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省 24 路 29 TEL:886-4-23501155 FAX:886-4-23507373 Baxenden Chemicals 異量異不離異 NC 量 Et Et R N H Et H R1 H R N R 1 例 1. 異量率 NCH=11 來量 NCH=12 理論行力 NCH11.3 11.8 率理 1 1.6 不理量來 NCH=11.6 來量異來 [Dimethyl Pyrazole(DMP)][Diethyl Malonate(DEM)] 來異異 (DEM) 數量不量例 NC:H 量量 NC:H 率 1:1.3 理 1:1.6 1:1.8 1. 量 NC 量理 Trixene BI 7963 DEM 367 298 265 Trixene BI 7990 DMP/DEM 468 414 384 Trixene BI 7991 DMP/DEM 397 351 326 Trixene BI 7992 DMP/DEM 397 351 326 1 9 2006.10

省 24 路 29 TEL:886-4-23501155 FAX:886-4-23507373 2. 異量 Trixene BI 7963 力量度 () NC:H MEK 度 90 1:1.0 8 HB 100 1:1.0 42 3H 110 1:1.0 100 6H 90 1:1.3 100 2H 100 1:1.3 250 4-5H 110 1:1.3 >250 4-5H 90 1:1.6 150 2H 100 1:1.6 >250 6H 110 1:1.6 >250 6H Trixene BI 7963 量例 Crodaplast AC589 來 0.5%DBTL 30 1. BI7981 caprolctam() HDI 不度 180 200 不 2. MEK() HDI 不 ( 例 D-2BL3175) 料 (coil coating)pmt 度 230~260 30~50 6~7 () 力 3. BI7982BI7960 DMP HDI 不度 120 200 10 12~15 2 9 2006.10

省 24 路 29 TEL:886-4-23501155 FAX:886-4-23507373 不列 A. 90 1.BI7962HDI BIURET 58 NC7.3 2.BI7963HDI BIURET 70 NC8.8 B. 120 1.BI7960HDI BIURET 70 NC10.2 2.BI7982HDI TRIMER 70 NC10.2 3.BI7950IPDI 65 NC7.4 4.BI7951IPDI TRIMER 65 NC7.8 5.BI7990IPDI TRIMER 65 NC7.8 6.BI7991HDI BIURET 70 NC9.2 7.BI7992HDI TRIMER 70 NC9.2 9.BI76411TDI 60 NC5.65 BI7641 都度 10 DBTDLAT-18 來更更量 0.2~0.3 C. 150 1.D2 HDI TRIMER 75 NC11.2 2.BH-75NHDI TRIMER 75 NC11.2 D. 140 1.BIH-1250IPDI TRIMER 100 NC12.0~12.6 E. 180 1.BI7981HDI TRIMER 70 NC8.8 BI7981 coil coating 26090 4~5 IPDI 列度 Tg 度不列 A. 120 1.BI7986HDI TRIMER 40 NC5.0 2.BI7987HDI TRIMER 40 NC4.5 B. 150 1.WT1000HDI TRIMER 63 NC9.4 BAXENDEN REACTS T ENVIRNMENTAL ISSUES WITH A LESS TXIC ISCYANATE BAXENDEN 異來 3 9 2006.10

