2009 년도잔류성유기오염물질 (POPs) 측정망실태조사최종보고서 2010
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POPs POPs. POPs 160, 12... / 0.051, 0.002 pg TEQ/m 3. 09 08 10 (0.045 0.425), (0.6 pg TEQ/m 3 ) 10 1. / 0.127 0.205, 0.007 0.012., 0.304. /, 0.165, 0.005 pg TEQ/L, 0.003 ng/l. /, 2.280, 0.246 pg TEQ/g, 0.113 ng/g 08.. 5.921, 0.539 ng/g. /, 0.860, 0.078 pg TEQ/g, 0.120 ng/g 08. - ii -
. 6.264, 4.015, 0752 pg/m 3..,., 79 200 ng/g 40%. 08,.. /.,, > > >. 08 09 DDTs/DDEs, o,p -DDT/p,p -DDT DDTs/DDEs. o,p -DDT/p,p -DDT ( ).. /,, - iii -
. ⅰ ⅳ ⅴ ⅷ Ⅰ. 1 1. 1 2. 3 Ⅱ. 5 1. POPs 5 2. 5 3. 7 Ⅲ. POps 8 1. 8 2. 14 3. 20 4. 27 Ⅳ. POPs 44 1., 44 2. 81 Ⅴ. 121 123 - iv -
- v -
I-2-1. 3 Ⅱ-1-1. 5 Ⅱ-2-1. POPs 5 Ⅱ-2-2. 6 Ⅱ-2-3. 7 Ⅲ-1-1 8 Ⅲ-1-2. 8 Ⅲ-1-3. 9 Ⅲ-1-4. 11 Ⅲ-1-5. 12 Ⅲ-1-6. 13 Ⅲ-2-1. 15 Ⅲ-2-2. 16 Ⅲ-2-3. 17 Ⅲ-2-4. 7 17 Ⅲ-2-5. 18 Ⅲ-2-6. 19 Ⅲ-2-7. 20 Ⅲ-4-1. 28 Ⅲ-4-2. 28 Ⅲ-4-3. 7 29 Ⅲ-4-4. 29 Ⅲ-4-5. 30 Ⅲ-4-6. (Field Blank) 31 Ⅲ-4-7. (Field Blank) 32 Ⅲ-4-8. (Field Blank) 32 - vi -
Ⅲ-4-9. (Field Blank) 33 Ⅲ-4-10. (Field Blank) 7 34 Ⅲ-4-11. (Field Blank) 34 Ⅲ-4-12. (Field Blank) 35 Ⅲ-4-13. (Field Blank) 35 Ⅲ-4-14. (Glassware Blank) 36 Ⅲ-4-15. (Glassware Blank) 36 Ⅲ-4-16. (Glassware Blank) 7 37 Ⅲ-4-17. (Glassware Blank) 37 Ⅲ-4-18. (Glassware Blank) 37 Ⅲ-4-19. (%) 38 Ⅲ-4-20. (%) 39 Ⅲ-4-21. HRMS (OCPs) (%) 39 Ⅲ-4-22. LRMS (OCPs) (%) 40 Ⅲ-4-23. Total PCBs (%) 40 Ⅲ-4-24. (%) 41 Ⅲ-4-25. 42 Ⅲ-4-26. 42 Ⅲ-4-27. 7 43 Ⅲ-4-28. 43 Ⅳ-1-1. 45 Ⅳ-1-2. 49 Ⅳ-1-3. (PCDD/DFs, Co-PCBs) 51 Ⅳ-1-4. (PCDD/DFs, Co-PCBs) 54 Ⅳ-1-5. 56 Ⅳ-1-6. POPs (PCDD/DFs, Co-PCBs) 61 Ⅳ-1-7. (PCDD/DFs, Co-PCBs) 62 - vii -
Ⅳ-1-8. 63 Ⅳ-1-9. (PCDD/DFs, Co-PCBs) 65 Ⅳ-1-10 POPs (PCDD/DFs, Co-PCBs) 69 Ⅳ-1-11. (PCDD/DFs, Co-PCBs) 70 Ⅳ-1-12. / 71 Ⅳ-1-13. 72 Ⅳ-1-14. POPs (PCDD/DFs, Co-PCBs) 76 Ⅳ-1-15. (PCDD/DFs, Co-PCBs) 77 Ⅳ-1-16. / 78 Ⅳ-1-17. 79 Ⅳ-2-1. 82 Ⅳ-2-2. 88 Ⅳ-2-3. 90 Ⅳ-2-4. 94 Ⅳ-2-5. 08 09 98 Ⅳ-2-6. 100 Ⅳ-2-7. 08 09 103 Ⅳ-2-8. POPs 105 Ⅳ-2-9. 106 Ⅳ-2-10. 107 Ⅳ-2-11. 110 Ⅳ-2-12. DDTs 112 Ⅳ-2-13. 115 Ⅳ-2-14. 116 Ⅳ-2-15. 117 Ⅳ-2-16. 118 Ⅳ-2-17. 119 - viii -
I-2-1. POPs 4 Ⅲ-1-1. POPs 10 Ⅲ-3-1. 21 Ⅲ-3-2. 21 Ⅲ-3-3. 22 Ⅲ-3-4. 23 Ⅲ-3-5. 24 Ⅲ-3-6. Co-PCBs 24 Ⅲ-3-7. OCPs 25 Ⅲ-3-8. OCPs 26 Ⅳ-1-1. (PCDD/DFs, Co-PCBs) 44 Ⅳ-1-2. (PCDD/DFs, Co-PCBs) 46 Ⅳ-1-3. (PCDD/DFs, Co-PCBs) 52 Ⅳ-1-4. 16 57 Ⅳ-1-5. 37 58 Ⅳ-1-6. (PCDD/DFs, Co-PCBs) 66 Ⅳ-1-7. (PCDD/DFs, Co-PCBs) 73 Ⅳ-1-8. (PCDD/DFs, Co-PCBs) 80 Ⅳ-2-1. 81 Ⅳ-2-2. 84 Ⅳ-2-3. 85 Ⅳ-2-4. 93 Ⅳ-2-5. ( 08-09) 96 Ⅳ-2-6. ( 08-09) 97 Ⅳ-2-7. 98 Ⅳ-2-8. 16 101 - ix -
Ⅳ-2-9 37 102 Ⅳ-2-10 10 103 Ⅳ-2-11. 111 Ⅳ-2-12. 120 - x -
I. 1. (POPs, Persistent Organic Pollutants) ( 10034, 2010. 2. 4) 2.,,,,,,,,,,, 12 ( 21705, 2009.8.25).,,.,.. 1972,. 2001 5 2004 5, 2007 1. 11, (monitoring), (presence) (levels) (trends), (fate) (transformation). 2007 1
, 11 4 2008 1. 2009. 2009 POPs ( ) 160, 12 POPs. - xii -
2.. 2009-98 (2009. 7.). : 2009. 01. ~ 2009. 12.(1 ). 2009 POPs I-2-1, I-2-1. I-2-1 POPs, 10%, POPs,. I-2-1. () - xiii -
I-2-1. POPs - xiv -
II. 1. POPs POPs ( 2009-98, 2009. 7.) POPs 160 12 POPs. II-1-1. 37 36 57 30 4 / 2 / 1 / 1 /,, PCBs, HCB,,,,,,,, (DDT) 2.. POPs POPs 160 603 61 664 II-2-1.,. II-2-1. POPs ( ) 4 37 3 = 444 2 36 = 72 1 57 = 57 1 30 = 30 603 () 1 15 3 = 45 1 7 = 7 1 6 = 6 1 3 = 3 61 489 79 63 33 664 - xv -
. POPs POPs ( 2007-165, 2007.11.7). POPs 11 HRGC/HRMS, ( ) GS/MS., POPs GC/NCI. II-2-2. II-2-2. POPs ES 10901.1, ES 10904.1 ES 10907.1 HRGC/MS GC/MS,, - ES 10901.1 - Total-PCBs - - HCB (DDT) ES 10900.1, ES 10903.2 ES 10906.2 ES 10900.1, ES 10903.2 ES 10906.2 ES 10900.1, ES 10903.2 ES 10906.2 ES 10900.1, ES 10903.2 ES 10906.2 ES 10900.1, ES 10903.2 ES 10906.2 ES 10900.1, ES 10903.2 ES 10906.2 ES 10900.1, ES 10903.2 ES 10906.2 ES 10900.1, ES 10903.2 ES 10906.2 ES 10307.1, ES 10367.1 ES 10427.1 - -,, GC/NCI ( ) - xvi -
II-2-3. 37 36 57 30 4 / 2 / 1 / 1 / 1 2, 4 5 7 8, 10 11 4 5, 10 11 4 5 10 11 ( 603 ) 111 4 = 444 36 2 = 72 57 30,,,, Total-PCBs Total-PCBs Total-PCBs HCB HCB HCB (DDT) (DDT) (DDT) (DDT) 3. 10% (61 ), POPs POPs, (CRM, Certified Reference Material). - xvii -
III. POPs 1..,,. III-1-1, III-1-2 III-1-3. III-1-1. 444 72 57 30 45 7 6 3 III-1-2. * * ( ) 2009. 4.20. 20 L ( ) 2009. 4.20. 20 L ( ) 2009. 4.21. 20 L () 2009. 4.21. 20 L 2009. 10.5. 20 L 2009. 10.9. 20 L 2009. 10.9. 20 L 2009. 4.23. 92.4393 g 2009. 4.24. 88.7621 g 2009. 4.24. 96.9268 g 2009. 4.21. 90.1750 g 2009. 4.24. 68.6194 g 2009. 4.29. 89.4302 g () 2009. 9.28. 80.1783 g ( ) 2009. 9.23. 92.3276 g ( ) 2009.10. 7. 81.1272 g * : 한국환경공단에서채취한시료일부를국립환경과학원이인수한시료임 - xviii -
III-1-3. (m 3 ) - - - - - - - - - - - - - - - 2009.4.21~4.22 1007.9 2009.4.22~4.23 1007.9 2009.4.23~4.24 1007.9 2009.4.21~4.22 1007.9 2009.4.22~4.23 1007.9 2009.4.23~4.24 1007.9 2009.4.21~4.22 1007.9 2009.4.22~4.23 1007.9 2009.4.23~4.24 1007.9 2009.4.28~4.29 1079.9 2009.4.29~4.30 1079.9 2009.4.30~5.01 1079.9 2009.4.28~4.29 1079.9 2009.4.29~4.30 1079.9 2009.4.30~5.01 1079.9 2009.4.28~4.29 1079.9 2009.4.29~4.30 1079.9 2009.4.30~5.01 1079.9 2009.4.28~4.29 1079.9 2009.4.29~4.30 1079.9 2009.4.30~5.01 1079.9 2009.4.21~4.22 1007.9 2009.4.22~4.23 1007.9 2009.4.23~4.24 1007.9 2009.10.20~10.21 1079.9 2009.10.21~10.22 1079.9 2009.10.22~10.23 1079.9 2009.10.20~10.21 1079.9 2009.10.21~10.22 1079.9 2009.10.22~10.23 1079.9 2009.10.13~10.14 1079.9 2009.10.14~10.15 1079.9 2009.10.15~10.16 1079.9 2009.10.13~10.14 1079.9 2009.10.14~10.15 1079.9 2009.10.15~10.16 1079.9 2009.10.13~10.14 1079.9 2009.10.14~10.15 1079.9 2009.10.15~10.16 1079.9 2009.10.20~10.21 1079.9 2009.10.21~10.22 1079.9 2009.10.22~10.23 1079.9 2009.10.20~10.21 1007.9 2009.10.21~10.22 1007.9 2009.10.22~10.23 1007.9 - xix -
. (2007),, HRGC/HRMS, HRGC/LRMS, HRGC/NCI-MS ( III-1-1)., UNEP 7 (IUPAC No. 28, 52, 101, 118, 138, 153 180) EPA Method 8082. III-1-4. (a) POPs (b) III-1-1. POPs - xx -
III-1-4.,,, HRGC/HRMS HRGC/HRMS,, GC/MSD HRGC/HRMS 8 1),, GC/MSD,,, GC/NCI-MS 2) 1) 9 2) NCI-MS ; Negative chemical ionization mass spectrometry 17 12, 9 ( 22 ). UNEP 7. III-1-5.. POPs.,.,,, III-1-6. - xxi -
