,misc.voc 0.0007% 137.1921245 93 2-methoxyethanol {methylcellosolve}{egme} 0.0007% 76.09442 94 pineoil 0.0006% 142.7713899 95 2-phenoxyethanol 0.0006% 138.1638 96 isopropylacetate 0.0006% 102.1317 97 diacetonealcohol(4-hydroxy-4-meth yl-2-pentanone) 0.0004% 116.15828 98 1,3,5-trimethylbenzene 0.0004% 120.19158 99 santosoldimethylester 0.0004% 137.1921245 100 methylcyclohexane 0.0004% 98 101 methoxypropanolacetate 0.0003% 132.15768 102 benzene 0.0003% 78.11184 103 3-carene 0.0002% 136.24 104 dl-limonene{dipentene} 0.0002% 136.23404 105 polypropyleneglycol 0.0002% 152.19038 180 181

< 부록 A12 : Consumer and commercial solvent use> no. chemical compound Mass fraction(%) Molar mass(g/mole) 106 propyleneglycolmonoethylether 0.00002% 104.14758 107 tert-butylalcohol 0.00001% 74.1216 108 ethyleneglycolpropylether{2-propox yethanol} 0.00001% 104.14758 109 glycoletherdpnb{1-(2-butoxy-1-met hylethoxy)-2-propanol} 0.000009% 190.27988 110 benzenederivates 0.000007% 135.1863 111 dimethoxymethane(methylal) 0.000006% 76.09442 112 3,5-dimethyl-1-hexyne-3-ol 0.000006% 126.19616 113 cumene(isopropylbenzene) 0.000002% 120.19158 114 propyleneglycolmonomethyletherac etate{2-(1-methoxy)propylacetate} 0.0000009% 132.15768 115 formaldehyde 0.0000003% 30.02598 116 isophorone{3,5,5-trimethyl-2-cycloh exenone} 0.00000004% 138.20686 182 183

Species POCP Method Reference (1-methylethyl)cyclohexane 40.5 2 (1-methylpropyl)cyclohexane 38.5 2 (2-methyl-1-propyl)acetate 32.8 2 (2-methylbutyl)cyclohexane 39.8 2 (2-methylpropyl)cyclohexane 42.7 2 1,1,1-trichloroethane 0.9 1 Derwentetal.,1998 1,1,1-trichlorotrifluoroethane 0 1 Cydefinition 1,1,2,2-tetrachloroethane 7.7 2 1,1,2-trichloroethane 6.2 2 1,1,2-trimethylcyclohexane 41.2 2 1,1,2-trimethylcyclopentane 40.8 2 1,1,3-trimethylcyclohexane 41.2 2 1,1,4,4-tetramethylcyclohexane 34.3 2 1,1-dichloroethane 9.4 2 1,1-dichloroethene 52.6 2 1,1-dichlorotetrafluoroethane 0 1 Cydefinition 1,1-dimethylcyclohexane 42.8 2 1,1-dimethylcyclopentane 28.8 2 1,2,3,4-tetrahydronaphthalene 115.1 2 1,2,3,4-tetramethylbenzene 114.6 2 1,2,3,5-tetramethylbenzene 136 2 1,2,3,5-tetramethylcyclohexane 42.7 2 1,2,3-trichlorobenzene 2.2 2 1,2,3-trimethylbenzene 126.7 1 Derwentetal.,1998 1,2,3-trimethylcyclohexane 45.4 2 1,2,3-trimethylcyclopentane 43.6 2 1,2,4,4-tetramethylcyclopentane 37.5 2 1,2,4,5-tetramethylbenzene 114.6 2 1,2,4-trichlorobenzene 15.3 2 1,2,4-trimethlycyclopentane 43.6 2 1,2,4-trimethylbenzene 