省 24 路 29 TEL:886-4-23501155 FAX:886-4-23507373 Blocked isocyanates are well established as formulation components in the coatings industry [1]. These are generally based on the blocking agents methyethylketoxime, caprolactam and diethyl malonate. Baxenden Chemicals has developed a range of blocked isocyanate products based on the blocking agent, 3,5-dimethyl pyrazole. These products have lower unblocking temperatures than other blocked isocyanates and are gaining an increasing share of the blocked isocyanate market. The majority of applications for blocked isocyanates are solvent-based, however with increasing environmental awareness and legislation, the use of solvents is expected to reduce and the use of water-based materials is expected to increase. Baxenden Chemicals has further responded to this opportunity by developing a novel water-based blocked isocyanate based on this pyrazole unit. 料異 (blocked isocyanates) (methylethylketoxime)(caprolactum) (ethyl malonate)baxenden Chemicals 列 3,5-dimethyl pyrazole() 異 (blocked isocyanate products) 異度 (unblocking temperature) 率來異 (blocked isocyanates) 益立來量益來 Baxenden Chemicals 更了 (pyrazole) 異 : 異 ( 理 ) 異 (isocyanates) PU 料異 -- (di- or tri- functional)(polyhydroxy compounds)( H- 力類 )(polyols that are normally-h terminated polyesters or acrylics) (catalysts,) (tin com-plex) 狀 (ure-thane polymer network) 來說兩 (pot life) 行異 (isocyanate group) 來異 (isocyanates) (polyols) 度利異 (blocking agent) 來 (a) (b) 4 9 2006.10

省 24 路 29 TEL:886-4-23501155 FAX:886-4-23507373 (c) 異 (blocked isocyanates)(polyols) 度 (activation temperature)( 度 unblocking temperature)(reactive,,) 度異 (unblock) NC (NC group)(polyols) (urethane polymer) 離 (free blocking agent) 留料利料更異車 (automotive EM)(coil coating)(textile coating)(electrostatic spray)(electro deposition) 都易 (one component heat curing systems) (one pack, 1K) 兩 (two packs, 2K) ( 度 ) 兩來說都行度料 (1K blocked systems) 來說不料六異 (heat curing) 料不異利 BLCKING AGENT() 類 (nature) 都 (active hydrogen atom) 都 ( 例 [diethyl malonate][methylene group] NC ) (butanoxime)(methylethylketoxime MEK) 年來良 (in-can stability) 都度 (unblocking temperature) 異 (aliphatic isocyanate) 來 MEK 度 (volatile) 料料 VC 量 ( :VC Volatile organic compound ) 立不不了來 MEK MEK HDI (HDI) 度 160 更度 MEK (yellowing) MEK 異老 [ 見 2] [caprolactam(-cap)] 度 MEK ( HDI 來說 190) 料 (powder coating) 度不不 E-CAP 不 MEK (diethyl malonate) 兩 (carbonyl groups) 5 9 2006.10

省 24 路 29 TEL:886-4-23501155 FAX:886-4-23507373 (methylene bridge)(polyol components) 異不 1b (mechanism) (unmasked) 不不類 (ester function) (transesterification)[ 見 3] 不 (urethane linkage)(crosslinked structure)(polyols) 120 度不 (shelf life) 了 3,5-(3,5-dimethyl pyrazole)( DMP) 來 [ 見 4] 理不度 Baxenden Chemical 列 DMP 異 (blocked isocyanates) DMP 異異度 115-120 見都度 DMP (melting point) 107-109 218 來留料說量 VC 令 (acid etch resistance) MEK 不料 3,5-dimethyl pyrazole 度 1 列了度 (peak unblocking temperature) 1 來數利 (differential scanning colorimety[ DSC] 來異 Water dispersible systems()() 來立來料來了兩 PU (2K aqueous polyurethane systems) 來料異 (water dispersible isocyanates) 來粒 (emulsion) 粒料異來了亮度 (gloss) 異異 (isocyanate dispersion) (limited pot life) 異尿 (urea) (blocking agent) TDI (TDI adduct) 6 9 2006.10 度 (peak exotherm) HDI 尿 (HDI biuret) DMP 71 122 MEK 119 163 E-CAP 166 190 1 Peak exotherms () 兩利異 (predispersed blocked isocyanate) 異 (blocked isocyanate) 不 Trixene BI 7986() Baxenden Chemical 異 (water dispersed blocked isocyanate) 利兩 PU