III-1-5. PCDD/Fs (17 ) (12 ) 2378-TCDD PCB #28 12378-PeCDD PCB #52 PCB #101 123478-HxCDD PCBs PCB #118 123678-HxCDD (7 ) PCB #138 123789-HxCDD PCB #153 1234678-HpCDD PCB #180 OCDD HCB - 2378-TCDF Heptachlor - 12378-PeCDF Heptachlor epoxide - 23478-PeCDF Aldrin - 123478-HxCDF Dieldrin - 123678-HxCDF Endrin - 123789-HxCDF 234678-HxCDF 1234678-HpCDF 1234789-HpCDF OCDF Chlordanes (5 ) PCB #77 Mirex - PCB #81 PCB #105 PCB #114 PCB #118 PCB #123 PCB #126 DDTs (6 ) PCB #156 Mirex - PCB #157 PCB #167 PCB #169 PCB #189 Toxaphene (3 ) trans-chlordane cis-chlordane trans-nonachlor cis-nonachlor Oxychlordane p,p-dde o,p-dde p,p-ddd o,p-ddd p,p-ddt o,p-ddt Parlar-26 Parlar-50 Parlar-62 - xxii -
III-1-6. HRGC/HRMS - - batch - - - HCB : 40~120% - : 30~120% - : 50~120% - 50-120% - RRF RSD - 0.99 - ±15% Ver. STD - RRF ±20% CS 3-10% Valley 10,000 PFK - 5ppm isotope ratio - ±15% lock mass - ±20% - 7 3.14 - - - - - xxiii -
2.. POPs (CRM, Certified reference material). 9 CRM, 17 12 CRM. 1) CRM,,,,. CRM 95%. CRM III-2-1. 2) CRM. CRM 95%. CRM III-2-2. - xxiv -
III-2-1. ( : pg/g) S.D PCDDs/ DFs 95% 2,3,7,8-TCDD 11.4 2.98 11.4±5.96 13.507 12.733 1,2,3,7,8-PeCDD 38.4 9.72 38.4±19.4 51.804 19.589 1,2,3,4,7,8-HxCDD 31.3 10.9 31.3±21.8 49.665 13.712 1,2,3,6,7,8-HxCDD 70.4 22.2 70.4±44.4 82.506 28.404 1,2,3,7,8,9-HxCDD 56.3 19.2 56.3±38.4 83.978 31.342 1,2,3,4,6,7,8-HpCDD 899 301 899±602 953.574 631.734 OCDD 3,660 1,150 3,660±2,300 3,465.628 2,338.883 2,3,7,8-TCDF 21.8 5.87 21.8±11.7 23.519 27.424 1,2,3,7,8-PeCDF 59.6 14.4 59.6±28.8 43.166 33.301 2,3,4,7,8-PeCDF 46.9 12.0 46.9±24.0 67.363 28.404 1,2,3,4,7,8-HxCDF 89.7 28.8 89.7±57.6 68.129 52.889 1,2,3,6,7,8-HxCDF 100 30.4 100±60.8 122.102 52.889 1,2,3,7,8,9-HxCDF 13.3 2.54 13.3±5.08 17.537 14.691 2,3,4,6,7,8-HxCDF 125 34.7 125±69.4 158.882 81.293 1,2,3,4,6,7,8-HpCDF 530 159 530±318 549.509 323.213 1,2,3,4,7,8,9-HpCDF 117 37.5 117±75.0 144.221 57.786 OCDF 864 243 864±486 840.918 387.855 PCB #77 8.26 1.85 8.26±3.70 8.061 12.733 PCB #81 5.26 0.93 5.26±1.86 5.038 5.877 PCB #105 7.61 3.29 7.61±6.58 13.773 11.753 PCB #114 2.75 0.65 2.75±1.30 2.745 2.938 PCB #118 8.26 4.48 8.26±8.96 12.799 4.897 PCB #123 1.72 0.45 1.72±0.90 2.393 0.979 PCB #126 13.9 2.52 13.9±5.04 13.658 8.815 PCB #156 9.43 1.65 9.43±3.30 11.513 10.774 PCB #157 6.24 0.84 6.24±1.68 6.950 5.877 PCB #167 4.26 0.69 4.26±1.38 4.999 4.897 PCB #169 9.93 1.45 9.93±2.90 9.701 8.815 PCB #189 14.3 2.22 14.3±4.44 14.493 10.774 - xxv -
III-2-2. ( : ng/g) S.D 95% Aldrin 207 10.75 207±21.5 194.180 188.864 trans-chlordane 316 16.0 316±32.0 196.982 290.300 cis-chlordane 173 8.2 173±16.4 356.198 186.300 p,p -DDD 297 12.3 297±24.6 277.752 280.676 p,p -DDE 95.7 5.25 95.7±10.5 90.455 93.369 p,p -DDT 339 14.85 339±29.7 305.270 318.252 Dieldrin 106 3.91 106±7.81 132.134 111.352 Endrin 383 18.4 383±36.8 403.021 353.038. 1),,,, (50 120%), (RRF) (15%).,.. (50~120%), III-2-3. - xxvi -
III-2-3. ( ) / 79.5 119.2 50.1 50 120% 93.0 117.4 66.1 / 86.5 119.8 55.7 50 120% 98.7 120.0 61.1 / 85.3 114.6 50.8 50 120% 96.3 119.3 53.2 / 80.7 119.8 50.0 50 120% 93.2 119.6 65.3 / 85.3 118.5 52.2 50 120% 85.4 110.7 51.1 / 71.9 97.9 50.0 50 120% 96.8 119.7 75.1 / 93.2 119.9 55.1 50 120% - 87.1 112.8 55.9 / 87.6 114.8 66.2 50 120% - 94.1 119.8 71.1 2) 7,., III-2-4. III-2-4. 7 ( ) PCBs 7 50-120% 69.9 93.0 50.2 94.2 119.6 67.4 PCBs 7 50-120% - 79.7 91.7 57.8 PCBs 7 50-120% - 76.0 105.9 50.1 - xxvii -
3),.,, (RRF) 15%, (Lock mass) ±20%, Ghost peak Isomer ratio. (Duplicate sample),. (50~120%), (70~120%), III-2-5 III-2-6. III-2-5 Heptachlor 92.7 119.9 61.9 91.1 119.2 54.8 Aldrin 79.9 100.5 53.3 85.4 111.2 57.8 o,p'-dde 85.0 111.5 57.8 82.1 102.6 51.1 p,p'-dde 88.7 117.1 54.6 86.8 111.9 52.1 o,p'-ddd 90.5 117.5 55.9 85.5 109.2 51.4 Dieldrin 77.8 110.3 54.5 83.5 115.5 51.7 Endrin 69.0 117.9 50.5 85.4 119.2 50.1 p,p'-ddd 91.2 119.0 57.2 88.0 113.3 53.9 o,p'-ddt 98.3 119.6 55.5 92.2 118.8 56.5 p,p'-ddt 99.7 119.7 50.5 95.8 119.9 58.1 Mirex 79.4 98.4 52.9 72.4 89.6 50.3 Heptachlor Epoxide 89.2 117.7 63.7 83.0 118.3 50.5 Oxychlordane 76.8 118.8 50.0 80.8 116.6 50.7 trans-chlordane 74.8 112.1 50.4 90.2 119.8 58.2 trans-nonachlor 74.9 108.3 51.6 79.3 115.0 50.2 cis-nonachlor 77.7 118.7 55.8 84.2 119.8 51.5 - xxviii -
III-2-5 () Heptachlor 102.6 119.8 60.7 93.7 119.1 59.9 Aldrin 85.9 113.1 50.2 78.5 104.8 56.9 o,p'-dde 83.5 103.1 50.5 78.9 97.8 52.7 p,p'-dde 89.7 118.0 53.4 83.5 110.2 61.4 o,p'-ddd 92.1 114.9 52.4 86.9 110.3 57.4 Dieldrin 87.9 116.8 61.7 79.7 106.7 57.6 Endrin 95.2 119.8 50.3 84.5 119.5 50.4 p,p'-ddd 95.9 118.3 53.2 89.3 112.8 61.1 o,p'-ddt 100.3 119.7 53.3 96.1 117.6 60.6 p,p'-ddt 103.0 119.9 52.4 97.3 119.6 63.8 Mirex 81.1 96.9 62.6 71.6 98.8 50.4 Heptachlor Epoxide 100.8 119.5 71.8 81.8 103.9 59.3 Oxychlordane 82.7 109.8 60.4 79.2 113.4 52.1 trans-chlordane 83.6 106.7 65.2 79.4 104.3 55.0 trans-nonachlor 80.1 99.4 66.4 75.1 101.4 53.0 cis-nonachlor 85.3 101.6 63.5 78.8 100.6 54.0 : 50~120% III-2-6. ( ) 70 120% 82.0 111.0 70.2 82.7 119.3 70.2 70 120% - 88.6 119.7 70.2 70 120% - 91.4 106.9 70.2 4), III-2-7. - xxix -
III-2-7. ( ) 74.6 101.0 50.7 50 120% 75.0 119.4 50.7 78.1 119.8 50.1 77.8 111.2 51.2 79.4 107.5 70.4 85.3 105.5 70.0-98.2 119.3 73.6-79.1 96.7 70.1 3. (duplicate sample) 1) 10% ( 45, 7, 6, 3 ), ND~8.7 pg, ND~7.7 pg. III-3-1 III-3-2. X, Y., 1.48±1.19. - xxx -
PCDD/DFs measured by KECO 9 8 7 6 5 4 3 2 1 Air (pg I-TEQ/m 3 ) Water (pg I-TEQ/L) Soil and Sediment (pg I-TEQ/g) 0 0 1 2 3 4 5 6 7 8 9 PCDD/DFs measured by NIER III-3-1. 0.40 0.35 Air (pg I-TEQ/m 3 ) PCDD/DFs measured by KECO 0.30 0.25 0.20 0.15 0.10 0.05 0.00 0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 PCDD/DFs measured by NIER III-3-2. - xxxi -
III-3-3. III-3-3 1, 1. 0.9~1.3, OCDD, TCDF, HpCDF,, TEF. 1.0~1.2. 2.5 2.0 KECO/NIER (Conc. ratio) 1.5 1.0 0.5 0.0 2,3,7,8-TCDF 1,2,3,7,8-PeCDF 2,3,4,7,8-PeCDF 1,2,3,4,7,8-HxCDF 1,2,3,6,7,8-HxCDF 1,2,3,7,8,9-HxCDF 2,3,4,6,7,8-HxCDF 1,2,3,4,6,7,8-HpCDF 1,2,3,4,7,8,9-HpCDF OCDF 2,3,7,8-TCDD 1,2,3,7,8-PeCDD 1,2,3,4,7,8-HxCDD 1,2,3,6,7,8-HxCDD 1,2,3,7,8,9-HxCDD 1,2,3,4,6,7,8-HpCDD OCDD III-3-3. - xxxii -
2) 10%, ND~3.562 pg, ND~3.877 pg. III-3-4, III-3-6. 12 0.98±0.16, III-3-5. 0.9~1.2 PCBs 2,3',4,4',5-PeCB(#118), 1.0~1.2. 4.0 Co-PCBs measured by KECO 3.5 3.0 2.5 2.0 1.5 1.0 0.5 Air (pg WHO-TEQ/m 3 ) Water (pg WHO-TEQ/L) Soil and Sediment (pg WHO-TEQ/g) 0.0 0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 Co-PCBs measured by NIER III-3-4. - xxxiii -
2.0 KECO/NIER (Conc. ratio) 1.5 1.0 0.5 0.0 #81 #77 #105 #114 #118 #123 #126 #156 #157 #167 #169 #189 III-3-5. 0.025 Air (pg-who TEQ/m 3 ) Co-PCBs measured by KECO 0.020 0.015 0.010 0.005 0.000 0.000 0.005 0.010 0.015 0.020 0.025 Co-PCBs measured by NIER III-3-6. - xxxiv -