127.8 1 Derwentetal.,1998 1,2,4-trimethylcyclohexane 45.4 2 1,2,4-trimethylcyclopentane 42.8 2 1,2-diaminoethane 51.3 3 1,2-diCromoethane 3.3 2 1,2-dichlorobenzene 12 2 1,2-dichloroethane 7 2 1,2-dichloroethene 42 1 Derwentetal.,1998 1,2-dichlorotetrafluoroethane 0 1 Cydefinition 1,2-dimethyl-3-isopropylcyclopentane 39.3 2 1,2-dimethylcyclohexane 48.2 2 1,2-dimethylcyclopentane 45.9 2 1,2-ethanedioldiacetate 16 2 1,2-ethylmethylcyclopentane 44.2 2 1,2-propanediol 44.6 1 JenkinandHayman,1999 1,3,4,5,6-pentahydroxy-2-hexanone 0 3 1,3,5-trichlorobenzene 17.3 2 1,3,5-trimethylbenzene 138.1 1 Derwentetal.,1998 1,3,5-trimethylcyclohexane 45.4 2 Species POCP Method Reference 1,3-Cutadiene 85.1 1 Derwentetal.,1998 1,3-dichlorobenzene 14.7 2 1,3-diethylbenzene 104.1 2 1,3-dimethyl-4-ethylbenzene 114.6 2 1,3-dimethyl-5-propylbenzene 132.5 2 1,3-dimethylcyclohexane 48.2 2 1,3-dimethylcyclopentane 45.9 2 1,3-dioxolane 50.9 2 1,3-ethylmethylcyclopentane 44.2 2 1,3-hexadiene 103.7 2 1,4-Cutyrolacetone 35.6 2 1,4-dichlorobenzene 5 2 1,4-diethylbenzene 89.6 2 1,4-dimethyl-2-isopropylbenzene 111.7 2 1,4-dimethylcyclohexane 48.2 2 1,4-dimethylpiperazine 51.3 3 1,4-dioxane 38.4 2 1-(2-Cutoxy-1-methyl-ethoxy)-2-propanol 41.3 2 1-(2-ethoxy-1-methyl-ethoxy)-2-propanol 56.4 2 1-(2-methoxy-1-methyl-ethoxy)-2-propanol 53.5 2 1-(Cutoxyethoxy)-2-propanol 55.5 2 1-butanal 79.5 1 Derwentetal.,1998 1-butanol 62 1 JenkinandHayman,1999 1-butene 107.9 1 Derwentetal.,1998 1-Cutoxy-2-propanol 46.3 1 JenkinandHayman,1999 1-Cutyne 73.2 2 1-chloro-2,3-epoxypropane 10.2 2 1-chloro-4-nitrobenzene 0 3 1-chloropropane 15.3 2 1-decene 91.7 2 1-ethoxy-2-propanol 49.7 2 1-ethoxy-2-propylacetate 35.2 2 1-ethyl-1,4-dimethylcyclohexane 38.7 2 1-ethyl-2,2,6-trimethylcyclohexane 37.2 2 1-ethyl-2,3-dimethylbenzene 114.6 2 1-ethyl-2,3-dimethylcyclohexane 42.3 2 1-ethyl-2-methylcyclopentane 36.5 2 1-ethyl-2-propylbenzene 86.2 2 1-ethyl-2-propylcyclohexane 40 2 1-ethyl-3,5-dimethylbenzene 136 2 1-ethyl-3-methylcyclohexane 45.6 2 1-ethyl-3-methylcyclopentane 36.5 2 1-ethyl-4-methylcyclohexane 45.6 2 1-ethylpropylbenzene 105.7 3 1-heptene 83.1 2 1-hexanal 100 2 1-hexene 87.4 1 Derwentetal.,1998 1-hydrophenol 78.2 2 1-methoxy-2-butanol 47.6 2 184 185