省 24 路 29 TEL:886-4-23501155 FAX:886-4-23507373 異連 (solvent-based blocked polyisocyanate crosslinkers) (polyurethane dispersions, PUD)Trixene BI 7986 異 [aliphatic isocyanate(hdi trimer, HDI ) 說 (naturally hydrophobic,) 理 (surfactants)(organic back-bone)(hydrophilic) 離離離料異異 (stable emulsion of the blocked isocyanate)(stabilizers) ph Trixene BI 7986 異 (stable blocked polyisocyanate emulsion) 2 列了 3. Trixene BI 7986 Xenacryl 2541 粒 (Grades) (Solids) 度 (Viscosity) 25 ph 粒 (particle size) nm BI 7986 42% 150 csp 7-8 70-100 8% 2. Trixene BI 7986 NMP 量料 1 2 28.6* 26.7** (paint remix) Xenacryl 2541 46.8 31.9 Trixene BI 7986 21.9 14.9-4. (Coalescing solvent) (water) - 21.4 (other additives) 20 1.0 * i2 **Ti2 (Zine phosphate) 3.Paint formulations 了 BI 7986 料料力 (hydroxylfunctional acrylic latexes)(curative) Xenacryl 25 列都 Baxenden 2K (film forming resins) 都量 (dry film weight) 45%(solids) 2% 量 (hydroxyl level)xenacryl 列粒 (particle size distribution) BI 7986 說粒良異 (film properties) 3 列了兩 Trixene BI 7986 1 亮度 (stoving enamel) 2 (primer surface) 4 列兩都 12045 DMP 異 (water-based system) (water-based tin catalyst) 例 Trixene 1402 7 9 2006.10

省 24 路 29 TEL:886-4-23501155 FAX:886-4-23507373 (Paint properties) 1 2 (Solid content) 50% 50% PH 9.0 8.8 度 (25) 2300 mpa.s 290 mpa.s (25) 1.21 1.19 PVC 19% 23.35 (Stoving cycle) 45,120 45,120 料 (Coating properties) 1 2 度 (Dry film thickness) n/a 25µm 不 (opacity) 96% 96% 亮度 @20 60% n/a 亮度 @60 84% 35% (Reverse impact) 100cm n/a (Bend Test)(3 mm mandrel) (Impact resistance)(1.8kg) (Reverse) n/a 100cm (Direct) n/a 100cm (Acetone resistance) (Double rubs) >100 n/a 不 (Acetone insoluble) (Soxhlet extraction, 索 ) n/a 98% 度 (Persoz hardness) n/a 69s 切 (Cross cut adhesion 0-5, 0,5 ) (Smooth steel) n/a 0 (Matt steel) n/a 0 (Tin plated steel) 0 0 理 (Phosphate treated steel) n/a 0 車 n/a 0 (Galvanized steel) 1 (Aluminum) n/a 1 (Chrome plated aluminum) n/a 0 : n/a 4. 料 (paint and coating properties) 90 年 21 料來力量料 (water-based material) 不來異 (Waterborne blocked isocyanates) 例 Trixene BI 7986 領 3,5-(dimethyl pyrazole) 料 8 9 2006.10

省 24 路 29 TEL:886-4-23501155 FAX:886-4-23507373 參料 1. Z.Wickes, Jur Prog rg Coatings, 1981 2. Z.Wickes et al, rganic Coatings Science and Technology, J Wiley, 1999, p199 3. Z.Wickes et el, rganic Coatings Science and Technology, J Wiley, 1999, p198 4. EP15917, US 4976837 5. W 9712924 : Asia Pacific Coatings Journal (January/February 2000) BACENDEN Reacts to Environmental Issues With A Less Toxic Isocyanate AUTHR: I RIMMER, R JNES, BAXENDEN CHEMICALS, ACCRINGTN, LANCASHIRE, UK : Baxenden Chemical 理 : 路 11-8 TEL: (04) 23861866 FAX: (04) 23812966 * 連 : 金料不力不 9 9 2006.10