3) 19 45 III-3-7. 202.64±115.22 pg/m 3, 168.46±71.69 pg/m 3. 0.99±0.40. 0.92~1.34. III-3-8 trans-chlordane. 500 Air (pg/m 3 ) Sum of OCPs measured by KECO 400 300 200 100 0 0 100 200 300 400 500 Sum of OCPs measured by NIER III-3-7. OCPs - xxxv -
3.0 2.5 KECO/NIER (Conc. ratio) 2.0 1.5 1.0 0.5 0.0 HCB Heptachlor Aldrin 2,4-DDE 4,4-DDE 2,4-DDD Dieldrin Endrin 4,4-DDD 2,4-DDT 4,4-DDT Mirex Heptachlor epoxide Oxychlordane trans-chlordane cis-chlordane t-nonachlor cis-nonachlor III-3-8. OCPs - xxxvi -
4. 1) (S/N ratio) 2.5 1 POPs. 2~3 7 3.14, III-4-1 ~ III-4-5. 2,3,4,7,8-PeCDF, OCDF, 1,2,3,7,8-PeCDD, 1,2,3,4,7,8-HxCDD, 1,2,3,6,7,8-HxCDD, 1,2,3,7,8,9-HxCDD, 1,2,3,4,6,7,8-HpCDD, 3,3',4,4'-T4CB, 2,3',4,4',5-P5CB, 3,3',4,4',5,5'-H6CB 3~4. PCBs 7 EPA 1668A HRMS,.,. PCB #138,.,, POPs. GC/NCI,. - xxxvii -
III-4-1. Furan Dioxin (pg/sm3 ) (pg/l) (pg/g) 2,3,7,8-TCDF 0.010 0.05 0.392 0.5 0.098 1 1,2,3,7,8-PeCDF 0.010 0.05 0.415 0.5 0.104 1 2,3,4,7,8-PeCDF 0.025 0.05 0.995 0.5 0.249 1 1,2,3,4,7,8-HxCDF 0.010 0.05 0.407 0.5 0.102 1 1,2,3,6,7,8-HxCDF 0.015 0.05 0.609 0.5 0.152 1 2,3,4,6,7,8-HxCDF 0.009 0.05 0.370 0.5 0.092 1 1,2,3,7,8,9-HxCDF 0.009 0.05 0.350 0.5 0.087 1 1,2,3,4,6,7,8-HpCDF 0.014 0.05 0.574 0.5 0.144 1 1,2,3,4,7,8,9-HpCDF 0.011 0.05 0.460 0.5 0.115 1 OCDF 0.048 0.05 1.927 0.5 0.482 1 2,3,7,8-TCDD 0.010 0.05 0.391 0.5 0.098 1 1,2,3,7,8-PeCDD 0.030 0.05 1.216 0.5 0.304 1 1,2,3,4,7,8-HxCDD 0.037 0.05 1.462 0.5 0.365 1 1,2,3,6,7,8-HxCDD 0.022 0.05 0.898 0.5 0.224 1 1,2,3,7,8,9-HxCDD 0.025 0.05 0.996 0.5 0.249 1 1,2,3,4,6,7,8-HpCDD 0.023 0.05 0.916 0.5 0.229 1 III-4-2. (pg/sm3 ) (pg/l) (pg/g) 81 3,4,4',5-T4CB 0.006 0.05 0.302 0.5 0.060 1 77 3,3',4,4'-T4CB 0.016 0.05 0.790 0.5 0.158 1 105 2,3,3',4,4'-P5CB 0.008 0.05 0.422 0.5 0.084 1 114 2,3,4,4',5-P5CB 0.009 0.05 0.431 0.5 0.086 1 118 2,3',4,4',5-P5CB 0.011 0.05 0.542 0.5 0.108 1 123 2',3,4,4',5-P5CB 0.014 0.05 0.700 0.5 0.140 1 126 3,3',4,4',5-P5CB 0.009 0.05 0.444 0.5 0.089 1 156 2,3,3',4,4',5-H6CB 0.013 0.05 0.643 0.5 0.129 1 157 2,3,3',4,4',5'-H6CB 0.014 0.05 0.697 0.5 0.139 1 167 2,3',4,4',5,5'-H6CB 0.013 0.05 0.635 0.5 0.127 1 169 3,3',4,4',5,5'-H6CB 0.017 0.05 0.849 0.5 0.170 1 189 2,3,3',4,4',5,5'-H7CB 0.014 0.05 0.683 0.5 0.137 1 - xxxviii -
III-4-3. 7 (pg/l) (pg/g) 28 2,4,4'-T3CB 0.084 0.192 0.017 0.500 52 2,2',5,5'-T4CB 0.076 0.191 0.015 0.500 101 2,2',4,5,5'-P5CB 0.134 0.241 0.027 0.500 118 2,3',4,4',5-P5CB 0.076 0.193 0.015 0.500 153 2,2',4,4',5,5'-H6CB 0.126 0.211 0.025 0.500 138 2,2',3,4,4',5'-H6CB 0.136 0.130 0.027 0.500 180 2,2',3,4,4',5,5'-H7CB 0.102 0.136 0.020 0.500 * 7 EPA,. III-4-4. (pg/sm3 ) (pg/l) (pg/g) HCB - 1 0.205 5 0.041 0.5 Heptachlor 0.193 1 0.818 5 0.164 0.5 Aldrin 0.208 1 0.421 5 0.084 0.5 Heptachlor Epoxide 0.713 1 0.412 5 0.082 0.5 Oxychlordane 1.123 1 1.289 5 0.258 0.5 trans-chlordane 0.447 1 0.226 5 0.045 0.5 o,p'-dde 0.104 1 0.395 5 0.079 0.5 cis-chlordane 0.482 1 0.419 5 0.084 0.5 trans-nonachlor 0.406 1 0.304 5 0.061 0.5 p,p'-dde 0.171 1 0.136 5 0.027 0.5 Dieldrin 0.452 1 0.668 5 0.134 0.5 o,p'-ddd 0.366 1 0.206 5 0.041 0.5 Endrin 0.802 1 0.941 5 0.188 0.5 p,p'-ddd 0.264 1 0.246 5 0.049 0.5 o,p'-ddt 0.364 1 0.228 5 0.046 0.5 cis-nonachlor 0.348 1 0.386 5 0.077 0.5 p,p'-ddt 0.409 1 0.229 5 0.046 0.5 Mirex 0.122 1 0.238 5 0.048 0.5 - xxxix -
III-4-5. (pg/s m3 ) (pg/l) (pg/g) parlar 26 0.008 0.2 0.194 5 0.039 0.5 Toxaphene parlar 50 0.035 0.2 0.873 5 0.175 0.5 parlar 62 0.007 0.2 0.187 5 0.037 0.5 2), POPs,,,.. ) (field blank) ( III-4-6. III-4-13.). 1, 1 (glassware blank). ) (glassware blank), ( III-4-14. III-4-18.)., shuttle, - xl -
. (,, ). ) (laboratory method blank) 1,. III-4-6. (Field Blank) Measured concentration(pg) Group Compounds 1 2 3 1 2 3 1 2 3 1 2 3 2,3,7,8-TCDF N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. 1,2,3,7,8-PeCDF N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. 2,3,4,7,8-PeCDF N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. 1,2,3,4,7,8-HxCDF N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. Furan 1,2,3,6,7,8-HxCDF N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. 2,3,4,6,7,8-HxCDF N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. 1,2,3,7,8,9-HxCDF N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. 1,2,3,4,6,7,8-HpCDF N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. 1,2,3,4,7,8,9-HpCDF N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. OCDF N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. 2,3,7,8-TCDD N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. 1,2,3,7,8-PeCDD N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. Dioxin 1,2,3,4,7,8-HxCDD N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. 1,2,3,6,7,8-HxCDD N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. 1,2,3,7,8,9-HxCDD N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. 1,2,3,4,6,7,8-HpCDD N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. - xli -
III-4-7. (Field Blank) Group Furan Dioxin Measured concentration(pg) Compounds 2,3,7,8-TCDF N.D. N.D. N.D. N.D. 1,2,3,7,8-PeCDF N.D. N.D. N.D. N.D. 2,3,4,7,8-PeCDF N.D. N.D. N.D. N.D. 1,2,3,4,7,8-HxCDF N.D. N.D. N.D. N.D. 1,2,3,6,7,8-HxCDF N.D. N.D. N.D. N.D. 2,3,4,6,7,8-HxCDF N.D. N.D. N.D. N.D. 1,2,3,7,8,9-HxCDF N.D. N.D. N.D. N.D. 1,2,3,4,6,7,8-HpCDF N.D. N.D. N.D. N.D. 1,2,3,4,7,8,9-HpCDF N.D. N.D. N.D. N.D. OCDF N.D. N.D. N.D. N.D. 2,3,7,8-TCDD N.D. N.D. N.D. N.D. 1,2,3,7,8-PeCDD N.D. N.D. N.D. N.D. 1,2,3,4,7,8-HxCDD N.D. N.D. N.D. N.D. 1,2,3,6,7,8-HxCDD N.D. N.D. N.D. N.D. 1,2,3,7,8,9-HxCDD N.D. N.D. N.D. N.D. 1,2,3,4,6,7,8-HpCDD N.D. N.D. N.D. N.D. III-4-8. (Field Blank) Group Compounds Measured concentration(pg) 1 2 3 1 2 3 1 2 3 1 2 3 81 3,4,4',5-T4CB N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. 77 3,3',4,4'-T4CB N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. 105 2,3,3',4,4'-P5CB N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. 114 2,3,4,4',5-P5CB N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. 118 2,3',4,4',5-P5CB N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. 123 2',3,4,4',5-P5CB N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. 126 3,3',4,4',5-P5CB N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. 156 2,3,3',4,4',5-H6CB N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. 157 2,3,3',4,4',5'-H6CB N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. 167 2,3',4,4',5,5'-H6CB N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. 169 3,3',4,4',5,5'-H6CB N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. 189 2,3,3',4,4',5,5'-H7CB N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. - xlii -