Species POCP Method Reference 1-methoxy-2-propanol 35.5 1 JenkinandHayman,1999 1-methoxy-2-propylacetate 32.3 2 1-methyl-1-phenylcyclopropane 63.7 3 1-methyl-1-propylbenzene 73.5 3 1-methyl-1-propylcyclohexane 38.5 2 1-methyl-1-propylcyclopentane 37.9 2 1-methyl-2-isopropylbenzene 88.4 2 1-methyl-2-propylbenzene 88.4 2 1-methyl-3-(isopropyl)benzene 104.1 2 1-methyl-3-isopropylcyclopentane 39.1 2 1-methyl-3-propylbenzene 104.1 2 1-methyl-4-isopropylbenzene 89.6 2 1-methyl-4-isopropylcyclohexane 43 2 1-methyl-4-tertbutylbenzene 87.3 2 1-methylbutylbenzene 105.7 3 1-methylcyclohexene 100.4 2 1-methylindan 80 2 1-methylindene 136.2 3 1-nonene 95.6 2 1-octene 78.2 2 1-pentanal 76.5 1 Derwentetal.,1998 1-pentanol 59.5 2 1-pentene 97.7 1 Derwentetal.,1998 1-propanal 79.8 1 Derwentetal.,1998 1-propanol 56.1 1 JenkinandHayman,1999 11-methyl-1-dodecanol 31 2 2,2'-iminodi(ethylamine) 51.3 3 2,2'-iminodiethanol 51.3 3 2,2,3,3-tetramethylbutane 12.9 2 2,2,3,3-tetramethylhexane 19.2 2 2,2,3-trimethylbutane 38.6 2 2,2,3-trimethylpentane 39.1 2 2,2,4,6,6-pentamethylheptane 21.4 2 2,2,4-trimethyl-1,3-pentanediol 27.5 3 monoisocutyrate 2,2,4-trimethylpentane 24.7 2 2,2,5-trimethylhexane 37.6 2 2,2-dimethylbutane 24.1 1 Derwentetal.,1998 2,2-dimethylhexane 38.6 2 2,2-dimethylpentane 38.6 2 2,2-dimethylpropane 17.3 1 Derwentetal.,1998 2,3,3,4-tetramethylpentane 37.2 2 2,3,3-trimethyl-1-butene 81.3 2 2,3,3-trimethylpentane 38 2 2,3,4-trimethylhexane 42.9 2 2,3,4-trimethylpentane 25.7 2 2,3,5-trimethylhexane 42.6 2 2,3-dimethylbutane 54.1 1 Derwentetal.,1998 2,3-dimethylfuran 62.8 2 Species POCP Method Reference 2,3-dimethylhexane 46.5 2 2,3-dimethylnonane 37.7 2 2,3-dimethyloctane 40.2 2 2,3-dimethylpentane 39.1 2 2,3-dimethylundecane 31.7 2 2,4,4-trimethyl-1-pentene 81.1 2 2,4,6-trichloro-1,3,5-triazine 51.3 3 2,4-difluoroaniline 0 3 2,4-dimethyl-1-(1-methylethyl)benzene 111.7 2 2,4-dimethyl-1-isopropylbenzene 111.7 2 2,4-dimethylfuran 62.8 2 2,4-dimethylheptane 42.6 2 2,4-dimethylhexane 46.5 2 2,4-dimethylpentane 46.6 2 2,4-toluenediisocyanate 51.3 3 2,5-dimethyldecane 34.6 2 2,5-dimethylfuran 62.8 2 2,5-dimethylheptane 51.2 2 2,5-dimethylhexane 44.6 2 2,5-dimethyloctane 40.2 2 2,6-dimethyldecane 35.1 2 2,6-dimethylheptane 42.3 2 2,6-dimethyloctane 40.2 2 2,6-dimethylundecane 31.7 2 2,6-toluenediisocyanate 51.3 3 2,7-dimethyloctane 39.9 2 2-(2-aminoethylamino)ethanol 51.3 3 2-(2-Cutoxyethoxy)ethanol 50.2 2 2-(2-Cutoxyethoxy)ethylacetate 40 2 2-(2-ethoxyethoxy)ethanol 49.3 2 2-(2-ethoxyethoxy)ethylacetate 34.6 2 2-(2-hydroxy-ethoxy)ethanol 40.1 2 2-(2-hydroxy-propoxy)-1-propanol 55.4 2 2-(methoxyethoxy)ethanol 42.8 2 