III-4-9. (Field Blank) Group Compounds Measured concentration(pg) 81 3,4,4',5-T4CB N.D. N.D. N.D. N.D. 77 3,3',4,4'-T4CB N.D. N.D. N.D. N.D. 105 2,3,3',4,4'-P5CB N.D. N.D. N.D. N.D. 114 2,3,4,4',5-P5CB N.D. N.D. N.D. N.D. 118 2,3',4,4',5-P5CB N.D. N.D. N.D. N.D. 123 2',3,4,4',5-P5CB N.D. N.D. N.D. N.D. 126 3,3',4,4',5-P5CB N.D. N.D. N.D. N.D. 156 2,3,3',4,4',5-H6CB N.D. N.D. N.D. N.D. 157 2,3,3',4,4',5'-H6CB N.D. N.D. N.D. N.D. 167 2,3',4,4',5,5'-H6CB N.D. N.D. N.D. N.D. 169 3,3',4,4',5,5'-H6CB N.D. N.D. N.D. N.D. 189 2,3,3',4,4',5,5'-H7CB N.D. N.D. N.D. N.D. III-4-10. (Field Blank) 7 Measured concentration(pg) Group Compounds 28 2,4,4'-T3CB N.D. N.D. N.D. N.D. 52 2,2',5,5'-T4CB N.D. N.D. N.D. N.D. 101 2,2',4,5,5'-P5CB N.D. N.D. N.D. N.D. 118 2,3',4,4',5-P5CB N.D. N.D. N.D. N.D. 153 2,2',4,4',5,5'-H6CB N.D. N.D. N.D. N.D. 138 2,2',3,4,4',5'-H6CB N.D. N.D. N.D. N.D. 180 2,2',3,4,4',5,5'-H7CB N.D. N.D. N.D. N.D. - xliii -
III-4-11. (Field Blank) Measured concentration(pg) Compounds 1 2 3 1 2 3 1 2 3 1 2 3 Heptachlor N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. Aldrin N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. Heptachlor Epoxide N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. Oxychlordane N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. trans-chlordane N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. o,p'-dde N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. cis-chlordane N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. trans-nonachlor N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. p,p'-dde N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. Dieldrin N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. o,p'-ddd N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. Endrin N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. p,p'-ddd N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. o,p'-ddt N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. cis-nonachlor N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. p,p'-ddt N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. Mirex N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. - xliv -
III-4-12. (Field Blank) Compounds Measured concentration(pg) HCB N.D. N.D. N.D. N.D. Heptachlor N.D. N.D. N.D. N.D. Aldrin N.D. N.D. N.D. N.D. Heptachlor Epoxide N.D. N.D. N.D. N.D. Oxychlordane N.D. N.D. N.D. N.D. trans-chlordane N.D. N.D. N.D. N.D. o,p'-dde N.D. N.D. N.D. N.D. cis-chlordane N.D. N.D. N.D. N.D. trans-nonachlor N.D. N.D. N.D. N.D. p,p'-dde N.D. N.D. N.D. N.D. Dieldrin N.D. N.D. N.D. N.D. o,p'-ddd N.D. N.D. N.D. N.D. Endrin N.D. N.D. N.D. N.D. p,p'-ddd N.D. N.D. N.D. N.D. o,p'-ddt N.D. N.D. N.D. N.D. cis-nonachlor N.D. N.D. N.D. N.D. p,p'-ddt N.D. N.D. N.D. N.D. Mirex N.D. N.D. N.D. N.D. III-4-13. (Field Blank) Group Compounds 1 2 3 1 2 3 1 2 3 1 2 3 parlar 26 N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. parlar 50 N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. parlar 62 N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. Group Compounds Measured concentration(pg) parlar 26 N.D. N.D. N.D. N.D. parlar 50 N.D. N.D. N.D. N.D. parlar 62 N.D. N.D. N.D. N.D. - xlv -
III-4-14. (Glassware Blank) Measured concentration(pg) Group Compounds Furan Dioxin Shuttle Shuttle 2,3,7,8-TCDF N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. 1,2,3,7,8-PeCDF N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. 2,3,4,7,8-PeCDF N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. 1,2,3,4,7,8-HxCDF N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. 1,2,3,6,7,8-HxCDF N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. 2,3,4,6,7,8-HxCDF N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. 1,2,3,7,8,9-HxCDF N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. 1,2,3,4,6,7,8-HpCDF N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. 1,2,3,4,7,8,9-HpCDF N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. OCDF N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. 2,3,7,8-TCDD N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. 1,2,3,7,8-PeCDD N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. 1,2,3,4,7,8-HxCDD N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. 1,2,3,6,7,8-HxCDD N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. 1,2,3,7,8,9-HxCDD N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. 1,2,3,4,6,7,8-HpCDD N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. Shuttle Shuttle III-4-15. (Glassware Blank) Group Compounds Measured concentration(pg) Shuttle Shuttle Shuttle Shuttle 81 3,4,4',5-T4CB N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. 77 3,3',4,4'-T4CB N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. 105 2,3,3',4,4'-P5CB N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. 114 2,3,4,4',5-P5CB N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. 118 2,3',4,4',5-P5CB N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. 123 2',3,4,4',5-P5CB N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. 126 3,3',4,4',5-P5CB N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. 156 2,3,3',4,4',5-H6CB N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. 157 2,3,3',4,4',5'-H6CB N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. 167 2,3',4,4',5,5'-H6CB N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. 169 3,3',4,4',5,5'-H6CB N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. 189 2,3,3',4,4',5,5'-H7CB N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. - xlvi -
III-4-16. (Glassware Blank) 7 Group Compounds Measured concentration(pg) 28 2,4,4'-T3CB N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. 52 2,2',5,5'-T4CB N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. 101 2,2',4,5,5'-P5CB N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. 118 2,3',4,4',5-P5CB N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. 153 2,2',4,4',5,5'-H6CB N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. 138 2,2',3,4,4',5'-H6CB N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. 180 2,2',3,4,4',5,5'-H7CB N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. III-4-17. (Glassware Blank) Measured concentration(pg) Compounds Shuttle Shuttle Shuttle Shuttle HCB N.D. - N.D. -. N.D. N.D. N.D. -. N.D. - N.D. N.D. Heptachlor N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. Aldrin N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. Heptachlor Epoxide N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. Oxychlordane N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. trans-chlordane N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. o,p'-dde N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. cis-chlordane N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. trans-nonachlor N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. p,p'-dde N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. Dieldrin N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. o,p'-ddd N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. Endrin N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. p,p'-ddd N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. o,p'-ddt N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. cis-nonachlor N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. p,p'-ddt N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. Mirex N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. III-4-18. (Glassware Blank) Measured concentration(pg) Group Compounds Shuttle Shuttle Shuttle Shuttle parlar 26 N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. parlar 50 N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. parlar 62 N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. - xlvii -
3) (accuracy),, 7,, 1 POPs.,, 7 PCBs,,. 97.4 115.2%, 93.6 105.0%, HRGC/HRMS 84.2 115.7%, HRGC/LRMS 76.8 96.3%, 7 PCBs 102.5 ~ 127.5%, 96.1 ~ 103.0% ( III-4-19 ~ III-4-24). III-4-19. (%) Group Compounds STD2 STD2 STD2 STD2 STD2 STD2 STD2 Furan Dioxin 2,3,7,8-TCDF 101.0 102.5 101.4 101.9 103.0 101.7 110.0 1,2,3,7,8-PeCDF 100.6 99.6 101.5 99.8 100.9 100.6 99.9 2,3,4,7,8-PeCDF 102.9 100.7 100.4 100.1 104.0 101.9 99.8 1,2,3,4,7,8-HxCDF 101.2 100.7 99.2 100.0 100.8 100.7 100.7 1,2,3,6,7,8-HxCDF 100.3 100.2 102.7 101.1 100.6 99.9 101.6 2,3,4,6,7,8-HxCDF 101.4 100.1 99.9 100.5 100.9 99.7 100.4 1,2,3,7,8,9-HxCDF 101.3 100.2 100.0 99.9 100.0 100.7 101.1 1,2,3,4,6,7,8-HpCDF 102.1 101.6 100.0 99.7 100.2 100.0 100.5 1,2,3,4,7,8,9-HpCDF 100.5 100.1 102.3 101.0 100.7 100.5 101.3 OCDF 100.2 100.1 99.9 103.8 100.2 102.7 101.5 2,3,7,8-TCDD 98.2 97.8 99.4 106.4 97.4 98.4 98.8 1,2,3,7,8-PeCDD 100.7 101.6 99.3 99.8 102.5 100.8 105.1 1,2,3,4,7,8-HxCDD 106.2 105.4 104.0 100.1 102.2 105.5 106.2 1,2,3,6,7,8-HxCDD 103.6 101.3 100.5 103.6 99.9 101.4 101.8 1,2,3,7,8,9-HxCDD 103.9 99.4 101.0 101.4 103.0 102.6 103.5 1,2,3,4,6,7,8-HpCDD 105.1 103.8 105.4 101.9 102.7 105.3 105.6 OCDD 115.2 112.1 112.7 112.4 111.6 110.8 113.5 97.4 115.2 102.1 - xlviii -
III-4-20. (%) Group Compounds STD2 STD2 STD2 STD2 STD2 STD2 STD2 81 3,4,4',5-T4CB 102.8 105.0 103.4 104.0 103.0 102.0 103.8 77 3,3',4,4'-T4CB 99.0 102.6 103.8 99.2 97.0 97.6 100.6 105 2,3,3',4,4'-P5CB 100.4 99.4 98.4 97.0 100.4 97.4 98.8 114 2,3,4,4',5-P5CB 102.4 102.6 101.4 100.2 100.4 100.0 98.8 118 2,3',4,4',5-P5CB 98.0 97.2 97.2 98.2 97.0 94.0 94.2 123 2',3,4,4',5-P5CB 100.0 99.2 98.0 97.4 95.2 93.6 96.6 126 3,3',4,4',5-P5CB 97.8 96.2 96.4 96.4 94.6 97.6 94.0 156 2,3,3',4,4',5-H6CB 99.2 102.6 98.4 98.4 97.8 100.2 102.8 157 2,3,3',4,4',5'-H6CB 98.4 98.6 97.8 99.0 102.6 96.0 101.4 167 2,3',4,4',5,5'-H6CB 99.2 98.8 100.4 102.8 97.4 102.4 98.6 169 3,3',4,4',5,5'-H6CB 99.8 101.2 101.8 101.4 99.4 94.2 101.8 189 2,3,3',4,4',5,5'-H7CB 99.2 102.0 100.2 101.6 100.0 96.8 96.4 93.6 105.0 99.3 III-4-21. HRMS (OCPs) (%) Compounds STD2 STD2 STD2 STD2 STD2 STD2 STD2 Heptachlor 98.3 98.6 94.9 97.9 95.9 95.8 98.5 Aldrin 95.1 97.3 95.2 98.2 95.1 94.2 98.1 Heptachlor Epoxide 108.0 97.4 112.6 101.4 98.5 107.6 100.7 Oxychlordane 107.1 96.2 84.2 111.9 99.4 98.9 94.2 trans-chlordane 98.2 96.3 102.2 95.3 94.9 101.3 92.3 o,p'-dde 98.6 99.9 99.3 100.1 100.7 98.4 99.6 cis-chlordane 91.7 87.4 98.0 96.3 98.1 95.2 95.1 trans-nonachlor 102.7 99.2 104.4 96.1 96.0 102.1 99.7 p,p'-dde 103.2 101.6 101.3 98.7 101.5 101.0 101.9 Dieldrin 101.2 101.7 98.5 94.5 103.2 93.7 98.3 o,p'-ddd 100.0 101.6 97.4 100.7 100.3 104.1 95.1 Endrin 115.7 97.8 102.2 100.9 106.6 96.8 104.8 p,p'-ddd 102.0 104.3 99.7 97.7 100.2 100.3 102.1 o,p'-ddt 101.5 96.0 102.0 101.7 101.0 95.6 102.1 cis-nonachlor 97.4 98.1 99.8 95.6 101.7 97.2 103.5 p,p'-ddt 95.5 93.1 89.8 94.1 88.5 91.7 86.3 Mirex 98.1 99.5 98.1 97.1 99.0 96.9 97.5 84.2 115.7 98.8 * Heptachlor Epoxide, Oxychlordane, trans/cis-chlordane, trans/cis-nonachlor STD3. - xlix -
III-4-22. LRMS (OCPs) (%) Compounds STD2 STD2 STD2 STD2 STD2 STD2 STD2 HCB 94.3 93.5 94.8 92.8 95.3 94.0 94.3 Heptachlor 91.5 84.0 87.8 81.3 87.0 88.0 87.5 Aldrin 93.3 92.8 89.3 90.8 91.3 91.8 88.8 Heptachlor Epoxide 88.0 85.8 83.3 83.8 85.0 84.0 86.0 Oxychlordane 79.3 76.8 79.3 81.0 91.3 87.5 82.5 trans-chlordane 89.5 87.0 88.8 89.5 88.8 89.3 89.5 o,p'-dde 93.8 92.8 91.0 93.8 95.3 93.5 95.8 cis-chlordane 88.5 87.5 88.0 88.5 89.0 86.0 91.5 trans-nonachlor 91.0 90.0 89.3 90.3 92.5 89.0 89.5 p,p'-dde 93.8 93.3 94.0 93.0 93.5 92.8 94.3 Dieldrin 93.3 86.3 86.3 87.5 88.0 91.5 88.8 o,p'-ddd 90.0 90.3 89.5 91.6 91.0 89.5 91.0 Endrin 90.0 86.0 91.0 87.8 85.8 92.3 96.3 p,p'-ddd 89.5 90.0 87.3 89.8 89.5 88.3 88.8 o,p'-ddt 89.0 86.8 88.0 88.8 89.0 89.5 88.3 cis-nonachlor 86.8 85.8 85.0 87.0 88.0 89.8 87.0 p,p'-ddt 88.0 89.0 86.8 87.3 89.0 88.0 89.0 Mirex 88.5 89.0 89.8 91.0 90.8 90.5 90.5 76.8 96.3 89.2 III-4-23. Total PCBs (%) Group Compounds STD2 STD2 STD2 STD2 STD2 STD2 STD2 28 2,4,4'-T3CB 120.0 117.5 115.0 110.0 115.0 112.5 117.5 52 2,2',5,5'-T4CB 115.0 115.0 112.5 110.0 120.0 115.0 115.0 101 2,2',4,5,5'-P5CB 122.5 115.0 122.5 120.0 127.5 112.5 125.0 118 2,3',4,4',5-P5CB 120.0 122.5 117.5 112.5 117.5 117.5 117.5 153 2,2',4,4',5,5'-H6CB 122.5 117.5 120.0 112.5 110.0 110.0 112.5 138 2,2',3,4,4',5'-H6CB 110.0 112.5 110.0 120.0 107.5 107.5 102.5 180 2,2',3,4,4',5,5'-H7CB 112.5 115.0 117.5 107.5 120.0 112.5 112.5 102.5 127.5 115.4 - l -