2-[2-(2-ethoxy-ethoxy)-ethoxy]ethanol 35.7 2 2-acetoxy-propylacetate 14.3 2 2-aminoethanol 51.3 3 2-butanol 44.7 1 JenkinandHayman,1999 2-butanone 37.3 1 Derwentetal.,1998 2-butanoneoxime 51.3 3 2-butene 113.9 1 Derwentetal.,1998 2-Cutoxyethanol 48.3 1 JenkinandHayman,1999 2-Cutoxyethylacetate 35.1 2 2-chloroethanol 30.3 2 2-chloropropane 14.5 2 2-chlorotoluene 13.1 2 2-ethoxyethanol 38.6 1 JenkinandHayman,1999 2-ethoxyethylacetate 34.6 2 2-ethoxypropanol 65.7 2 186 187

Species POCP Method Reference 2-ethyl-1,3-dimethylbenzene 114.6 2 2-ethyltoluene 89.8 1 Derwentetal.,1998 2-hexoxyethanol 44.7 2 2-hydrophenol 78.2 2 2-isopropoxyethanol 51.4 2 2-methoxy-2-methylpropane 17.5 1 JenkinandHayman,1999 2-methoxyethanol 30.7 1 JenkinandHayman,1999 2-methoxyethylacetate 40.5 2 2-methoxypropane 39.4 2 2-methylCenzaldehyde -9.2 3 2-methyl-1,3-dioxolane 46.2 2 Species POCP Method Reference 2-methyl-1-butene 77.1 1 Derwentetal.,1998 2-methyl-1-butylbenzene 86.2 2 2-methyl-1-pentene 107.2 2 2-methyl-1-propanol 36 1 JenkinandHayman,1999 2-methyl-2,4-pentanediol 46.4 2 2-methyl-2-butene 84.2 1 Derwentetal.,1998 2-methyl-2-hexene 81.3 2 2-methyl-2-pentene 79.9 2 2-methyl-2-propanol 10.6 1 JenkinandHayman,1999 2-methyl-5-ethyloctane 38 2 2-methylbutanal 86 2 2-methylbutane 40.5 1 Derwentetal.,1998 2-methyldecalin 41.4 2 2-methyldecane 37.5 2 2-methylfuran 59.6 2 2-methylheptane 44.6 2 2-methylhexane 41.1 1 Derwentetal.,1998 2-methylnonane 39.9 2 2-methyloctane 42.8 2 2-methylpentane 42 1 Derwentetal.,1998 2-methylpropanal 51.4 1 Derwentetal.,1998 2-methylpropane 30.7 1 Derwentetal.,1998 2-methylpropenal 82.9 2 2-methylpropene 62.7 1 Derwentetal.,1998 2-methylpropylacetate 21.3 2 2-methylpyridine 51.3 3 2-methylundecane 35.2 2 2-pentanone 54.8 1 Derwentetal.,1998 2-pentene 111.9 1 Derwentetal.,1998 2-phenoxyethanol 43.9 2 2-phenylpropene 14.2 3 2-propanol 18.8 1 JenkinandHayman,1999 2-propen-1-ol 74.6 2 2-propylacetate 21.1 1 JenkinandHayman,1999 3,3,4-trimethylhexane 37.6 2 3,3,5-trimethylheptane 36.2 2 3,3-dimethylheptane 37.2 2 Species POCP Method Reference 3,3-dimethyloctane 35.8 2 3,3-dimethylpentane 37.8 2 3,4-dimethylheptane 42.6 2 3,4-dimethylhexane 45.3 2 3,5,5-trimethylhexane 32.1 2 3,5-dimethyloctane 40.5 2 3,6-dimethyloctane 40.5 2 3,7-dimethylnonane 37.9 2 3-(2-hydroxy-propoxy)-1-propanol 56.4 2 3-chloro-4-fluoropicoline 51.3 3 3-chloropropene 46 2 3-chloropyridine 51.3 3 3-ethyl-2-methylheptane 39.9 2 3-ethyl-2-methylhexane 43.1 2 3-ethyl-2-methylpentane 46.1 2 3-ethylheptane 43.1 2 3-ethylhexane 41.5 2 3-ethyloctane 44.4 2 3-ethylpentane 47.7 2 3-ethyltoluene 101.9 1 Derwentetal.,1998 3-heptene 103.3 2 3-hydrophenol 78.2 2 3-methylCenzaldehyde -9.2 3 3-methyl-1-butene 67.1 1 Derwentetal.,1998 3-methyl-T-2-pentene 107.2 2 3-methylbutanal 78.6 2 3-methylbutanol 43.3 1 JenkinandHayman,1999 3-methyldecane 37.7 2 3-methylfuran 59.6 2 3-methylheptane 45 2 3-methylhexane 36.4 1 Derwentetal.,1998 3-methylnonane 40.2 2 3-methyloctane 42.6 2 3-methylpentane 47.9 1 Derwentetal.,1998 3-methylundecane 35.1 2 3-pentanone 41.4 1 Derwentetal.,1998 3A,4,7,7A-tetrahydro-4,7-methanoindene 72 3 4,4'-methylenedianiline 51.3 3 4,4-dimethylheptane 37.2 2 4,5-dimethylnonane 37.9 2 4,6-dimethylindan 132.5 3 4,7-dimethylindan 132.5 3 4-4'-methylenediphenyldiisocyanate 51.3 3 4-Cromophenylacetate 51.3 3 4-chlorotoluene 13.1 2 4-ethylmorpholine 51.3 3 4-ethyl-1,2-dimethylbenzene 114.6 2 4-ethyloctane 44.4 2 4-ethyltoluene 90.6 1 Derwentetal.,1998 188 189

Species POCP Method Reference Cenzo(g,h,i)perylene 0 3 Cenzo(k)fluoranthene 0 3 Cenzophenone 51.3 3 Cenzopyrenes 0 3 benzylalcohol 46.9 2 benzylchloride 17.7 2 Ciphenyl 66.6 2 Cis(2-hydroxyethyl)ether 40.2 2 Cis(chloromethyl)ether 29.2 2 Cis(tributyltin)oxide 0 3 Cromoethane 1.3 2 Cromoethene 12.2 2 Cromomethane 0.6 2 butane 35.2 1 Derwentetal.,1998 butanethiols 0 3 butene 99.6 3 Cutoxyl 51.3 3 butylacetate 26.9 1 JenkinandHayman,1999 butylacrylate 47.9 2 butylglycolate 26.8 2 butyllactate 29.1 2 butylbenzene 69 2 butylcyclohexane 42.5 2 Cutyrolactone 51.3 3 C10alkanes 38.7 3 C10alkenes 87.8 3 C10aromatichydrocarCons 132 3 C10cycloalkanes 38.4 3 C11alkanes 36.4 3 C11alkenes 84.5 3 C11aromatichydrocarCons 134.2 3 C11cycloalkanes 38.4 3 C12alkanes 35.7 3 C12cycloalkanes 35.7 3 C13alkanes 31.7 3 C13+alkanes 31.7 3 C13+aromatichydrocarCons 128.3 3 C14alkanes 30.7 3 C15alkanes 28.4 3 C16alkanes 24.2 3 C2-alkyl-anthracenes 139.8 2 C2-alkyl-Cenzanthracenes 0 3 C2-alkyl-Cenzophenanthrenes 0 3 C2-alkyl-chrysenes 0 3 C2-alkyl-phenanthrenes 115.7 3 C5alkenes 87.6 3 C6alkenes 95.7 3 C7alkanes 42.3 3 C7alkenes 95.9 3 Species POCP Method Reference C8alkanes 42.2 3 C8alkenes 93.7 3 C8cycloalkanes 48.1 3 C9alkanes 40.4 3 C9alkenes 90.8 3 C9aromatichydrocarCons 98.6 3 C9cycloalkanes 41.4 3 camphor/fenchone 74.5 3 carcondisulphide 0 3 carcontetrachloride 0 1 Cydefinition carconylsulphide 0 3 