III-4-25. (%) Group Compounds STD2 STD2 STD2 STD2 STD2 STD2 STD2 parlar 26 97.5 98.9 97.6 98.6 98.7 99.0 98.5 parlar 50 96.3 96.5 96.1 98.1 101.0 102.0 102.2 parlar 62 103.0 103.0 101.9 102.3 101.8 101.9 101.5 102.5 127.5 115.4 5) (precision),, 7, (RSD, relative standard deviation) (CV, coefficient of variation). / 1 POPs. (x' =, S = ), 7 PCBs,, 0-5%, Oxychlordane 5% ( III-4-25~III-4-28). - li -
III-4-25. Group Furan Dioxin Compounds (%) 2,3,7,8-TCDF 3.029 1,2,3,7,8-PeCDF 0.659 2,3,4,7,8-PeCDF 1.562 1,2,3,4,7,8-HxCDF 0.645 1,2,3,6,7,8-HxCDF 0.961 2,3,4,6,7,8-HxCDF 0.587 1,2,3,7,8,9-HxCDF 0.555 1,2,3,4,6,7,8-HpCDF 0.909 1,2,3,4,7,8,9-HpCDF 0.726 OCDF 1.516 2,3,7,8-TCDD 3.130 1,2,3,7,8-PeCDD 1.910 1,2,3,4,7,8-HxCDD 2.233 1,2,3,6,7,8-HxCDD 1.405 1,2,3,7,8,9-HxCDD 1.553 1,2,3,4,6,7,8-HpCDD 1.399 OCDD 1.278 III-4-26. Group Compounds (%) 81 3,4,4',5-T4CB 0.930 77 3,3',4,4'-T4CB 2.516 105 2,3,3',4,4'-P5CB 1.360 114 2,3,4,4',5-P5CB 1.362 118 2,3',4,4',5-P5CB 1.789 123 2',3,4,4',5-P5CB 2.295 126 3,3',4,4',5-P5CB 1.470 156 2,3,3',4,4',5-H6CB 2.051 157 2,3,3',4,4',5'-H6CB 2.241 167 2,3',4,4',5,5'-H6CB 2.023 169 3,3',4,4',5,5'-H6CB 2.706 189 2,3,3',4,4',5,5'-H7CB 2.187 - lii -
III-4-27. 7 Group Compounds (%) 28 2,4,4'-T3CB 2.915 52 2,2',5,5'-T4CB 2.650 101 2,2',4,5,5'-P5CB 4.428 118 2,3',4,4',5-P5CB 2.577 153 2,2',4,4',5,5'-H6CB 4.348 138 2,2',3,4,4',5'-H6CB 4.910 180 2,2',3,4,4',5,5'-H7CB 3.551 III-4-28. Compounds HRMS for Ambient(%) LRMS for etc (%) HCB 1.378 0.866 Heptachlor 1.582 3.753 Aldrin 1.726 1.840 Heptachlor Epoxide 5.473 1.925 Oxychlordane 9.049 6.220 trans-chlordane 3.662 1.012 o,p'-dde 0.831 1.679 cis-chlordane 4.060 1.887 trans-nonachlor 3.233 1.343 p,p'-dde 1.340 0.578 Dieldrin 3.650 2.995 o,p'-ddd 2.921 0.906 Endrin 6.166 4.167 p,p'-ddd 2.080 1.100 o,p'-ddt 2.897 1.025 cis-nonachlor 2.796 1.766 p,p'-ddt 3.569 1.034 Mirex 0.990 1.052 parlar 26-0.628 parlar 50-2.811 parlar 62-0.584 - liii -
1., 1) (PCDD/DFs, co-pcbs) ) 2009 (PCDD/DFs, Co-PCBs) IV-1-1, IV-1-1. / 0.051±0.060 pg I-TEQ/m 3, 0.002±0.003 pg WHO-TEQ/m 3. / 0.053±0.062 pg TEQ/m 3. 0.16 0.14 winter spring summer fall concentration (pg TEQ/m 3 ) 0.12 0.10 0.08 0.06 0.04 mean : 0.051 0.02 0.00 PCDD/DFs Co-PCBs mean : 0.002 IV-1-1. (PCDD/DFs, Co-PCBs) - liv -
IV-1-1. ( : pg TEQ/m 3 ) PCDD/DFs PCDD/DFs+Co-PCBs 0.034 0.000 0.034 0.043 0.003 0.047 0.050 0.002 0.052 0.006 0.000 0.006 0.059 0.001 0.060 0.205 0.012 0.217 0.047 0.002 0.048 0.304 0.010 0.314 0.130 0.009 0.139 0.127 0.007 0.134 0.089 0.004 0.092 0.013 0.000 0.013 0.032 0.000 0.032 0.092 0.001 0.093 0.055 0.001 0.056 0.065 0.003 0.068 0.041 0.001 0.042 0.045 0.000 0.045 0.019 0.001 0.020 0.015 0.000 0.015 0.056 0.006 0.062 0.009 0.000 0.009 0.070 0.007 0.077 0.033 0.001 0.034 0.024 0.001 0.025 0.001 0.000 0.001 0.020 0.000 0.020 0.010 0.000 0.010 0.024 0.002 0.026 0.039 0.002 0.040 0.001 0.000 0.001 0.034 0.002 0.036 0.027 0.001 0.028 0.028 0.002 0.030 0.030 0.002 0.031 0.001 0.000 0.001 0.001 0.000 0.001 0.304 0.012 0.314 0.001 0.000 0.001 0.051 0.002 0.053 0.060 0.003 0.062 PCDDs :, PCDFs :, Co-PCBs : - lv -
) (PCDD/DFs, Co-PCBs) IV-1-2. 148 0.001 pg TEQ/m 3 50%, 0.001~0.01 pg TEQ/m 3 50% 0.01 pg TEQ/m 3. / 0.001 pg TEQ/m 3 10%, 0.001~0.01 pg TEQ/m 3 10% 0.01~0.5 pg TEQ/m 3 80% / 0.01~0.5 pg TEQ/m 3. 1.00 cumulative fraction 0.75 0.50 PCDD/DFs Co-PCBs n = 148 0.25 0.00 1E-3 0.01 0.1 concentration (pg TEQ/m 3 ) IV-1-2. (PCDD/DFs, Co-PCBs) - lvi -
) (PCDD/DFs, Co-PCBs) IV-1-2. / 2002 2004 0.074~0.16 pg TEQ/m 3, 0.143~0.497 pg TEQ/m 3, 0.003~0.247 pg TEQ/m 3, 0.018~0.644 pg TEQ/m 3., 2004 2005 0.001~5.791 pg TEQ/m 3, 1999 2005 0.008~0.723 pg TEQ/m 3., 0.014~0.099 pg TEQ/m 3,,,, 0.004~0.306 pg TEQ/m 3. 0.051 pg TEQ/m 3,. 2002 0.003~0.065 pg TEQ/m 3., IV-1-2. 2004~2005 0.0006~0.0365 pg TEQ/m 3, 0.001~0.018 pg TEQ/m 3 0.002±0.003 pg TEQ/m 3, 0.002 pg TEQ/m 3, 0.00058 pg TEQ/m 3. (PCDD/DFs, Co-PCBs). IV-1-3, IV-1-3. 1999 2008 / 0.0454~0.425 pg TEQ/m 3, 0.051 pg - lvii -
TEQ/m 3, 0.6 pg TEQ/m 3. 2002 2008, 0.001~0.0209 pg TEQ/m 3 /. / 1999 24 0.425 pg TEQ/m 3 2004 0.1682 pg TEQ/m 3 2005 2009 0.0454, 0.0675, 0.028, 0.051 pg TEQ/m 3 / 2005 ( IV-1-3). / 2003 0.0209 pg TEQ/m 3, 2005, 0.001~0.004 pg TEQ/m 3. 1997 50ton/day, 2001, 2004, 2006 2005. - lviii -
IV-1-2. Hong Kong Country/city PCDD/Fs (pg I-TEQ/m 3 ) Co-PCBs (pg I-TEQ/m 3 ) Period site ref 0.0073-0.154 a 0.00061-0.016 a Tap Mun 0.001-5.791 a 0.00253-0.0365 a 2004-2005 Yuen Long Maggie t al., 2008 0.0074-0.312 a 0.00179-0.0166 a Tsuen Wan Japan 0.08-0.28 1997 Seike et al., 1997 Japan 0.021-0.45(0.16) a 2002 Japan 0.017-0.20(0.077) a 2003 Japan 0.021-0.25(0.074) a 2004 China/Shanghai China/Anshan 0.143 commercial 0.497 industrial 0.144 industrial 0.289 urban 0.006-0.119 a 0.001-0.008 a 2008 0.003-0.247 a 0.001-0.018 a 2009 Environmental Monitoring Report Li et al., 2008 Li et al., 2010 China/Beijing 0.018-0.644-2006 Li et al., 2008 Taiwan Germany 0.056-0.348 1999-2000 school zone Chang et al., 2004 0.0474-2004 Changhua County Lee et al., 2009 0.0319-0.256-2005 Kaohsiung Wang et al., 2009 0.0244-0.493-2004 - 0.00824-0.723-2004 - 0.014-0.027 rural 0.048-0.064 suburban 0.053-0.099 urban Shih et al,. 2008 Wallenhorst et al., 1997 0.048-0.085 multi type impact area Germany 0.07-0.35 1993 Rappe et al., 1993 Turkey 0.0233-0.563 2002 rural Bakoglu et al., 2005 Australia 0.02-0.06 1992 Taucher et al., 1992 Belgium 0.02-0.59 1993 Wevers et al., 1993 UK ND-1.8 1994 Duarte et al. 1994 Croatia 0.009-0.306 1997-2000 urban site Krauthacker et al., 2006 - lix -
( IV-1-2 ) Country/city PCDD/Fs Co-PCBs (pg I-TEQ/m 3 ) (pg I-TEQ/m 3 ) Period site ref Portugal/Porto 0.147-0.151(0.149) suburban Portugal/Lisbon 0.019-0.039(0.034) 2002 suburban Coutinho et al., 2007 Portugal/Madeira 0.004-0.025(0.015) rural & forest Italy/Rome 0.00543-0.734(0.0654) 0.00066-0.00728(0.00244) urban 2002 0.00148-0.00657(0.00295) 0.00012-0.00187(0.00058) Background Menichini et al., 2007 USA 0.09-0.45 1996 Riggs et al., 1996 a : WHO-TEQ - lx -