chlorobenzene 9.9 2 chlorobutane 17.6 2 chlorocyclohexane 34.8 2 chlorodifluoromethane 0.2 2 chloroethane 10.4 2 chloroethylene 36.1 2 chlorofluoromethane 1.9 2 chlorofluoropicolines 51.3 3 chloromethane 0.5 1 Derwentetal.,1998 chloroprene 43.7 2 chrysene 0 3 cis-1,3-dimethylcyclopentane 45.8 2 cis-2-butene 114.6 1 Derwentetal.,1998 cis-2-hexene 106.9 1 Derwentetal.,1998 cis-2-octene 99.4 2 cis-2-pentene 112.1 1 Derwentetal.,1998 coronene 0 3 crotonaldehyde 70 2 cycloheptane 53.4 2 cyclohexanamine 51.3 3 cyclohexane 29 1 Derwentetal.,1998 cyclohexanol 51.8 1 JenkinandHayman,1999 cyclohexanone 29.9 1 Derwentetal.,1998 cyclooctane 46.7 2 cyclopenta(c,d)pyrene 0 3 cyclopenta-anthracenes 0 3 cyclopenta-phenanthrenes 0 3 cyclopentane 51.5 2 cyclopentene 106.8 2 decalin 44.4 2 decane 38.4 1 Derwentetal.,1998 diacetoneketogulonicacid 0 3 diaminotoluene 51.3 3 diazinon 51.3 3 dicenzanthracenes 0 3 dicenzo(a,h)anthracene 0 3 dicenzophenanthrenes 0 3 dicenzopyrenes 0 3 190 191

Species POCP Method Reference dichlorodifluoromethane 0 1 Cydefinition dichlorofluoromethane 1.3 2 dichloromethane 6.8 1 Derwentetal.,1998 dichlorvos 51.3 3 diethyldisulphide 0 3 diethylether 44.5 1 JenkinandHayman,1999 diethylsulphate 0 3 diethylamine 51.3 3 diethylbenzene 105.7 3 difluoromethane 0.6 2 dihydroxyacetone 28.5 2 diisopropylether 39.8 1 JenkinandHayman,1999 diisopropylbenzene 82.2 2 dimethoxymethane 16.4 1 JenkinandHayman,1999 dimethyldisulphide 0 3 dimethylesters 17.1 3 dimethylether 18.9 1 JenkinandHayman,1999 dimethylfurans 64.6 3 dimethylsulphate 0 3 dimethylsulphide 0 3 dimethylamine 51.3 3 dimethylbutene 59.9 3 dimethylcyclohexane 47.3 2 dimethylcyclopentane 45.8 3 dimethylformamide 51.3 3 dimethylhexene 93.7 3 dimethylnonane 38.4 3 dimethylpentane 49.4 3 dipentene 74.5 2 dipropylether 53.1 2 dodecane 35.7 1 Derwentetal.,1998 ethane 12.3 1 Derwentetal.,1998 ethanethiol 0 3 ethanol 39.9 1 JenkinandHayman,1999 ethofumesate 51.3 3 ethylacetate 20.9 1 JenkinandHayman,1999 ethylacrylate 41.4 2 ethylbutanoate 30.1 2 ethylchloroformate 10.1 2 ethylhexanol 53.5 3 ethyllactate 32.8 2 ethylpentanoate 32.4 2 ethylpropionate 19.9 2 ethylamine 51.3 3 ethylbenzene 73 1 Derwentetal.,1998 ethylcyclohexane 48.3 2 ethylcyclopentane 46.6 2 ethyldimethylbenzene 132 3 ethylene 100 1 Derwentetal.,1998 Species POCP Method Reference ethyleneoxide 2.4 2 ethylisopropylbenzene 105.7 3 fenitrothion 51.3 3 fluoranthene 0 3 fluorene 77.4 2 formaldehyde 51.9 1 Derwentetal.,1998 formanilide 0 3 formicacid 3.2 1 Derwentetal.,1998 fumaricacid 17.1 2 glycerol 39.2 2 glyoxal 58 2 heptadecane 12.2 2 heptane 49.4 1 Derwentetal.,1998 hexachlorocyclohexane 2.3 2 hexachloroethane 0 1 Cydefinition hexadecane 26 2 hexafluoropropene 69.4 2 hexamethylcyclotrisiloxane 0 3 hexamethyldisilane 0 3 hexamethyldisiloxane 0 3 hexamethylenediamine 51.3 3 hexane 48.2 1 Derwentetal.,1998 hexylcyclohexane 36.7 2 indan 79.7 2 indene 137.7 2 indeno(1,2,3-c,d)pyrene 0 3 iodomethane 0.7 2 isobutylbenzene 57.8 2 isobutylcyclohexane 36.3 2 isopentylbenzene 67.3 2 isophorone 77.6 2 isoprene 109.2 1 Derwentetal.,1998 isoprene+cvoc 90 3 isopropanolamine 51.3 3 isopropylbenzene 50 1 Derwentetal.,1998 isopropylcyclohexane 38 2 isopropylcyclopentane 43.7 2 limonene 74.5 2 m-cresol 68 2 m-xylene 110.8 1 Derwentetal.,1998 malathion 51.3 3 maleicanhydride 26.8 2 menthene 89.9 3 methacrylicacid 50.2 2 methanethiol 0 3 methanol 14 1 JenkinandHayman,1999 methoxy-2-propoxy-2-propanol 37.5 2 methylacetate 5.9 1 JenkinandHayman,1999 methylacrylate 39.1 2 192 193

Species POCP Method Reference methylethylether 25.3 2 methylformate 2.7 1 JenkinandHayman,1999 methylfurans 40.2 3 methylglyoxal 72 2 methylmethacrylate 46.7 2 methylnaphthalenes 125.2 3 methylpentanoate 31.9 2 methylstyrene 14.2 3 methyl-anthracenes 0 3 methyl-cenzanthracenes 0 3 methyl-cenzphenanthrenes 0 3 methyl-chrysenes 0 3 methyl-fluoranthenes 0 3 methyl-phenanthrenes 117.4 2 methylamine 0 3 methylcyclodecane 39.3 2 methylcycloheptane 47 2 methylcyclohexane 51 2 methylcyclopentane 48.1 2 methylethylbenzene 94.1 3 methylhexane 38.8 3 methylindane 80 2 methylpropene 62.7 1 Derwentetal.,1998 methylpropylbenzene 105.7 3 methyltetralin 114 3 monohydricphenols 78.2 2 N,N-diethylCenzenamine 51.3 3 N,N-dimethylCenzenamine 51.3 3 N-(hydroxymethyl)acrylamide 51.3 3 N-methylpyrrolidone 51.3 3 naphthalene 97.7 2 naphthol 61.1 2 NedocromilSodium 0 3 nitrobenzene 0 3 nitromethane 0 3 nitropentane 18.5 2 nitropropane 0 3 nonane 41.4 1 Derwentetal.,1998 o-cresol 67.3 2 o-xylene 105.3 1 Derwentetal.,1998 octahydroindan 44.5 2 octamethylcyclotetrasiloxane 0 3 octane 45.3 1 Derwentetal.,1998 octylamine 51.3 3 p-cenzoquinone 51.6 2 p-cresol 65.5 2 p-xylene 101 1 Derwentetal.,1998 palmiticacid 27.2 2 pentadecane 28.4 2 Species POCP Method Reference pentane 39.5 1 Derwentetal.,1998 pentanethiols 0 3 pentylbenzene 67.3 2 pentylcyclohexane 39.6 2 