IV-1-3. (PCDD/DFs, Co-PCBs) (pg TEQ/m 3 ) (n) PCDD/DFs Co-PCBs 1999 24 0.425 (ND~4.448) 2000 26 0.315 (ND~2.511) 2001 26 0.300 (ND~3.655) 2002 33 2003 35 0.2464 (ND~1.9123) 0.2455 (ND~5.2962) 0.0183 0.0209, 2006 2004 35 0.1682 (ND~2.1493) 0.0101 2005 15 0.0454 (ND~0.3448) 0.0025 2006 32 0.0675 (ND~0.5538) 0.004 2008 37 0.028 (ND~0.617) 0.001 (ND~0.016), 2009 2001 3 0.555 (0.382~0.777) 2002 3 2003 6 0.606 (0.398~1.140) 0.441 (0.079~1.188) 0.04887 (0.01936~0.09748) 0.02911 (0.00663~0.04433) Kim et al., 2007 2004 6 0.347 (0.135~0.628) 0.02774 (0.00718~0.06360) - lxi -
0.5 0.4 PCDD/DFs CO-PCBs 0.020 PCDD/DFs (pg-teq/m 3 ) 0.3 0.2 0.1 0.015 0.010 0.005 Co-PCBs (pg-teq/m 3 ) 0.0 0.000 1998 1999 2000 2001 2002 2003 2004 2005 2006 2007 2008 2009 2010 year IV-1-3. (PCDD/DFs, Co-PCBs) - lxii -
) (PCDD/DFs, Co-PCBs) 37 1 4 IV-1-4. /, 0.074±0.079 pg TEQ/m 3, (0.061±0.100 pg TEQ/m 3 ), (0.036±0.067 pg TEQ/m 3 ), (0.032±0.038 pg TEQ/m 3 ),. 0.003 pg TEQ/m 3, 3 0.002 pg TEQ/m 3. (37),.,. 1 (one way ANOVA; analysis of variance), 2 (multi way ANOVA; analysis of variance). / 1., p = 0.052 p > 0.05 95% /. 0.074 pg TEQ/m 3,.,. - lxiii -
IV-1-4. (PCDD/DFs, Co-PCBs) (pg TEQ/m 3 ) PCDD/DFs(pg TEQ/m 3 ) Co-PCBs(pg TEQ/m 3 ) 0.064 0.016 0.055 0.001 0.000 0.000 0.000 0.000 0.107 0.031 0.034 0.001 0.005 0.003 0.005 0.000 0.148 0.046 0.004 0.000 0.006 0.003 0.000 0.000 0.015 0.000 0.005 0.003 0.000 0.000 0.000 0.000 0.057 0.068 0.017 0.092 0.000 0.003 0.000 0.002 0.203 0.081 0.321 0.216 0.009 0.007 0.017 0.015 0.150 0.029 0.005 0.003 0.007 0.000 0.000 0.000 0.366 0.178 0.119 0.554 0.011 0.009 0.007 0.012 0.157 0.091 0.146 0.127 0.009 0.004 0.013 0.008 0.231 0.041 0.066 0.171 0.009 0.003 0.004 0.013 0.186 0.091 0.015 0.061 0.006 0.005 0.000 0.004 0.013 0.001 0.032 0.007 0.000 0.000 0.000 0.000 0.065 0.004 0.030 0.030 0.000 0.000 0.000 0.000 0.116 0.027 0.147 0.079 0.000 0.000 0.002 0.000 0.059 0.057 0.019 0.086 0.000 0.000 0.000 0.002 0.016 0.000 0.191 0.053 0.000 0.000 0.007 0.005 0.094 0.029 0.003 0.038 0.002 0.002 0.000 0.000 0.019 0.000 0.001 0.159 0.000 0.000 0.000 0.000 0.003 0.034 0.013 0.025 0.000 0.002 0.000 0.003 0.004 0.027 0.001 0.029 0.000 0.000 0.000 0.000 0.070 0.026 0.050 0.077 0.005 0.006 0.004 0.008 0.012 0.004 0.001 0.018 0.000 0.000 0.000 0.000 0.102 0.036 0.014 0.128 0.007 0.002 0.002 0.016 0.040 0.005 0.001 0.085 0.000 0.000 0.000 0.002 0.046 0.021 0.001 0.028 0.002 0.002 0.000 0.000 0.001 0.000 0.000 0.001 0.000 0.000 0.000 0.000 0.041 0.003 0.002 0.034 0.002 0.000 0.000 0.000 0.018 0.001 0.018 0.004 0.000 0.000 0.000 0.000 0.090 0.002 0.001 0.002 0.004 0.000 0.004 0.000 0.084 0.050 0.001 0.018 0.003 0.004 0.000 0.000 0.001 0.001 0.000 0.000 0.000 0.000 0.000 0.000 0.052 0.030 0.001 0.054 0.002 0.000 0.000 0.006 0.023 0.070 0.006 0.008 0.000 0.004 0.000 0.000 0.052 0.001 0.019 0.041 0.003 0.000 0.002 0.002 0.015 0.084 0.000 0.019 0.000 0.006 0.000 0.000 0.001 0.001 0.002 0.001 0.000 0.000 0.000 0.000 0.000 0.001 0.002 0.001 0.000 0.000 0.000 0.000 0.366 0.178 0.321 0.554 0.011 0.009 0.017 0.016 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.074 0.032 0.036 0.061 0.002 0.002 0.002 0.003 0.079 0.038 0.067 0.100 0.003 0.002 0.004 0.005 - lxiv -
) (PCDD/DFs, Co-PCBs) 37 16, (PCDD/DFs, Co-PCBs) IV-1-5 / 37, 1 36. 17,,, 16, 11 14. 16 ( IV-1-4), /, 0.154 pg TEQ/m 3 0.115 pg TEQ/m 3, 0.001~0.092 pg TEQ/m 3. 0.006, 0.007 pg TEQ/m 3, 0.000~0.003 pg TEQ/m 3. 37 IV-1-5. / 08 0.304 pg TEQ/m 3,, 0.205, 0.130, 0.127 pg TEQ/m 3. 2009 0.481 pg TEQ/m 3, 20 (,, ) 0.410~0.714 pg TEQ/m 3., 0.012 pg TEQ/m 3,, 0.010, 0.009, 0.007 pg TEQ/m 3. (PCDD/DFs, Co-PCBs) - lxv -
,,,. IV-1-5. PCDD/DFs(pg TEQ/m 3 ) Co-PCBs(pg TEQ/m 3 ) 37/37 37/37 36/37 37/37 17/37 16/37 11/37 14/37 0.000-0.366 0.000-0.178 0.000-0.321 0.000-0.554 0.002-0.011 0.002-0.009 0.002-0.017 0.002-0.016 0.074 0.032 0.037 0.061 0.005 0.004 0.006 0.007 PCDDs :, PCDFs :, Co-PCBs : - lxvi -
0.20 0.18 PCDD/DFs Co-PCBs concentration (pg TEQ/m 3 ) 0.16 0.14 0.12 0.10 0.08 0.06 0.04 0.02 0.00 S KW KG IC PS DJ DG KJ US CB CN KB KN JB JN JJ S :, KW :, KG :, IC :, PS :, DJ :, DG :, KJ :, US :, CB :, CN :, KB :, KN :, JB :, JN :, JJ : IV-1-4. 16 - lxvii -
IV-1-5. 37 - lxviii -
2) (PCDD/DFs, Co-PCBs) 2009 57 1 /, IV-1-6. / 2.280 pg TEQ/g, 0.246 pg TEQ/g. 7 0.113 ng/g. / 57, 55, 7 2. 1999 / 1999 ~2001 0.935~1.734 pg TEQ/g, 2008 1.903 pg TEQ/g. 2001 ~2004 0.004~0.066 pg TEQ/g, 2005 4.548 pg TEQ/g. /. 2008 2002 2008 ( IV-1-7 ), 0.003~0.872 pg TEQ/g 0.246 pg TEQ/g. 7 0.113 ng/g 2008 0.235 ng/g. (PCDD/DFs, Co-PCBs) IV-1-8. Zhang et al.(2009) 4.36 pg TEQ/g, 5.14 pg TEQ/g, 5.47 pg TEQ/g, 2.21 pg TEQ/g, 2.53~9 pg TEQ/g, 2.94~14.9 pg TEQ/g 2009 / 2.280 pg TEQ/g. 0.09~34.28 pg TEQ/g, 0.15~3.69 pg TEQ/g, - lxix -
0~112 pg TEQ/g 0.78~1911 pg TEQ/g. 0.083~22.6 pg TEQ/g 0.1~78.5 pg TEQ/g. /. ND~11 pg TEQ/g, 2.4 pg TEQ/g. 0.112~1.04 pg TEQ/g 0.000~3.562 pg TEQ/g. (PCDD/DFs, Co-PCBs) IV-1-9, IV-1-5. / 16.149 pg TEQ/g, 14.192 pg TEQ/g, 9.342 pg TEQ/g, 7.712 pg TEQ/g, 6.132 pg TEQ/g. /. 3.562 pg TEQ/g, 1.807 pg TEQ/g, /. 57 2, 5.921 ng/g, 0.539 ng/g. - lxx -
IV-1-6. POPs (PCDD/DFs, Co-PCBs) PCDD/DFs (pg I-TEQ/g) Co-PCBs (pg WHO-TEQ/g) PCBs (ng/g) 16.149 3.562 5.921 1) (n=57) 0.041 0.000 ND 2.280 0.246 0.113 / 57/57 55/57 2/57 2) 16.149 3.562 5.921 0.041 0.004 0.539 1) (0.000) 2) 2.280 0.255 3.230 - lxxi -
IV-1-7 (PCDD/DFs, Co-PCBs) (pg TEQ/g) (n) PCDD/DFs Co-PCBs 1999 35 0.935 (0.000~22.439) 2000 35 1.734 (0.000~40.478) 2001 35 1.703 (0.000~43.333) 2002 35 0.004 (0.000~0.069) 0.003 (0.000~0.023), 2006 2003 33 0.066 (0.000~0.919) 0.006 (0.000~0.139) 2004 38 0.031 (0.000~0.280) 0.006 (0.000~0.141) 2005 23 4.548 (0.005~80.934) 0.872 (0.000~15.641) 2008 57 1.903 (0.039~10.814) 0.235 (0.000~1.974), 2009, ( ), ( ) 2007 12 2007 12 0.359 (0.000~3.379) 0.081 (0.000~0.5), 2009, (,, ) 1994 16 6.563 (0.2~29.3) Im et al., 2002 :,,,,,,,,,,, :,, - lxxii -
IV-1-8. Country/city PCDD/Fs (pg I-TEQ/g) Co-PCBs (pg WHO-TEQ/g) Period site ref 0.565-1.69-2004 Control area China Wong et al., 2007 13.2-28.4 - Rural China 2.3-45 a 0.42-11 a 2006 Taizhou Shen et al., 2009 China 0.017-3.86 a ND-1.18 a - 6.41-7.75 a 0.11-8.95 a - Liu, et al., 2009 0.45-2.63-2007 China 0.94-5.78-2008 Plant Li et al., 2010 0.69-3.54-2009 0.30-8.22(4.36) - Residential/commercial area China 1.44-8.23(5.14) - Industrial area 1.19-15.9(5.47) - Suburban 0.36-2.87(2.21) - Remote mountains Zhang et al., 2009 China 7.18±0.56 a 2.4±4.36 eastern China Liu et al., 2009 Japan/Akita 0.016-0.68 paddy soil Kiguchi et al., 2007 Japan 0.3-9.4(3.1) - 1992-1998 Rural Paddy soil Seike et al., 2001 Japan 0.17-67(9) - Urban Ono et al., 2001 Japan 2.53-1993 Industrial area Sakurai et al., 1996 Taiwan 2.94-14.9 a 0.112-1.04 2001-2002 agricultural region Jou et al., 2007 Taiwan 10.3 2004 Changhua County Lee et al., 2009 Spain 0.33-15.08 2003-2004 industrial landfill 0.37-0.90 forest Karell et al., 2006 - lxxiii -