permethrin 51.3 3 perylene 0 3 phenanthrene 97.8 2 phenol 63.3 2 phenoxyaceticacid(phenoxyacid) 15.2 3 phenylaceticacid 15.2 3 phenylacetonitrile 51.3 3 phenylnaphthalenes 114.8 2 phorate 0 3 phthalicanhydride 105.3 3 pineoil 74.5 3 polyethyleneglycol 0 3 polyisobutene 0 3 polyvinylchloride 0 3 potassiumphenylacetate 51.3 3 propadiene 84.7 2 propane 17.6 1 Derwentetal.,1998 propanetriol 33.5 2 propanoicacid 15 1 Derwentetal.,1998 propionitrile 0 3 propylacetate 28.2 1 JenkinandHayman,1999 propylbutanoate 31.9 2 propylpropionate 28.5 2 propylamine 51.3 3 propylbenzene 63.6 1 Derwentetal.,1998 propylcyclohexane 45.4 2 propylcyclopentane 44.5 2 propylene 112.3 1 Derwentetal.,1998 propyleneoxide 13.4 2 propyne 74.6 2 pyrene 0 3 pyridine 51.3 3 salicylicacid 44.8 2 sec-butylbenzene 68.9 2 sec-butylcyclohexane 42.6 2 simazine 0 3 sodium2-ethylhexanoate 51.3 3 sodiumacetate 0 3 sodiumphenylacetate 51.3 3 styrene 14.2 1 Derwentetal.,1998 styreneacrylate 0 3 sulphanilamide 0 3 terpenes 74.5 2 tert-butylamine 51.3 3 tert-butylbenzene 53.4 2 194 195

Species POCP Method Reference tert-butylcyclopropane 11.5 2 tert-pentylbenzene 67.3 2 tetrachloroethene 2.9 1 Derwentetal.,1998 tetradecane 30.7 2 tetrafluoroethene 9.4 2 tetrahydrofuran 57 2 tetrahydrofurylalcohol 58.3 2 tetramethylcyclohexane 38.5 3 toluene 63.7 1 Derwentetal.,1998 toluene-2,3-diamine 51.3 3 toluene-2,4-diamine 51.3 3 toluene-2,4-diisocyanate 51.3 3 toluene-2,5-diamine 51.3 3 toluene-2,6-diamine 51.3 3 toluene-2,6-diisocyanate 51.3 3 toluene-3,4-diamine 51.3 3 toluene-3,5-diamine 51.3 3 trans-2-butene 113.2 1 Derwentetal.,1998 trans-2-hexene 107.3 1 Derwentetal.,1998 trans-2-pentene 111.7 1 Derwentetal.,1998 trans-3-hexene 107.2 2 tri-n-butylphosphate 0 3 trialkylphosphate 0 3 trichloroethene 32.5 1 Derwentetal.,1998 trichlorofluoromethane 0 1 Cydefinition trichloromethane 2.3 1 Derwentetal.,1998 tridecane 32.7 2 triethanolamine 51.3 3 triethylamine 51.3 3 trifluoroethene 54.7 2 trifluoromethane 0 3 trifluralin 51.3 3 trimethylamine 51.3 3 trimethylfluorosilane 0 3 undecane 38.4 1 Derwentetal.,1998 unspeciated 51.3 3 unspeciatedalcohols 36.4 3 unspeciatedaliphatichydrocarcons 36.8 3 unspeciatedalkanes 36.8 3 unspeciatedalkenes 97.5 3 unspeciatedamines 51.3 3 unspeciatedaromatichydrocarcons 95.4 3 unspeciatedcarcoxylicacids 15.2 3 unspeciatedcycloalkanes 43.4 3 unspeciatedhydrocarcons 71.9 3 unspeciatedketones 42 3 urea 0 3 vinylacetate 48.5 2 196