IV-1-8. () Country/city PCDD/Fs Co-PCBs (pg I-TEQ/g) (pg WHO-TEQ/g) Period site ref 0.27-2.24 1996 control site Spain 0.1-34.28 1993-1999 plant site Eljarrat et al., 2001 0.09-1.08 1995 industrial 0-26(1) b - Rural German 0-112(3) b - High density urban area 0-88(2) b - Urbanized area Umweltbundesamt, 2002 0-72(4) b - Industrial areas Russia 0.15-1.95 - Background Rural area 1.19-3.69-2002 Urban Amirova et al., 2002 UK 0.78-17.5(5.2) - Rural area HMIP, 1995 UK 6-1911 - Industrial urban areas Vizard et al., 2003 UK 3-20 - 1990 Suburban/urban sites Stenhouse et al., 1990 UK 4.9-87(28.4) - Urban HMIP, 1995 USA 0.1-6.0(2.5) - Background US EPA, 2000 USA 2-21(9.4) - Urban USA 0.083-22.6(3.0) - 1994 Rural Rappe et al., 1997 USA 1.77-5.51(2.88) - 2001 Agriculture fields Petreas et al., 2003 Canada 0.73-5.9 (3.58) - Background Tewhey Associates, 1997 0.16-0.22 - Rural Canada 0.1-78.5 - Urban Birmingham et al., 1990 1.7-101.8 - Industrial sites a : pg WHO-TEQ/g b : median value - lxxiv -
IV-1-9. (PCDD/DFs, Co-PCBs) ( : pg TEQ/g) PCDD/DFs Co-PCBs PCDD/DFs+Co-PCBs total PCBs(ng/g) 1.236 0.201 1.437 ND 2.312 0.359 2.671 ND 0.901 0.128 1.029 ND 2.792 0.220 3.012 ND CC 0.824 0.095 0.919 ND 0.965 0.111 1.076 ND 1.716 0.117 1.833 ND 5.942 0.810 6.752 ND 0.135 0.000 0.135 ND 0.548 0.055 0.603 ND 0.721 0.128 0.849 ND 14.192 1.807 15.999 0.539 0.814 0.052 0.866 ND 0.240 0.020 0.260 ND 0.479 0.005 0.484 ND 0.810 0.004 0.814 ND 4.335 0.060 4.395 ND 9.342 0.047 9.389 ND 0.499 0.051 0.550 ND 1.106 0.076 1.182 ND 0.573 0.063 0.636 ND 2.312 0.025 2.337 ND 0.200 0.023 0.223 ND 0.041 0.004 0.045 ND 0.972 0.186 1.158 ND 0.301 0.018 0.319 ND 2.604 0.355 2.959 ND 0.417 0.042 0.459 ND 6.132 0.221 6.353 ND 0.878 0.079 0.957 ND 4.278 3.562 7.840 5.921 1.437 0.307 1.744 ND 0.985 0.068 1.053 ND 0.432 0.020 0.452 ND 1.068 0.111 1.179 ND 0.837 0.043 0.880 ND 1.641 0.172 1.813 ND 7.712 0.192 7.904 ND 0.606 0.093 0.699 ND 0.953 0.115 1.068 ND 1 1.814 0.365 2.179 ND 0.955 0.084 1.039 ND 3.012 0.368 3.380 ND 0.942 0.206 1.148 ND 5.297 1.236 6.533 ND 2.398 0.157 2.555 ND 0.594 0.050 0.644 ND 2.987 0.263 3.250 ND 0.152 0.016 0.168 ND 16.149 0.703 16.852 ND 0.239 0.000 0.239 ND 0.400 0.042 0.442 ND 2.970 0.063 3.033 ND 0.598 0.069 0.667 ND CC 0.205 0.040 0.245 ND 3.230 0.233 3.463 ND 3.728 0.069 3.797 ND 16.149 3.562 16.852 5.921 0.041 0.000 0.045 ND 2.280 0.246 2.526 0.113 - lxxv -
IV-1-6. (PCDD/DFs, Co-PCBs) - lxxvi -
3) (PCDD/DFs, Co-PCBs) ) (PCDD/DFs, Co-PCBs), 36 8, 9, 5, 4, 10. (PCDD/DFs, Co-PCBs) IV-1-10. / 0.165 pg TEQ/L, 0.005 pg TEQ/L, (7 ) 0.003 ng/l. / 36 36, 7, (7 ) 1. 1999 2005, 2008 IV-1-11., / 0.006~2.479 pg TEQ/L (0.165 pg TEQ/L). 0.001~0.110 pg TEQ/L (0.005 pg TEQ/L). IV-1-12. / 1998 2004, 0.0069~48 pg TEQ/L, 0.001 pg TEQ/L, 0.004 pg TEQ/L. 2000 0.017 pg TEQ/L, 2006 ~1.6 pg TEQ/L, 1.2~1.3 pg TEQ/L, 0.009~0.050 pg TEQ/L. / 2009 - lxxvii -
(0.165 pg TEQ/L). 36 (PCDD/DFs, Co-PCBs) IV-1-13, IV-1-6. / 0.484 pg TEQ/L, 0.061 pg TEQ/L, 0.011 pg TEQ/L 0.010 pg TEQ/L. / 1.073 pg TEQ/L 36. 1.009 pg TEQ/L, 0.033 pg TEQ/L, 0.165 pg TEQ/L, 0.019 pg TEQ/L., 0.075 pg TEQ/L, 2008. - lxxviii -
IV-1-10. POPs (PCDD/DFs, Co-PCBs) 1) (n=36) PCDD/DFs (pg I-TEQ/L) Co-PCBs (pg WHO-TEQ/L) PCBs (ng/l) 1.073 0.075 0.119 0.001 0.000 ND 0.165 0.005 0.003 / 36/36 7/36 1/36 2) 1.073 0.075 0.119 0.001 0.001 0.119 1) (0.000) 2) 0.165 0.024 0.119 - lxxix -
IV-1-11. (PCDD/DFs, Co-PCBs) ( : pg TEQ/L) (n) PCDD/DFs Co-PCBs 1999 43 0.056 (0.000~0.502) 2000 43 0.094 (0.000~1.061) 2001 43 0.073 (0.000~0.946) 2002 43 0.047 (0.000~1.373) 0.006 (0.000~0.048), 2006 2003 38 0.019 (0.000~0.377) 0.001 (0.000~0.009) 2004 41 0.006 (0.000~0.120) 0.000~0.003 2005 24 2.479 (0.042~42.977) 0.110 (0.000~1.174) 2008 36 0.072 (0.000~0.648) 0.004 (0.000~0.151), 2009 - lxxx -
IV-1-12. / Country/city PCDD/DFs (pg I-TEQ/L) Period site ref Japan China 0.065~13 1998 0.054~14 1999 0.012~48 2000 0.0028~27 2001 0.010~2.7 2002 0.020~11 2003 0.0069~4.6 2004 0.009 2005 0.020-0.050 2006 the whole country, 2005 Xijiang river Liu et al., 2008 Denmark 0.001 1991 Baltic sea Broman et al., 1991 Germany 0.004 1994 River Elbe Götz et al., 1994 USA 0.017 2000 Hudson River Lohmann et al., 2000 ND~1.6 2006 Houston Ship Channel Suarez et al., 2006 North Island 1.2~1.3 1996 Lake Rotorua Gifford et al., 1996 - lxxxi -
IV-1-13. PCDD/DFs Co-PCBs (8) (9) (5) (4) (10) PCDD/DFs + Co-PCBs ( : pg TEQ/L) PCBs(ng/L) 1.009 0.000 1.009 ND 0.692 0.000 0.692 ND 0.710 0.000 0.710 ND 0.011 0.000 0.011 0.119 0.021 0.001 0.021 ND 0.998 0.075 1.073 ND 0.194 0.000 0.194 ND 0.239 0.062 0.301 ND 0.484 0.017 0.501 0.015 0.002 0.000 0.002 ND 0.010 0.002 0.012 ND 0.002 0.000 0.002 ND 0.005 0.000 0.005 ND 0.008 0.000 0.008 ND 0.011 0.001 0.012 ND 0.002 0.000 0.002 ND 0.033 0.000 0.033 ND 0.026 0.000 0.026 ND 0.011 0.000 0.011 ND 0.018 0.000 0.018 ND 0.002 0.000 0.002 ND 0.001 0.000 0.001 ND 0.165 0.001 0.166 ND 0.118 0.000 0.118 ND 0.061 0.000 0.061 ND 0.002 0.000 0.002 ND 0.003 0.000 0.003 ND 0.019 0.000 0.019 ND 0.017 0.000 0.017 ND 0.010 0.000 0.010 ND 0.004 0.000 0.004 ND 0.035 0.000 0.035 ND 1.073 0.029 1.102 ND 0.240 0.000 0.240 ND 0.188 0.000 0.188 ND 0.002 0.000 0.002 ND 0.016 0.000 0.016 ND 0.004 0.000 0.004 ND 0.048 0.000 0.048 ND 0.013 0.000 0.013 ND 0.162 0.003 0.165 ND - lxxxii -
IV-1-7. (PCDD/DFs, Co-PCBs) - lxxxiii -
) (PCDD/DFs, Co-PCBs) 30 8, 7, 4 3, 8, (PCDD/DFs, Co-PCBs) IV-1-14. / 0.860 pg TEQ/g, 0.078 pg TEQ/g, (7 ) 0.120 ng/g. / 30, 20, (7 ) 3. 1999, 4 POPs 2006 2009 2008 IV-1-15. / 0.002~7.328 pg TEQ/g, 2008 1.293 pg TEQ/g. 4 POPs 1.86~3.99 pg TEQ/g, 0.609~2.602 pg TEQ/g, 0.218~4.754 pg TEQ/g, 0.054~0.084 pg TEQ/g 0.034~0.401 pg TEQ/g. 0.002~1.694 pg TEQ/g, 2008 0.090 pg TEQ/g. 4 POPs 0.12~0.23 pg TEQ/g, 0.142~0.535 pg TEQ/g, 0.084~0.544 pg TEQ/g, 0.003~0.017 pg TEQ/g 0.002~0.029pg TEQ/g. 2009 / 0.860 pg TEQ/g 0.078 pg TEQ/g, 2008. / - lxxxiv -